Catalysts for nitrogen reduction to ammonia
Abstract
We present the production of synthetic ammonia remains dependent on the energy- and capital-intensive Haber-Bosch process. Extensive research in molecular catalysis has demonstrated ammonia production from di-nitrogen, albeit at low production rates. Mechanistic understanding of di-nitrogen reduction to ammonia continues to be delineated through study of molecular catalyst structure, as well as through understanding the naturally-occurring nitrogenase enzyme. The transition to Haber-Bosch alternatives through robust, heterogeneous catalyst surfaces remains an unsolved research challenge. Catalysts for electrochemical reduction of di-nitrogen to ammonia are a specific focus of research, due to the potential to compete with Haber-Bosch and eliminate associated carbon dioxide emissions. However, limited progress has been made, as most electrocatalyst surfaces lack specificity towards nitrogen fixation. Lastly in this review, we discuss the progress of the field in developing a mechanistic understanding of nitrogenase-promoted and molecular catalyst-promoted ammonia synthesis and provide a review of the state-of-the-art and scientific needs for heterogeneous electrocatalysts.
- Authors:
-
[4];
- Univ. of Arkansas, Fayetteville, AR (United States). Ralph E. Martin Department of Chemical Engineering
- Case Western Reserve Univ., Cleveland, OH (United States). Department of Chemical and Biomolecular Engineering
- Pennsylvania State Univ., University Park, PA (United States). Department of Chemical Engineering
- Univ. of Utah, Salt Lake City, UT (United States). Department of Chemistry
- Publication Date:
- Research Org.:
- Univ. of Arkansas, Fayetteville, AR (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1481881
- Grant/Contract Number:
- SC0016529
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Catalysis
- Additional Journal Information:
- Journal Volume: 1; Journal Issue: 7; Journal ID: ISSN 2520-1158
- Publisher:
- Springer Nature
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Foster, Shelby L., Bakovic, Sergio I. Perez, Duda, Royce D., Maheshwari, Sharad, Milton, Ross D., Minteer, Shelley D., Janik, Michael J., Renner, Julie N., and Greenlee, Lauren F. Catalysts for nitrogen reduction to ammonia. United States: N. p., 2018.
Web. doi:10.1038/s41929-018-0092-7.
Foster, Shelby L., Bakovic, Sergio I. Perez, Duda, Royce D., Maheshwari, Sharad, Milton, Ross D., Minteer, Shelley D., Janik, Michael J., Renner, Julie N., & Greenlee, Lauren F. Catalysts for nitrogen reduction to ammonia. United States. doi:https://doi.org/10.1038/s41929-018-0092-7
Foster, Shelby L., Bakovic, Sergio I. Perez, Duda, Royce D., Maheshwari, Sharad, Milton, Ross D., Minteer, Shelley D., Janik, Michael J., Renner, Julie N., and Greenlee, Lauren F. Thu .
"Catalysts for nitrogen reduction to ammonia". United States. doi:https://doi.org/10.1038/s41929-018-0092-7. https://www.osti.gov/servlets/purl/1481881.
@article{osti_1481881,
title = {Catalysts for nitrogen reduction to ammonia},
author = {Foster, Shelby L. and Bakovic, Sergio I. Perez and Duda, Royce D. and Maheshwari, Sharad and Milton, Ross D. and Minteer, Shelley D. and Janik, Michael J. and Renner, Julie N. and Greenlee, Lauren F.},
abstractNote = {We present the production of synthetic ammonia remains dependent on the energy- and capital-intensive Haber-Bosch process. Extensive research in molecular catalysis has demonstrated ammonia production from di-nitrogen, albeit at low production rates. Mechanistic understanding of di-nitrogen reduction to ammonia continues to be delineated through study of molecular catalyst structure, as well as through understanding the naturally-occurring nitrogenase enzyme. The transition to Haber-Bosch alternatives through robust, heterogeneous catalyst surfaces remains an unsolved research challenge. Catalysts for electrochemical reduction of di-nitrogen to ammonia are a specific focus of research, due to the potential to compete with Haber-Bosch and eliminate associated carbon dioxide emissions. However, limited progress has been made, as most electrocatalyst surfaces lack specificity towards nitrogen fixation. Lastly in this review, we discuss the progress of the field in developing a mechanistic understanding of nitrogenase-promoted and molecular catalyst-promoted ammonia synthesis and provide a review of the state-of-the-art and scientific needs for heterogeneous electrocatalysts.},
doi = {10.1038/s41929-018-0092-7},
journal = {Nature Catalysis},
number = 7,
volume = 1,
place = {United States},
year = {2018},
month = {7}
}
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Works referenced in this record:
Exploring the limits: A low-pressure, low-temperature Haber–Bosch process
journal, April 2014
- Vojvodic, Aleksandra; Medford, Andrew James; Studt, Felix
- Chemical Physics Letters, Vol. 598
Localization of a Catalytic Intermediate Bound to the FeMo-cofactor of Nitrogenase
journal, June 2004
- Igarashi, Robert Y.; Dos Santos, Patricia C.; Niehaus, Walter G.
- Journal of Biological Chemistry, Vol. 279, Issue 33
The Effect of Lanthanide Oxides as a Support for Ruthenium Catalysts in Ammonia Synthesis
journal, August 1996
- Niwa, Yusuke; Aika, Ken-ichi
- Journal of Catalysis, Vol. 162, Issue 1
Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands
journal, June 2016
- Čorić, Ilija; Holland, Patrick L.
- Journal of the American Chemical Society, Vol. 138, Issue 23
Au Sub-Nanoclusters on TiO 2 toward Highly Efficient and Selective Electrocatalyst for N 2 Conversion to NH 3 at Ambient Conditions
journal, February 2017
- Shi, Miao-Miao; Bao, Di; Wulan, Ba-Ri
- Advanced Materials, Vol. 29, Issue 17
Trapping H - Bound to the Nitrogenase FeMo-Cofactor Active Site during H 2 Evolution: Characterization by ENDOR Spectroscopy
journal, May 2005
- Igarashi, Robert Y.; Laryukhin, Mikhail; Dos Santos, Patricia C.
- Journal of the American Chemical Society, Vol. 127, Issue 17
Nitrogen Fixation via a Terminal Fe(IV) Nitride
journal, October 2017
- Thompson, Niklas B.; Green, Michael T.; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 139, Issue 43
Wind to Ammonia: Electrochemical Processes in Room Temperature Ionic Liquids
conference, January 2009
- Pappenfus, Ted M.; Lee, Kyung-mee; Thoma, Laura M.
- 214th ECS Meeting, ECS Transactions
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
journal, January 2014
- Hoffman, Brian M.; Lukoyanov, Dmitriy; Yang, Zhi-Yong
- Chemical Reviews, Vol. 114, Issue 8
On the rate-determining step and the role of potassium in the catalytic synthesis of ammonia
journal, January 1992
- Spencer, M. S.
- Catalysis Letters, Vol. 13, Issue 1-2
N 2 -to-NH 3 Conversion by a triphos-Iron Catalyst and Enhanced Turnover under Photolysis
journal, May 2017
- Buscagan, Trixia M.; Oyala, Paul H.; Peters, Jonas C.
- Angewandte Chemie International Edition, Vol. 56, Issue 24
Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation
journal, April 2012
- Figg, Travis M.; Holland, Patrick L.; Cundari, Thomas R.
- Inorganic Chemistry, Vol. 51, Issue 14
Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions
journal, January 2012
- Yuki, Masahiro; Tanaka, Hiromasa; Sasaki, Kouitsu
- Nature Communications, Vol. 3, Issue 1
Electrolytic Synthesis of Ammonia in Molten Salts under Atmospheric Pressure
journal, January 2003
- Murakami, Tsuyoshi; Nishikiori, Tokujiro; Nohira, Toshiyuki
- Journal of the American Chemical Society, Vol. 125, Issue 2
Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
journal, July 2016
- Kuriyama, Shogo; Arashiba, Kazuya; Nakajima, Kazunari
- Nature Communications, Vol. 7, Issue 1
Nitrogen fixation catalyzed by ferrocene-substituted dinitrogen-bridged dimolybdenum–dinitrogen complexes: unique behavior of ferrocene moiety as redox active site
journal, January 2015
- Kuriyama, Shogo; Arashiba, Kazuya; Nakajima, Kazunari
- Chemical Science, Vol. 6, Issue 7
Ligand binding to the FeMo-cofactor: Structures of CO-bound and reactivated nitrogenase
journal, September 2014
- Spatzal, T.; Perez, K. A.; Einsle, O.
- Science, Vol. 345, Issue 6204
Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron
journal, May 2010
- Lee, Yunho; Mankad, Neal P.; Peters, Jonas C.
- Nature Chemistry, Vol. 2, Issue 7
Electron Transfer within Nitrogenase: Evidence for a Deficit-Spending Mechanism
journal, November 2011
- Danyal, Karamatullah; Dean, Dennis R.; Hoffman, Brian M.
- Biochemistry, Vol. 50, Issue 43
Theoretical Investigation on the Role of the Central Carbon Atom and Close Protein Environment on the Nitrogen Reduction in Mo Nitrogenase
journal, February 2016
- Rao, Li; Xu, Xin; Adamo, Carlo
- ACS Catalysis, Vol. 6, Issue 3
Synthesis and reactivity of iron–dinitrogen complexes bearing anionic methyl- and phenyl-substituted pyrrole-based PNP-type pincer ligands toward catalytic nitrogen fixation
journal, January 2017
- Sekiguchi, Yoshiya; Kuriyama, Shogo; Eizawa, Aya
- Chemical Communications, Vol. 53, Issue 88
Evaluating Molecular Cobalt Complexes for the Conversion of N 2 to NH 3
journal, May 2015
- Del Castillo, Trevor J.; Thompson, Niklas B.; Suess, Daniel L. M.
- Inorganic Chemistry, Vol. 54, Issue 19
Ammonia synthesis catalyst 100 years: Practice, enlightenment and challenge
journal, October 2014
- Liu, Huazhang
- Chinese Journal of Catalysis, Vol. 35, Issue 10
The importance of C7 sites and surface roughness in the ammonia synthesis reaction over iron
journal, January 1987
- Strongin, D.
- Journal of Catalysis, Vol. 103, Issue 1
Process Intensification in Ammonia Synthesis Using Novel Coassembled Supported Microporous Catalysts Promoted by Nonthermal Plasma
journal, January 2017
- Akay, Galip; Zhang, Kui
- Industrial & Engineering Chemistry Research, Vol. 56, Issue 2
Mechanistic insights into nitrogen fixation by nitrogenase enzymes
journal, January 2015
- Varley, J. B.; Wang, Y.; Chan, K.
- Physical Chemistry Chemical Physics, Vol. 17, Issue 44
Differential Effects on N 2 Binding and Reduction, HD Formation, and Azide Reduction with α-195 His - and α-191 Gln -Substituted MoFe Proteins of Azotobacter vinelandii Nitrogenase †
journal, December 2000
- Fisher, Karl; Dilworth, Michael J.; Newton, William E.
- Biochemistry, Vol. 39, Issue 50
The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry
journal, December 2014
- Bjornsson, Ragnar; Neese, Frank; Schrock, Richard R.
- JBIC Journal of Biological Inorganic Chemistry, Vol. 20, Issue 2
Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation
journal, April 2017
- Eizawa, Aya; Arashiba, Kazuya; Tanaka, Hiromasa
- Nature Communications, Vol. 8, Issue 1
Mechanism of Mo-Dependent Nitrogenase
journal, June 2009
- Seefeldt, Lance C.; Hoffman, Brian M.; Dean, Dennis R.
- Annual Review of Biochemistry, Vol. 78, Issue 1
Spectroscopic Evidence for Changes in the Redox State of the Nitrogenase P-Cluster during Turnover †
journal, May 1999
- Chan, Jeannine M.; Christiansen, Jason; Dean, Dennis R.
- Biochemistry, Vol. 38, Issue 18
Alkali Metal Control over N–N Cleavage in Iron Complexes
journal, November 2014
- Grubel, Katarzyna; Brennessel, William W.; Mercado, Brandon Q.
- Journal of the American Chemical Society, Vol. 136, Issue 48
A Multi-iron System Capable of Rapid N 2 Formation and N 2 Cleavage
journal, July 2014
- MacLeod, K. Cory; Vinyard, David J.; Holland, Patrick L.
- Journal of the American Chemical Society, Vol. 136, Issue 29
Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand
journal, June 2014
- Kuriyama, Shogo; Arashiba, Kazuya; Nakajima, Kazunari
- Journal of the American Chemical Society, Vol. 136, Issue 27
Identification of a spin-coupled Mo( iii ) in the nitrogenase iron–molybdenum cofactor
journal, January 2014
- Bjornsson, Ragnar; Lima, Frederico A.; Spatzal, Thomas
- Chem. Sci., Vol. 5, Issue 8
Graphitic Nanofilaments as Novel Support of Ru–Ba Catalysts for Ammonia Synthesis
journal, October 2002
- Liang, C.
- Journal of Catalysis, Vol. 211, Issue 1
Ammonia Synthesis Catalyzed by Ruthenium Supported on Basic Zeolites
journal, September 1996
- Fishel, Christopher T.; Davis, Robert J.; Garces, Juan M.
- Journal of Catalysis, Vol. 163, Issue 1
A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57 Fe Mössbauer Data, and a Hydride Resting State
journal, January 2016
- Del Castillo, Trevor J.; Thompson, Niklas B.; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 138, Issue 16
Challenges in reduction of dinitrogen by proton and electron transfer
journal, January 2014
- van der Ham, Cornelis J. M.; Koper, Marc T. M.; Hetterscheid, Dennis G. H.
- Chem. Soc. Rev., Vol. 43, Issue 15
Alkyne substrate interaction within the nitrogenase MoFe protein
journal, November 2007
- Dos Santos, Patricia C.; Mayer, Suzanne M.; Barney, Brett M.
- Journal of Inorganic Biochemistry, Vol. 101, Issue 11-12
Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes
journal, June 2017
- Wickramasinghe, Lasantha A.; Ogawa, Takaya; Schrock, Richard R.
- Journal of the American Chemical Society, Vol. 139, Issue 27
A theoretical evaluation of possible transition metal electro-catalysts for N 2 reduction
journal, January 2012
- Skúlason, Egill; Bligaard, Thomas; Gudmundsdóttir, Sigrídur
- Phys. Chem. Chem. Phys., Vol. 14, Issue 3
Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron
journal, May 2013
- MacLeod, K. Cory; Holland, Patrick L.
- Nature Chemistry, Vol. 5, Issue 7
Ru-Loaded C12A7:e – Electride as a Catalyst for Ammonia Synthesis
journal, February 2017
- Hara, Michikazu; Kitano, Masaaki; Hosono, Hideo
- ACS Catalysis, Vol. 7, Issue 4
Low temperature ruthenium catalyst for ammonia synthesis supported on BaCeO3 nanocrystals
journal, May 2010
- Yang, Xiao-Long; Zhang, Wei-Qiang; Xia, Chun-Gu
- Catalysis Communications, Vol. 11, Issue 10
Bioelectrochemical Haber-Bosch Process: An Ammonia-Producing H 2 /N 2 Fuel Cell
journal, February 2017
- Milton, Ross D.; Cai, Rong; Abdellaoui, Sofiene
- Angewandte Chemie International Edition, Vol. 56, Issue 10
Catalytic Reduction of N 2 to NH 3 by an Fe–N 2 Complex Featuring a C-Atom Anchor
journal, January 2014
- Creutz, Sidney E.; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 136, Issue 3
Support effects on the catalytic activity and selectivity of ruthenium in CO and N2 activation
journal, January 1982
- Bossi, Alessandro; Garbassi, Fabio; Petrini, Guido
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 78, Issue 4
Investigation of N2-fixation on polyaniline electrodes in methanol by electrochemical impedance spectroscopy
journal, December 2010
- Köleli, Fatih; Röpke, Derya; Aydin, Rezzan
- Journal of Applied Electrochemistry, Vol. 41, Issue 4
Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride
journal, October 2015
- Arnet, Nicholas A.; Dugan, Thomas R.; Menges, Fabian S.
- Journal of the American Chemical Society, Vol. 137, Issue 41
Studies of Low-Coordinate Iron Dinitrogen Complexes
journal, January 2006
- Smith, Jeremy M.; Sadique, Azwana R.; Cundari, Thomas R.
- Journal of the American Chemical Society, Vol. 128, Issue 3
N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex
journal, November 2011
- Rodriguez, M. M.; Bill, E.; Brennessel, W. W.
- Science, Vol. 334, Issue 6057
Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment
journal, June 2008
- Schrock, Richard R.
- Angewandte Chemie International Edition, Vol. 47, Issue 30
Surface characterization of ammonia synthesis catalysts
journal, February 1983
- Ertl, G.
- Journal of Catalysis, Vol. 79, Issue 2
Dinitrogen Activation by Group 4 Metal Complexes
journal, April 2007
- Ohki, Yasuhiro; Fryzuk, Michael D.
- Angewandte Chemie International Edition, Vol. 46, Issue 18
Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes
journal, March 2016
- McWilliams, Sean F.; Rodgers, Kenton R.; Lukat-Rodgers, Gudrun
- Inorganic Chemistry, Vol. 55, Issue 6
From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis
journal, August 2015
- Medford, Andrew J.; Vojvodic, Aleksandra; Hummelshøj, Jens S.
- Journal of Catalysis, Vol. 328
Ruthenium catalysts for ammonia synthesis at high pressures: Preparation, characterization, and power-law kinetics
journal, April 1997
- Rosowski, F.; Hornung, A.; Hinrichsen, O.
- Applied Catalysis A: General, Vol. 151, Issue 2
The controlled relay of multiple protons required at the active site of nitrogenase
journal, January 2012
- Dance, Ian
- Dalton Transactions, Vol. 41, Issue 25
Molybdenum Triamidoamine Complexes that Contain Hexa- tert -butylterphenyl, Hexamethylterphenyl, or p -Bromohexaisopropylterphenyl Substituents. An Examination of Some Catalyst Variations for the Catalytic Reduction of Dinitrogen
journal, May 2004
- Ritleng, Vincent; Yandulov, Dmitry V.; Weare, Walter W.
- Journal of the American Chemical Society, Vol. 126, Issue 19
Calculated details of a mechanism for conversion of N2 to NH3 at the FeMo cluster of nitrogenase
journal, January 1997
- Dance, Ian
- Chemical Communications, Issue 2
Evidence That the P i Release Event Is the Rate-Limiting Step in the Nitrogenase Catalytic Cycle
journal, June 2016
- Yang, Zhi-Yong; Ledbetter, Rhesa; Shaw, Sudipta
- Biochemistry, Vol. 55, Issue 26
Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes
journal, November 2017
- Fajardo, Javier; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 139, Issue 45
Boron Nitride: A Novel Support for Ruthenium-Based Ammonia Synthesis Catalysts
journal, May 2001
- Jacobsen, Claus J. H.
- Journal of Catalysis, Vol. 200, Issue 1
Electrochemical Synthesis of NH 3 at Low Temperature and Atmospheric Pressure Using a γ-Fe 2 O 3 Catalyst
journal, October 2017
- Kong, Jimin; Lim, Ahyoun; Yoon, Changwon
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 11
Synergistic Effect of MgO and CeO2 as a Support for Ruthenium Catalysts in Ammonia Synthesis
journal, February 2006
- Saito, Makoto; Itoh, Masahiro; Iwamoto, Jun
- Catalysis Letters, Vol. 106, Issue 3-4
Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands
journal, August 2016
- Kuriyama, Shogo; Arashiba, Kazuya; Tanaka, Hiromasa
- Angewandte Chemie International Edition, Vol. 55, Issue 46
Electrochemical Nitrogen Reduction Reaction on Noble Metal Catalysts in Proton and Hydroxide Exchange Membrane Electrolyzers
journal, January 2017
- Nash, Jared; Yang, Xuan; Anibal, Jacob
- Journal of The Electrochemical Society, Vol. 164, Issue 14
Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids
journal, January 2017
- Zhou, Fengling; Azofra, Luis Miguel; Ali, Muataz
- Energy & Environmental Science, Vol. 10, Issue 12
Catalytic N 2 -to-NH 3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET
journal, February 2017
- Chalkley, Matthew J.; Del Castillo, Trevor J.; Matson, Benjamin D.
- ACS Central Science, Vol. 3, Issue 3
On the feasibility of N2 fixation via a single-site FeI/FeIV cycle: Spectroscopic studies of FeI(N2)FeI, FeIVN, and related species
journal, November 2006
- Hendrich, M. P.; Gunderson, W.; Behan, R. K.
- Proceedings of the National Academy of Sciences, Vol. 103, Issue 46
Uncoupling Nitrogenase: Catalytic Reduction of Hydrazine to Ammonia by a MoFe Protein in the Absence of Fe Protein-ATP
journal, September 2010
- Danyal, Karamatullah; Inglet, Boyd S.; Vincent, Kylie A.
- Journal of the American Chemical Society, Vol. 132, Issue 38
Nitrogenase bioelectrocatalysis: heterogeneous ammonia and hydrogen production by MoFe protein
journal, January 2016
- Milton, Ross D.; Abdellaoui, Sofiene; Khadka, Nimesh
- Energy & Environmental Science, Vol. 9, Issue 8
Research inspired by the chemistry of nitrogenase — Novel metal complexes and their reactivity toward dinitrogen, nitriles, and alkynes
journal, April 2005
- Hidai, Masanobu; Mizobe, Yasushi
- Canadian Journal of Chemistry, Vol. 83, Issue 4
Coadsorption of oxygen and hydrogen on ruthenium(001): blocking and electronic effects of preadsorbed oxygen
journal, November 1986
- Hrbek, J.
- The Journal of Physical Chemistry, Vol. 90, Issue 23
Selective Catalytic Reduction of N 2 to N 2 H 4 by a Simple Fe Complex
journal, October 2016
- Hill, Peter J.; Doyle, Laurence R.; Crawford, Andrew D.
- Journal of the American Chemical Society, Vol. 138, Issue 41
The Kinetics of Ammonia Synthesis over Ruthenium-Based Catalysts: The Role of Barium and Cesium
journal, January 2002
- Szmigiel, Dariusz; Bielawa, Hubert; Kurtz, Melanie
- Journal of Catalysis, Vol. 205, Issue 1
Multimetallic cooperativity in activation of dinitrogen at iron–potassium sites
journal, January 2014
- Chiang, Karen P.; Bellows, Sarina M.; Brennessel, William W.
- Chem. Sci., Vol. 5, Issue 1
Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation
journal, January 2018
- Higuchi, Junichi; Kuriyama, Shogo; Eizawa, Aya
- Dalton Transactions, Vol. 47, Issue 4
Electron transfer in nitrogenase catalysis
journal, April 2012
- Seefeldt, Lance C.; Hoffman, Brian M.; Dean, Dennis R.
- Current Opinion in Chemical Biology, Vol. 16, Issue 1-2
Binding of dinitrogen to an iron–sulfur–carbon site
journal, September 2015
- Čorić, Ilija; Mercado, Brandon Q.; Bill, Eckhard
- Nature, Vol. 526, Issue 7571
Role for the nitrogenase MoFe protein α-subunit in FeMo-cofactor binding and catalysis
journal, January 1990
- Scott, Deborah J.; May, Harold D.; Newton, William E.
- Nature, Vol. 343, Issue 6254
Role of the MoFe Protein .alpha.-Subunit Histidine-195 Residue in FeMo-cofactor Binding and Nitrogenase Catalysis
journal, March 1995
- Kim, Chul-Hwan; Newton, William E.; Dean, Dennis R.
- Biochemistry, Vol. 34, Issue 9
Nitrogenase of Klebsiella pneumoniae. Kinetics of the dissociation of oxidized iron protein from molybdenum-iron protein: identification of the rate-limiting step for substrate reduction
journal, November 1983
- Thorneley, R. N. F.; Lowe, D. J.
- Biochemical Journal, Vol. 215, Issue 2
Evidence for a dynamic role for homocitrate during nitrogen fixation: the effect of substitution at the α-Lys426 position in MoFe-protein of Azotobacter vinelandii
journal, June 2006
- Durrant, Marcus C.; Francis, Amanda; Lowe, David J.
- Biochemical Journal, Vol. 397, Issue 2
Catalytic Reduction of Dinitrogen to Ammonia by Use of Molybdenum–Nitride Complexes Bearing a Tridentate Triphosphine as Catalysts
journal, April 2015
- Arashiba, Kazuya; Kinoshita, Eriko; Kuriyama, Shogo
- Journal of the American Chemical Society, Vol. 137, Issue 17
The Challenge of Electrochemical Ammonia Synthesis: A New Perspective on the Role of Nitrogen Scaling Relations
journal, June 2015
- Montoya, Joseph H.; Tsai, Charlie; Vojvodic, Aleksandra
- ChemSusChem, Vol. 8, Issue 13
Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes
journal, June 2015
- McWilliams, Sean F.; Holland, Patrick L.
- Accounts of Chemical Research, Vol. 48, Issue 7
Universal transition state scaling relations for (de)hydrogenation over transition metals
journal, January 2011
- Wang, S.; Petzold, V.; Tripkovic, V.
- Physical Chemistry Chemical Physics, Vol. 13, Issue 46
The Genesis and Development of the Commercial BP Doubly Promoted Catalyst for Ammonia Synthesis
journal, March 2014
- Brown, David E.; Edmonds, Terry; Joyner, Richard W.
- Catalysis Letters, Vol. 144, Issue 4
57 Fe ENDOR Spectroscopy and ‘Electron Inventory’ Analysis of the Nitrogenase E 4 Intermediate Suggest the Metal-Ion Core of FeMo-Cofactor Cycles Through Only One Redox Couple
journal, November 2011
- Doan, Peter E.; Telser, Joshua; Barney, Brett M.
- Journal of the American Chemical Society, Vol. 133, Issue 43
Functionalization and cleavage of coordinated dinitrogen via hydroboration using primary and secondary boranes
journal, April 2005
- MacKay, Bruce A.; Johnson, Samuel A.; Patrick, Brian O.
- Canadian Journal of Chemistry, Vol. 83, Issue 4
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
journal, July 2003
- Yandulov, D. V.
- Science, Vol. 301, Issue 5629
Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor
journal, November 2011
- Spatzal, T.; Aksoyoglu, M.; Zhang, L.
- Science, Vol. 334, Issue 6058
Support and promoter effect of ruthenium catalyst I. Characterization of alkali-promoted ruthenium/alumina catalysts for ammonia synthesis
journal, April 1985
- Aika, K.
- Journal of Catalysis, Vol. 92, Issue 2
Catalytic Nitrogen Fixation via Direct Cleavage of Nitrogen–Nitrogen Triple Bond of Molecular Dinitrogen under Ambient Reaction Conditions
journal, October 2017
- Arashiba, Kazuya; Eizawa, Aya; Tanaka, Hiromasa
- Bulletin of the Chemical Society of Japan, Vol. 90, Issue 10
Ammonia synthesis by N2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2O3
journal, August 2014
- Licht, S.; Cui, B.; Wang, B.
- Science, Vol. 345, Issue 6197
Substrate Interaction at an Iron-Sulfur Face of the FeMo-cofactor during Nitrogenase Catalysis
journal, October 2004
- Barney, Brett M.; Igarashi, Robert Y.; Dos Santos, Patricia C.
- Journal of Biological Chemistry, Vol. 279, Issue 51
The hydride route to the preparation of dinitrogen complexes
journal, January 2010
- Ballmann, Joachim; Munhá, Rui F.; Fryzuk, Michael D.
- Chemical Communications, Vol. 46, Issue 7
Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia
journal, April 2014
- Tanaka, Hiromasa; Arashiba, Kazuya; Kuriyama, Shogo
- Nature Communications, Vol. 5, Issue 1
Room-Temperature Electrocatalytic Synthesis of NH 3 from H 2 O and N 2 in a Gas–Liquid–Solid Three-Phase Reactor
journal, July 2017
- Chen, Shiming; Perathoner, Siglinda; Ampelli, Claudio
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 8
Bioelectrochemical Haber-Bosch Process: An Ammonia-Producing H 2 /N 2 Fuel Cell
journal, February 2017
- Milton, Ross D.; Cai, Rong; Abdellaoui, Sofiene
- Angewandte Chemie, Vol. 129, Issue 10
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
journal, December 2005
- Schrock, Richard R.
- Accounts of Chemical Research, Vol. 38, Issue 12
Works referencing / citing this record:
Metal-Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen
journal, December 2018
- Schendzielorz, Florian; Finger, Markus; Abbenseth, Josh
- Angewandte Chemie International Edition, Vol. 58, Issue 3
Bimetallic Cooperative Cleavage of Dinitrogen to Nitride and Tandem Frustrated Lewis Pair Hydrogenation to Ammonia
journal, April 2019
- Doyle, Laurence R.; Wooles, Ashley J.; Liddle, Stephen T.
- Angewandte Chemie International Edition, Vol. 58, Issue 20
Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(v)–dinitrogen complex
journal, August 2019
- Lu, Erli; Atkinson, Benjamin E.; Wooles, Ashley J.
- Nature Chemistry, Vol. 11, Issue 9
Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage
journal, January 2019
- Toda, Tatsuro; Suzuki, Satoshi; Kuwata, Shigeki
- Chemical Communications, Vol. 55, Issue 8
Au Sub-Nanoclusters on TiO 2 toward Highly Efficient and Selective Electrocatalyst for N 2 Conversion to NH 3 at Ambient Conditions
journal, February 2017
- Shi, Miao-Miao; Bao, Di; Wulan, Ba-Ri
- Advanced Materials, Vol. 29, Issue 17
Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum: Theory versus Experiment
journal, June 2008
- Schrock, Richard R.
- Angewandte Chemie International Edition, Vol. 47, Issue 30
Direct Transformation of Molecular Dinitrogen into Ammonia Catalyzed by Cobalt Dinitrogen Complexes Bearing Anionic PNP Pincer Ligands
journal, August 2016
- Kuriyama, Shogo; Arashiba, Kazuya; Tanaka, Hiromasa
- Angewandte Chemie International Edition, Vol. 55, Issue 46
Bioelectrochemical Haber-Bosch Process: An Ammonia-Producing H 2 /N 2 Fuel Cell
journal, February 2017
- Milton, Ross D.; Cai, Rong; Abdellaoui, Sofiene
- Angewandte Chemie International Edition, Vol. 56, Issue 10
N 2 -to-NH 3 Conversion by a triphos-Iron Catalyst and Enhanced Turnover under Photolysis
journal, May 2017
- Buscagan, Trixia M.; Oyala, Paul H.; Peters, Jonas C.
- Angewandte Chemie International Edition, Vol. 56, Issue 24
Controlled Incorporation of Nitrides into W-Fe-S Clusters
journal, September 2019
- Xu, Gan; Zhou, Jie; Wang, Zheng
- Angewandte Chemie International Edition, Vol. 58, Issue 46
The Challenge of Electrochemical Ammonia Synthesis: A New Perspective on the Role of Nitrogen Scaling Relations
journal, June 2015
- Montoya, Joseph H.; Tsai, Charlie; Vojvodic, Aleksandra
- ChemSusChem, Vol. 8, Issue 13
The Effect of Lanthanide Oxides as a Support for Ruthenium Catalysts in Ammonia Synthesis
journal, August 1996
- Niwa, Yusuke; Aika, Ken-ichi
- Journal of Catalysis, Vol. 162, Issue 1
Ammonia Synthesis Catalyzed by Ruthenium Supported on Basic Zeolites
journal, September 1996
- Fishel, Christopher T.; Davis, Robert J.; Garces, Juan M.
- Journal of Catalysis, Vol. 163, Issue 1
Boron Nitride: A Novel Support for Ruthenium-Based Ammonia Synthesis Catalysts
journal, May 2001
- Jacobsen, Claus J. H.
- Journal of Catalysis, Vol. 200, Issue 1
The Kinetics of Ammonia Synthesis over Ruthenium-Based Catalysts: The Role of Barium and Cesium
journal, January 2002
- Szmigiel, Dariusz; Bielawa, Hubert; Kurtz, Melanie
- Journal of Catalysis, Vol. 205, Issue 1
On the rate-determining step and the role of potassium in the catalytic synthesis of ammonia
journal, January 1992
- Spencer, M. S.
- Catalysis Letters, Vol. 13, Issue 1-2
The discovery of Mo(III) in FeMoco: reuniting enzyme and model chemistry
journal, December 2014
- Bjornsson, Ragnar; Neese, Frank; Schrock, Richard R.
- JBIC Journal of Biological Inorganic Chemistry, Vol. 20, Issue 2
The Genesis and Development of the Commercial BP Doubly Promoted Catalyst for Ammonia Synthesis
journal, March 2014
- Brown, David E.; Edmonds, Terry; Joyner, Richard W.
- Catalysis Letters, Vol. 144, Issue 4
Investigation of N2-fixation on polyaniline electrodes in methanol by electrochemical impedance spectroscopy
journal, December 2010
- Köleli, Fatih; Röpke, Derya; Aydin, Rezzan
- Journal of Applied Electrochemistry, Vol. 41, Issue 4
Surface characterization of ammonia synthesis catalysts
journal, February 1983
- Ertl, G.
- Journal of Catalysis, Vol. 79, Issue 2
Support and promoter effect of ruthenium catalyst I. Characterization of alkali-promoted ruthenium/alumina catalysts for ammonia synthesis
journal, April 1985
- Aika, K.
- Journal of Catalysis, Vol. 92, Issue 2
The importance of C7 sites and surface roughness in the ammonia synthesis reaction over iron
journal, January 1987
- Strongin, D.
- Journal of Catalysis, Vol. 103, Issue 1
Low temperature ruthenium catalyst for ammonia synthesis supported on BaCeO3 nanocrystals
journal, May 2010
- Yang, Xiao-Long; Zhang, Wei-Qiang; Xia, Chun-Gu
- Catalysis Communications, Vol. 11, Issue 10
Electron transfer in nitrogenase catalysis
journal, April 2012
- Seefeldt, Lance C.; Hoffman, Brian M.; Dean, Dennis R.
- Current Opinion in Chemical Biology, Vol. 16, Issue 1-2
Exploring the limits: A low-pressure, low-temperature Haber–Bosch process
journal, April 2014
- Vojvodic, Aleksandra; Medford, Andrew James; Studt, Felix
- Chemical Physics Letters, Vol. 598
From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis
journal, August 2015
- Medford, Andrew J.; Vojvodic, Aleksandra; Hummelshøj, Jens S.
- Journal of Catalysis, Vol. 328
Alkyne substrate interaction within the nitrogenase MoFe protein
journal, November 2007
- Dos Santos, Patricia C.; Mayer, Suzanne M.; Barney, Brett M.
- Journal of Inorganic Biochemistry, Vol. 101, Issue 11-12
Graphitic Nanofilaments as Novel Support of Ru–Ba Catalysts for Ammonia Synthesis
journal, October 2002
- Liang, C.
- Journal of Catalysis, Vol. 211, Issue 1
Ruthenium catalysts for ammonia synthesis at high pressures: Preparation, characterization, and power-law kinetics
journal, April 1997
- Rosowski, F.; Hornung, A.; Hinrichsen, O.
- Applied Catalysis A: General, Vol. 151, Issue 2
Ammonia synthesis catalyst 100 years: Practice, enlightenment and challenge
journal, October 2014
- Liu, Huazhang
- Chinese Journal of Catalysis, Vol. 35, Issue 10
Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes
journal, June 2015
- McWilliams, Sean F.; Holland, Patrick L.
- Accounts of Chemical Research, Vol. 48, Issue 7
Evidence That the P i Release Event Is the Rate-Limiting Step in the Nitrogenase Catalytic Cycle
journal, June 2016
- Yang, Zhi-Yong; Ledbetter, Rhesa; Shaw, Sudipta
- Biochemistry, Vol. 55, Issue 26
Process Intensification in Ammonia Synthesis Using Novel Coassembled Supported Microporous Catalysts Promoted by Nonthermal Plasma
journal, January 2017
- Akay, Galip; Zhang, Kui
- Industrial & Engineering Chemistry Research, Vol. 56, Issue 2
Evaluating Molecular Cobalt Complexes for the Conversion of N 2 to NH 3
journal, May 2015
- Del Castillo, Trevor J.; Thompson, Niklas B.; Suess, Daniel L. M.
- Inorganic Chemistry, Vol. 54, Issue 19
Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes
journal, March 2016
- McWilliams, Sean F.; Rodgers, Kenton R.; Lukat-Rodgers, Gudrun
- Inorganic Chemistry, Vol. 55, Issue 6
Theoretical Investigation on the Role of the Central Carbon Atom and Close Protein Environment on the Nitrogen Reduction in Mo Nitrogenase
journal, February 2016
- Rao, Li; Xu, Xin; Adamo, Carlo
- ACS Catalysis, Vol. 6, Issue 3
Ru-Loaded C12A7:e – Electride as a Catalyst for Ammonia Synthesis
journal, February 2017
- Hara, Michikazu; Kitano, Masaaki; Hosono, Hideo
- ACS Catalysis, Vol. 7, Issue 4
Catalytic N 2 -to-NH 3 Conversion by Fe at Lower Driving Force: A Proposed Role for Metallocene-Mediated PCET
journal, February 2017
- Chalkley, Matthew J.; Del Castillo, Trevor J.; Matson, Benjamin D.
- ACS Central Science, Vol. 3, Issue 3
Room-Temperature Electrocatalytic Synthesis of NH 3 from H 2 O and N 2 in a Gas–Liquid–Solid Three-Phase Reactor
journal, July 2017
- Chen, Shiming; Perathoner, Siglinda; Ampelli, Claudio
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 8
Electrochemical Synthesis of NH 3 at Low Temperature and Atmospheric Pressure Using a γ-Fe 2 O 3 Catalyst
journal, October 2017
- Kong, Jimin; Lim, Ahyoun; Yoon, Changwon
- ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 11
Role of the MoFe Protein .alpha.-Subunit Histidine-195 Residue in FeMo-cofactor Binding and Nitrogenase Catalysis
journal, March 1995
- Kim, Chul-Hwan; Newton, William E.; Dean, Dennis R.
- Biochemistry, Vol. 34, Issue 9
Differential Effects on N 2 Binding and Reduction, HD Formation, and Azide Reduction with α-195 His - and α-191 Gln -Substituted MoFe Proteins of Azotobacter vinelandii Nitrogenase †
journal, December 2000
- Fisher, Karl; Dilworth, Michael J.; Newton, William E.
- Biochemistry, Vol. 39, Issue 50
Electron Transfer within Nitrogenase: Evidence for a Deficit-Spending Mechanism
journal, November 2011
- Danyal, Karamatullah; Dean, Dennis R.; Hoffman, Brian M.
- Biochemistry, Vol. 50, Issue 43
Spectroscopic Evidence for Changes in the Redox State of the Nitrogenase P-Cluster during Turnover †
journal, May 1999
- Chan, Jeannine M.; Christiansen, Jason; Dean, Dennis R.
- Biochemistry, Vol. 38, Issue 18
Mechanism of Nitrogen Fixation by Nitrogenase: The Next Stage
journal, January 2014
- Hoffman, Brian M.; Lukoyanov, Dmitriy; Yang, Zhi-Yong
- Chemical Reviews, Vol. 114, Issue 8
Cooperativity Between Low-Valent Iron and Potassium Promoters in Dinitrogen Fixation
journal, April 2012
- Figg, Travis M.; Holland, Patrick L.; Cundari, Thomas R.
- Inorganic Chemistry, Vol. 51, Issue 14
Coadsorption of oxygen and hydrogen on ruthenium(001): blocking and electronic effects of preadsorbed oxygen
journal, November 1986
- Hrbek, J.
- The Journal of Physical Chemistry, Vol. 90, Issue 23
Electrolytic Synthesis of Ammonia in Molten Salts under Atmospheric Pressure
journal, January 2003
- Murakami, Tsuyoshi; Nishikiori, Tokujiro; Nohira, Toshiyuki
- Journal of the American Chemical Society, Vol. 125, Issue 2
Molybdenum Triamidoamine Complexes that Contain Hexa- tert -butylterphenyl, Hexamethylterphenyl, or p -Bromohexaisopropylterphenyl Substituents. An Examination of Some Catalyst Variations for the Catalytic Reduction of Dinitrogen
journal, May 2004
- Ritleng, Vincent; Yandulov, Dmitry V.; Weare, Walter W.
- Journal of the American Chemical Society, Vol. 126, Issue 19
Trapping H - Bound to the Nitrogenase FeMo-Cofactor Active Site during H 2 Evolution: Characterization by ENDOR Spectroscopy
journal, May 2005
- Igarashi, Robert Y.; Laryukhin, Mikhail; Dos Santos, Patricia C.
- Journal of the American Chemical Society, Vol. 127, Issue 17
Studies of Low-Coordinate Iron Dinitrogen Complexes
journal, January 2006
- Smith, Jeremy M.; Sadique, Azwana R.; Cundari, Thomas R.
- Journal of the American Chemical Society, Vol. 128, Issue 3
Uncoupling Nitrogenase: Catalytic Reduction of Hydrazine to Ammonia by a MoFe Protein in the Absence of Fe Protein-ATP
journal, September 2010
- Danyal, Karamatullah; Inglet, Boyd S.; Vincent, Kylie A.
- Journal of the American Chemical Society, Vol. 132, Issue 38
57 Fe ENDOR Spectroscopy and ‘Electron Inventory’ Analysis of the Nitrogenase E 4 Intermediate Suggest the Metal-Ion Core of FeMo-Cofactor Cycles Through Only One Redox Couple
journal, November 2011
- Doan, Peter E.; Telser, Joshua; Barney, Brett M.
- Journal of the American Chemical Society, Vol. 133, Issue 43
Catalytic Reduction of N 2 to NH 3 by an Fe–N 2 Complex Featuring a C-Atom Anchor
journal, January 2014
- Creutz, Sidney E.; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 136, Issue 3
Catalytic Formation of Ammonia from Molecular Dinitrogen by Use of Dinitrogen-Bridged Dimolybdenum–Dinitrogen Complexes Bearing PNP-Pincer Ligands: Remarkable Effect of Substituent at PNP-Pincer Ligand
journal, June 2014
- Kuriyama, Shogo; Arashiba, Kazuya; Nakajima, Kazunari
- Journal of the American Chemical Society, Vol. 136, Issue 27
A Multi-iron System Capable of Rapid N 2 Formation and N 2 Cleavage
journal, July 2014
- MacLeod, K. Cory; Vinyard, David J.; Holland, Patrick L.
- Journal of the American Chemical Society, Vol. 136, Issue 29
Alkali Metal Control over N–N Cleavage in Iron Complexes
journal, November 2014
- Grubel, Katarzyna; Brennessel, William W.; Mercado, Brandon Q.
- Journal of the American Chemical Society, Vol. 136, Issue 48
Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride
journal, October 2015
- Arnet, Nicholas A.; Dugan, Thomas R.; Menges, Fabian S.
- Journal of the American Chemical Society, Vol. 137, Issue 41
Insight into the Iron–Molybdenum Cofactor of Nitrogenase from Synthetic Iron Complexes with Sulfur, Carbon, and Hydride Ligands
journal, June 2016
- Čorić, Ilija; Holland, Patrick L.
- Journal of the American Chemical Society, Vol. 138, Issue 23
A Synthetic Single-Site Fe Nitrogenase: High Turnover, Freeze-Quench 57 Fe Mössbauer Data, and a Hydride Resting State
journal, January 2016
- Del Castillo, Trevor J.; Thompson, Niklas B.; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 138, Issue 16
Selective Catalytic Reduction of N 2 to N 2 H 4 by a Simple Fe Complex
journal, October 2016
- Hill, Peter J.; Doyle, Laurence R.; Crawford, Andrew D.
- Journal of the American Chemical Society, Vol. 138, Issue 41
Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes
journal, June 2017
- Wickramasinghe, Lasantha A.; Ogawa, Takaya; Schrock, Richard R.
- Journal of the American Chemical Society, Vol. 139, Issue 27
Nitrogen Fixation via a Terminal Fe(IV) Nitride
journal, October 2017
- Thompson, Niklas B.; Green, Michael T.; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 139, Issue 43
Catalytic Nitrogen-to-Ammonia Conversion by Osmium and Ruthenium Complexes
journal, November 2017
- Fajardo, Javier; Peters, Jonas C.
- Journal of the American Chemical Society, Vol. 139, Issue 45
Role for the nitrogenase MoFe protein α-subunit in FeMo-cofactor binding and catalysis
journal, January 1990
- Scott, Deborah J.; May, Harold D.; Newton, William E.
- Nature, Vol. 343, Issue 6254
Binding of dinitrogen to an iron–sulfur–carbon site
journal, September 2015
- Čorić, Ilija; Mercado, Brandon Q.; Bill, Eckhard
- Nature, Vol. 526, Issue 7571
Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron
journal, May 2013
- MacLeod, K. Cory; Holland, Patrick L.
- Nature Chemistry, Vol. 5, Issue 7
Triggering N2 uptake via redox-induced expulsion of coordinated NH3 and N2 silylation at trigonal bipyramidal iron
journal, May 2010
- Lee, Yunho; Mankad, Neal P.; Peters, Jonas C.
- Nature Chemistry, Vol. 2, Issue 7
Catalytic transformation of dinitrogen into ammonia and hydrazine by iron-dinitrogen complexes bearing pincer ligand
journal, July 2016
- Kuriyama, Shogo; Arashiba, Kazuya; Nakajima, Kazunari
- Nature Communications, Vol. 7, Issue 1
Iron-catalysed transformation of molecular dinitrogen into silylamine under ambient conditions
journal, January 2012
- Yuki, Masahiro; Tanaka, Hiromasa; Sasaki, Kouitsu
- Nature Communications, Vol. 3, Issue 1
Unique behaviour of dinitrogen-bridged dimolybdenum complexes bearing pincer ligand towards catalytic formation of ammonia
journal, April 2014
- Tanaka, Hiromasa; Arashiba, Kazuya; Kuriyama, Shogo
- Nature Communications, Vol. 5, Issue 1
The hydride route to the preparation of dinitrogen complexes
journal, January 2010
- Ballmann, Joachim; Munhá, Rui F.; Fryzuk, Michael D.
- Chemical Communications, Vol. 46, Issue 7
Universal transition state scaling relations for (de)hydrogenation over transition metals
journal, January 2011
- Wang, S.; Petzold, V.; Tripkovic, V.
- Physical Chemistry Chemical Physics, Vol. 13, Issue 46
The controlled relay of multiple protons required at the active site of nitrogenase
journal, January 2012
- Dance, Ian
- Dalton Transactions, Vol. 41, Issue 25
Multimetallic cooperativity in activation of dinitrogen at iron–potassium sites
journal, January 2014
- Chiang, Karen P.; Bellows, Sarina M.; Brennessel, William W.
- Chem. Sci., Vol. 5, Issue 1
Challenges in reduction of dinitrogen by proton and electron transfer
journal, January 2014
- van der Ham, Cornelis J. M.; Koper, Marc T. M.; Hetterscheid, Dennis G. H.
- Chem. Soc. Rev., Vol. 43, Issue 15
Identification of a spin-coupled Mo( iii ) in the nitrogenase iron–molybdenum cofactor
journal, January 2014
- Bjornsson, Ragnar; Lima, Frederico A.; Spatzal, Thomas
- Chem. Sci., Vol. 5, Issue 8
Nitrogenase bioelectrocatalysis: heterogeneous ammonia and hydrogen production by MoFe protein
journal, January 2016
- Milton, Ross D.; Abdellaoui, Sofiene; Khadka, Nimesh
- Energy & Environmental Science, Vol. 9, Issue 8
Synthesis and reactivity of iron–dinitrogen complexes bearing anionic methyl- and phenyl-substituted pyrrole-based PNP-type pincer ligands toward catalytic nitrogen fixation
journal, January 2017
- Sekiguchi, Yoshiya; Kuriyama, Shogo; Eizawa, Aya
- Chemical Communications, Vol. 53, Issue 88
Preparation and reactivity of iron complexes bearing anionic carbazole-based PNP-type pincer ligands toward catalytic nitrogen fixation
journal, January 2018
- Higuchi, Junichi; Kuriyama, Shogo; Eizawa, Aya
- Dalton Transactions, Vol. 47, Issue 4
Electro-synthesis of ammonia from nitrogen at ambient temperature and pressure in ionic liquids
journal, January 2017
- Zhou, Fengling; Azofra, Luis Miguel; Ali, Muataz
- Energy & Environmental Science, Vol. 10, Issue 12
Support effects on the catalytic activity and selectivity of ruthenium in CO and N2 activation
journal, January 1982
- Bossi, Alessandro; Garbassi, Fabio; Petrini, Guido
- Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 78, Issue 4
Evidence for a dynamic role for homocitrate during nitrogen fixation: the effect of substitution at the α-Lys426 position in MoFe-protein of Azotobacter vinelandii
journal, June 2006
- Durrant, Marcus C.; Francis, Amanda; Lowe, David J.
- Biochemical Journal, Vol. 397, Issue 2
Nitrogenase of Klebsiella pneumoniae. Kinetics of the dissociation of oxidized iron protein from molybdenum-iron protein: identification of the rate-limiting step for substrate reduction
journal, November 1983
- Thorneley, R. N. F.; Lowe, D. J.
- Biochemical Journal, Vol. 215, Issue 2
Localization of a Catalytic Intermediate Bound to the FeMo-cofactor of Nitrogenase
journal, June 2004
- Igarashi, Robert Y.; Dos Santos, Patricia C.; Niehaus, Walter G.
- Journal of Biological Chemistry, Vol. 279, Issue 33
Substrate Interaction at an Iron-Sulfur Face of the FeMo-cofactor during Nitrogenase Catalysis
journal, October 2004
- Barney, Brett M.; Igarashi, Robert Y.; Dos Santos, Patricia C.
- Journal of Biological Chemistry, Vol. 279, Issue 51
Catalytic Reduction of Dinitrogen to Ammonia at a Single Molybdenum Center
journal, July 2003
- Yandulov, D. V.
- Science, Vol. 301, Issue 5629
N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex
journal, November 2011
- Rodriguez, M. M.; Bill, E.; Brennessel, W. W.
- Science, Vol. 334, Issue 6057
Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor
journal, November 2011
- Spatzal, T.; Aksoyoglu, M.; Zhang, L.
- Science, Vol. 334, Issue 6058
Ammonia synthesis by N2 and steam electrolysis in molten hydroxide suspensions of nanoscale Fe2O3
journal, August 2014
- Licht, S.; Cui, B.; Wang, B.
- Science, Vol. 345, Issue 6197
Ligand binding to the FeMo-cofactor: Structures of CO-bound and reactivated nitrogenase
journal, September 2014
- Spatzal, T.; Perez, K. A.; Einsle, O.
- Science, Vol. 345, Issue 6204
Functionalization and cleavage of coordinated dinitrogen via hydroboration using primary and secondary boranes
journal, April 2005
- MacKay, Bruce A.; Johnson, Samuel A.; Patrick, Brian O.
- Canadian Journal of Chemistry, Vol. 83, Issue 4
Research inspired by the chemistry of nitrogenase — Novel metal complexes and their reactivity toward dinitrogen, nitriles, and alkynes
journal, April 2005
- Hidai, Masanobu; Mizobe, Yasushi
- Canadian Journal of Chemistry, Vol. 83, Issue 4
Mechanism of Mo-Dependent Nitrogenase
journal, June 2009
- Seefeldt, Lance C.; Hoffman, Brian M.; Dean, Dennis R.
- Annual Review of Biochemistry, Vol. 78, Issue 1
Wind to Ammonia: Electrochemical Processes in Room Temperature Ionic Liquids
conference, January 2009
- Pappenfus, Ted M.; Lee, Kyung-mee; Thoma, Laura M.
- 214th ECS Meeting, ECS Transactions
Electrochemical Nitrogen Reduction Reaction on Noble Metal Catalysts in Proton and Hydroxide Exchange Membrane Electrolyzers
journal, January 2017
- Nash, Jared; Yang, Xuan; Anibal, Jacob
- Journal of The Electrochemical Society, Vol. 164, Issue 14
Catalytic Nitrogen Fixation via Direct Cleavage of Nitrogen–Nitrogen Triple Bond of Molecular Dinitrogen under Ambient Reaction Conditions
journal, October 2017
- Arashiba, Kazuya; Eizawa, Aya; Tanaka, Hiromasa
- Bulletin of the Chemical Society of Japan, Vol. 90, Issue 10
Bimetallic Cooperative Cleavage of Dinitrogen to Nitride and Tandem Frustrated Lewis Pair Hydrogenation to Ammonia
journal, April 2019
- Doyle, Laurence R.; Wooles, Ashley J.; Liddle, Stephen T.
- Angewandte Chemie, Vol. 131, Issue 20
Metal-Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen
journal, December 2018
- Schendzielorz, Florian; Finger, Markus; Abbenseth, Josh
- Angewandte Chemie International Edition, Vol. 58, Issue 3
Controlled Incorporation of Nitrides into W-Fe-S Clusters
journal, September 2019
- Xu, Gan; Zhou, Jie; Wang, Zheng
- Angewandte Chemie International Edition, Vol. 58, Issue 46
Back-bonding between an electron-poor, high-oxidation-state metal and poor π-acceptor ligand in a uranium(v)–dinitrogen complex
journal, August 2019
- Lu, Erli; Atkinson, Benjamin E.; Wooles, Ashley J.
- Nature Chemistry, Vol. 11, Issue 9
Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage
journal, January 2019
- Toda, Tatsuro; Suzuki, Satoshi; Kuwata, Shigeki
- Chemical Communications, Vol. 55, Issue 8
Carbon‐Based Metal‐Free Catalysts for Electrocatalytic Reduction of Nitrogen for Synthesis of Ammonia at Ambient Conditions
journal, January 2019
- Zhao, Shenlong; Lu, Xunyu; Wang, Lianzhou
- Advanced Materials, Vol. 31, Issue 13
2D Electrocatalysts for Converting Earth‐Abundant Simple Molecules into Value‐Added Commodity Chemicals: Recent Progress and Perspectives
journal, October 2019
- Yin, Huajie; Dou, Yuhai; Chen, Shan
- Advanced Materials
Photo(electro)catalytic Nitrogen Fixation: Problems and Possibilities
journal, April 2019
- Vu, Manh‐Hiep; Sakar, Mohan; Hassanzadeh‐Tabrizi, Sayed Ali
- Advanced Materials Interfaces, Vol. 6, Issue 12
Recent Advanced Materials for Electrochemical and Photoelectrochemical Synthesis of Ammonia from Dinitrogen: One Step Closer to a Sustainable Energy Future
journal, September 2019
- Yan, Zihao; Ji, Mengxia; Xia, Jiexiang
- Advanced Energy Materials, Vol. 10, Issue 11
Vacancy in Ultrathin 2D Nanomaterials toward Sustainable Energy Application
journal, November 2019
- Bai, Fan; Xu, Liang; Zhai, Xiaoying
- Advanced Energy Materials, Vol. 10, Issue 11
Metal‐Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen
journal, December 2018
- Schendzielorz, Florian; Finger, Markus; Abbenseth, Josh
- Angewandte Chemie
Controlled Incorporation of Nitrides into W‐Fe‐S Clusters
journal, September 2019
- Xu, Gan; Zhou, Jie; Wang, Zheng
- Angewandte Chemie, Vol. 131, Issue 46
Nanoporous Gold Embedded ZIF Composite for Enhanced Electrochemical Nitrogen Fixation
journal, October 2019
- Yang, Yijie; Wang, Shu‐Qi; Wen, Haoming
- Angewandte Chemie International Edition, Vol. 58, Issue 43
Single‐Atom Catalysts for the Electrocatalytic Reduction of Nitrogen to Ammonia under Ambient Conditions
journal, July 2019
- Qiu, Yuan; Peng, Xianyun; Lü, Fang
- Chemistry – An Asian Journal
Activation and Functionalization of Dinitrogen in the Presence of Molecular Hydrogen Promoted by Transition Metal Complexes: Activation and Functionalization of Dinitrogen in the Presence of Molecular Hydrogen Promoted by Transition Metal Complexes
journal, February 2020
- Sivasankar, Chinnappan; Madarasi, Packirisamy Kuzhalmozhi; Tamizmani, Masilamani
- European Journal of Inorganic Chemistry, Vol. 2020, Issue 15-16
Mechanistic Study on Catalytic Disproportionation of Hydrazine by a Protic Pincer-Type Iron Complex through Proton-Coupled Electron Transfer: Mechanistic Study on Catalytic Disproportionation of Hydrazine by a Protic Pincer-Type Iron Complex through Proton-Coupled Electron Transfer
journal, December 2019
- Tanaka, Hiromasa; Hitaoka, Seiji; Umehara, Kazuki
- European Journal of Inorganic Chemistry, Vol. 2020, Issue 15-16
Electrochemical Fabrication of Porous Au Film on Ni Foam for Nitrogen Reduction to Ammonia
journal, January 2019
- Wang, Hongjing; Yu, Hongjie; Wang, Ziqiang
- Small, Vol. 15, Issue 6
Defect Engineering Strategies for Nitrogen Reduction Reactions under Ambient Conditions
journal, October 2018
- Yan, Dafeng; Li, Hao; Chen, Chen
- Small Methods, Vol. 3, Issue 6
Recent Progress on Electrocatalyst and Photocatalyst Design for Nitrogen Reduction
journal, October 2018
- Li, Mengqiao; Huang, Hao; Low, Jingxiang
- Small Methods, Vol. 3, Issue 6
Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia
journal, March 2019
- Suryanto, Bryan H. R.; Du, Hoang-Long; Wang, Dabin
- Nature Catalysis, Vol. 2, Issue 4
Artificial photosynthesis: opportunities and challenges of molecular catalysts
journal, January 2019
- Zhang, Biaobiao; Sun, Licheng
- Chemical Society Reviews, Vol. 48, Issue 7
Elementary kinetics of nitrogen electroreduction to ammonia on late transition metals
journal, January 2019
- Rostamikia, Gholamreza; Maheshwari, Sharad; Janik, Michael J.
- Catalysis Science & Technology, Vol. 9, Issue 1
Metal–organic framework-derived shuttle-like V 2 O 3 /C for electrocatalytic N 2 reduction under ambient conditions
journal, January 2019
- Zhang, Rong; Han, Jingrui; Zheng, Baozhan
- Inorganic Chemistry Frontiers, Vol. 6, Issue 2
A boron-interstitial doped C 2 N layer as a metal-free electrocatalyst for N 2 fixation: a computational study
journal, January 2019
- Ji, Shuang; Wang, Zhongxu; Zhao, Jingxiang
- Journal of Materials Chemistry A, Vol. 7, Issue 5
Recent progress in electrocatalytic nitrogen reduction
journal, January 2019
- Guo, Xiaoxi; Du, Huitong; Qu, Fengli
- Journal of Materials Chemistry A, Vol. 7, Issue 8
Electrocatalytic N 2 -to-NH 3 conversion with high faradaic efficiency enabled using a Bi nanosheet array
journal, January 2019
- Zhang, Rong; Ji, Lei; Kong, Wenhan
- Chemical Communications, Vol. 55, Issue 36
Boron-doped silver nanosponges with enhanced performance towards electrocatalytic nitrogen reduction to ammonia
journal, January 2019
- Li, Yinghao; Yu, Hongjie; Wang, Ziqiang
- Chemical Communications, Vol. 55, Issue 98
Boron and nitrogen dual-doped carbon nanospheres for efficient electrochemical reduction of N 2 to NH 3
journal, January 2020
- Xiao, Shenglin; Luo, Fang; Hu, Hao
- Chemical Communications, Vol. 56, Issue 3
How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully
journal, January 2019
- Tang, Cheng; Qiao, Shi-Zhang
- Chemical Society Reviews, Vol. 48, Issue 12
Single atom electrocatalysts supported on graphene or graphene-like carbons
journal, January 2019
- Fei, Huilong; Dong, Juncai; Chen, Dongliang
- Chemical Society Reviews, Vol. 48, Issue 20
Sandwich-like reduced graphene oxide/yolk–shell-structured Fe@Fe 3 O 4 /carbonized paper as an efficient freestanding electrode for electrochemical synthesis of ammonia directly from H 2 O and nitrogen
journal, January 2019
- Li, Chun; Fu, Yongsheng; Wu, Zhen
- Nanoscale, Vol. 11, Issue 27
Single molybdenum atom anchored on 2D Ti 2 NO 2 MXene as a promising electrocatalyst for N 2 fixation
journal, January 2019
- Cheng, Yuwen; Dai, Jianhong; Song, Yan
- Nanoscale, Vol. 11, Issue 39
Coupling Cu with Au for enhanced electrocatalytic activity of nitrogen reduction reaction
journal, January 2020
- Liu, Yongqin; Huang, Liang; Zhu, Xinyang
- Nanoscale, Vol. 12, Issue 3
Theoretical screening of efficient single-atom catalysts for nitrogen fixation based on a defective BN monolayer
journal, January 2020
- Ma, Zuju; Cui, Zhitao; Xiao, Chengwei
- Nanoscale, Vol. 12, Issue 3
Pt-embedded in monolayer g-C 3 N 4 as a promising single-atom electrocatalyst for ammonia synthesis
journal, January 2019
- Yin, Hui; Li, Shu-Long; Gan, Li-Yong
- Journal of Materials Chemistry A, Vol. 7, Issue 19
Ambient dinitrogen electrocatalytic reduction for ammonia synthesis
journal, January 2019
- Chen, Aling; Xia, Bao Yu
- Journal of Materials Chemistry A, Vol. 7, Issue 41
A novel phosphotungstic acid-supported single metal atom catalyst with high activity and selectivity for the synthesis of NH 3 from electrochemical N 2 reduction: a DFT prediction
journal, January 2019
- Gao, Liye; Wang, Feiteng; Yu, Ming-an
- Journal of Materials Chemistry A, Vol. 7, Issue 34
Facile, cost-effective plasma synthesis of self-supportive FeS x on Fe foam for efficient electrochemical reduction of N 2 under ambient conditions
journal, January 2019
- Xiong, Wei; Guo, Zheng; Zhao, Shijun
- Journal of Materials Chemistry A, Vol. 7, Issue 34
Glycerol oxidation assisted electrocatalytic nitrogen reduction: ammonia and glyceraldehyde co-production on bimetallic RhCu ultrathin nanoflake nanoaggregates
journal, January 2019
- Bai, Juan; Huang, Hao; Li, Fu-Min
- Journal of Materials Chemistry A, Vol. 7, Issue 37
Fe nanodot-decorated MoS 2 nanosheets on carbon cloth: an efficient and flexible electrode for ambient ammonia synthesis
journal, January 2019
- Zhao, Xinhui; Zhang, Xu; Xue, Zhimin
- Journal of Materials Chemistry A, Vol. 7, Issue 48
W supported on g-CN manifests high activity and selectivity for N 2 electroreduction to NH 3
journal, January 2020
- Wang, Shuhua; Wei, Wei; Lv, Xingshuai
- Journal of Materials Chemistry A, Vol. 8, Issue 3
Theory and experiments join forces to characterize the electrocatalytic interface
journal, March 2019
- Steinmann, Stephan N.; Wei, Zi-Yang; Sautet, Philippe
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 16
Complete cleavage of the N≡N triple bond by Ta 2 N + via degenerate ligand exchange at ambient temperature: A perfect catalytic cycle
journal, October 2019
- Geng, Caiyun; Li, Jilai; Weiske, Thomas
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 43
Investigating the operation parameters for ammonia synthesis in dielectric barrier discharge reactors
journal, October 2019
- Li, S.; van Raak, T.; Gallucci, F.
- Journal of Physics D: Applied Physics, Vol. 53, Issue 1