Catalysts for nitrogen reduction to ammonia
Abstract
We present the production of synthetic ammonia remains dependent on the energy- and capital-intensive Haber-Bosch process. Extensive research in molecular catalysis has demonstrated ammonia production from di-nitrogen, albeit at low production rates. Mechanistic understanding of di-nitrogen reduction to ammonia continues to be delineated through study of molecular catalyst structure, as well as through understanding the naturally-occurring nitrogenase enzyme. The transition to Haber-Bosch alternatives through robust, heterogeneous catalyst surfaces remains an unsolved research challenge. Catalysts for electrochemical reduction of di-nitrogen to ammonia are a specific focus of research, due to the potential to compete with Haber-Bosch and eliminate associated carbon dioxide emissions. However, limited progress has been made, as most electrocatalyst surfaces lack specificity towards nitrogen fixation. Lastly in this review, we discuss the progress of the field in developing a mechanistic understanding of nitrogenase-promoted and molecular catalyst-promoted ammonia synthesis and provide a review of the state-of-the-art and scientific needs for heterogeneous electrocatalysts.
- Authors:
-
- Univ. of Arkansas, Fayetteville, AR (United States). Ralph E. Martin Department of Chemical Engineering
- Case Western Reserve Univ., Cleveland, OH (United States). Department of Chemical and Biomolecular Engineering
- Pennsylvania State Univ., University Park, PA (United States). Department of Chemical Engineering
- Univ. of Utah, Salt Lake City, UT (United States). Department of Chemistry
- Publication Date:
- Research Org.:
- Univ. of Arkansas, Fayetteville, AR (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1481881
- Grant/Contract Number:
- SC0016529
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Catalysis
- Additional Journal Information:
- Journal Volume: 1; Journal Issue: 7; Journal ID: ISSN 2520-1158
- Publisher:
- Springer Nature
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Foster, Shelby L., Bakovic, Sergio I. Perez, Duda, Royce D., Maheshwari, Sharad, Milton, Ross D., Minteer, Shelley D., Janik, Michael J., Renner, Julie N., and Greenlee, Lauren F. Catalysts for nitrogen reduction to ammonia. United States: N. p., 2018.
Web. doi:10.1038/s41929-018-0092-7.
Foster, Shelby L., Bakovic, Sergio I. Perez, Duda, Royce D., Maheshwari, Sharad, Milton, Ross D., Minteer, Shelley D., Janik, Michael J., Renner, Julie N., & Greenlee, Lauren F. Catalysts for nitrogen reduction to ammonia. United States. doi:https://doi.org/10.1038/s41929-018-0092-7
Foster, Shelby L., Bakovic, Sergio I. Perez, Duda, Royce D., Maheshwari, Sharad, Milton, Ross D., Minteer, Shelley D., Janik, Michael J., Renner, Julie N., and Greenlee, Lauren F. Thu .
"Catalysts for nitrogen reduction to ammonia". United States. doi:https://doi.org/10.1038/s41929-018-0092-7. https://www.osti.gov/servlets/purl/1481881.
@article{osti_1481881,
title = {Catalysts for nitrogen reduction to ammonia},
author = {Foster, Shelby L. and Bakovic, Sergio I. Perez and Duda, Royce D. and Maheshwari, Sharad and Milton, Ross D. and Minteer, Shelley D. and Janik, Michael J. and Renner, Julie N. and Greenlee, Lauren F.},
abstractNote = {We present the production of synthetic ammonia remains dependent on the energy- and capital-intensive Haber-Bosch process. Extensive research in molecular catalysis has demonstrated ammonia production from di-nitrogen, albeit at low production rates. Mechanistic understanding of di-nitrogen reduction to ammonia continues to be delineated through study of molecular catalyst structure, as well as through understanding the naturally-occurring nitrogenase enzyme. The transition to Haber-Bosch alternatives through robust, heterogeneous catalyst surfaces remains an unsolved research challenge. Catalysts for electrochemical reduction of di-nitrogen to ammonia are a specific focus of research, due to the potential to compete with Haber-Bosch and eliminate associated carbon dioxide emissions. However, limited progress has been made, as most electrocatalyst surfaces lack specificity towards nitrogen fixation. Lastly in this review, we discuss the progress of the field in developing a mechanistic understanding of nitrogenase-promoted and molecular catalyst-promoted ammonia synthesis and provide a review of the state-of-the-art and scientific needs for heterogeneous electrocatalysts.},
doi = {10.1038/s41929-018-0092-7},
journal = {Nature Catalysis},
number = 7,
volume = 1,
place = {United States},
year = {2018},
month = {7}
}
Web of Science
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Boron-doped silver nanosponges with enhanced performance towards electrocatalytic nitrogen reduction to ammonia
journal, January 2019
- Li, Yinghao; Yu, Hongjie; Wang, Ziqiang
- Chemical Communications, Vol. 55, Issue 98
Boron and nitrogen dual-doped carbon nanospheres for efficient electrochemical reduction of N 2 to NH 3
journal, January 2020
- Xiao, Shenglin; Luo, Fang; Hu, Hao
- Chemical Communications, Vol. 56, Issue 3
How to explore ambient electrocatalytic nitrogen reduction reliably and insightfully
journal, January 2019
- Tang, Cheng; Qiao, Shi-Zhang
- Chemical Society Reviews, Vol. 48, Issue 12
Single atom electrocatalysts supported on graphene or graphene-like carbons
journal, January 2019
- Fei, Huilong; Dong, Juncai; Chen, Dongliang
- Chemical Society Reviews, Vol. 48, Issue 20
Sandwich-like reduced graphene oxide/yolk–shell-structured Fe@Fe 3 O 4 /carbonized paper as an efficient freestanding electrode for electrochemical synthesis of ammonia directly from H 2 O and nitrogen
journal, January 2019
- Li, Chun; Fu, Yongsheng; Wu, Zhen
- Nanoscale, Vol. 11, Issue 27
Single molybdenum atom anchored on 2D Ti 2 NO 2 MXene as a promising electrocatalyst for N 2 fixation
journal, January 2019
- Cheng, Yuwen; Dai, Jianhong; Song, Yan
- Nanoscale, Vol. 11, Issue 39
Coupling Cu with Au for enhanced electrocatalytic activity of nitrogen reduction reaction
journal, January 2020
- Liu, Yongqin; Huang, Liang; Zhu, Xinyang
- Nanoscale, Vol. 12, Issue 3
Theoretical screening of efficient single-atom catalysts for nitrogen fixation based on a defective BN monolayer
journal, January 2020
- Ma, Zuju; Cui, Zhitao; Xiao, Chengwei
- Nanoscale, Vol. 12, Issue 3
Pt-embedded in monolayer g-C 3 N 4 as a promising single-atom electrocatalyst for ammonia synthesis
journal, January 2019
- Yin, Hui; Li, Shu-Long; Gan, Li-Yong
- Journal of Materials Chemistry A, Vol. 7, Issue 19
Ambient dinitrogen electrocatalytic reduction for ammonia synthesis
journal, January 2019
- Chen, Aling; Xia, Bao Yu
- Journal of Materials Chemistry A, Vol. 7, Issue 41
A novel phosphotungstic acid-supported single metal atom catalyst with high activity and selectivity for the synthesis of NH 3 from electrochemical N 2 reduction: a DFT prediction
journal, January 2019
- Gao, Liye; Wang, Feiteng; Yu, Ming-an
- Journal of Materials Chemistry A, Vol. 7, Issue 34
Facile, cost-effective plasma synthesis of self-supportive FeS x on Fe foam for efficient electrochemical reduction of N 2 under ambient conditions
journal, January 2019
- Xiong, Wei; Guo, Zheng; Zhao, Shijun
- Journal of Materials Chemistry A, Vol. 7, Issue 34
Glycerol oxidation assisted electrocatalytic nitrogen reduction: ammonia and glyceraldehyde co-production on bimetallic RhCu ultrathin nanoflake nanoaggregates
journal, January 2019
- Bai, Juan; Huang, Hao; Li, Fu-Min
- Journal of Materials Chemistry A, Vol. 7, Issue 37
Fe nanodot-decorated MoS 2 nanosheets on carbon cloth: an efficient and flexible electrode for ambient ammonia synthesis
journal, January 2019
- Zhao, Xinhui; Zhang, Xu; Xue, Zhimin
- Journal of Materials Chemistry A, Vol. 7, Issue 48
W supported on g-CN manifests high activity and selectivity for N 2 electroreduction to NH 3
journal, January 2020
- Wang, Shuhua; Wei, Wei; Lv, Xingshuai
- Journal of Materials Chemistry A, Vol. 8, Issue 3
Theory and experiments join forces to characterize the electrocatalytic interface
journal, March 2019
- Steinmann, Stephan N.; Wei, Zi-Yang; Sautet, Philippe
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 16
Complete cleavage of the N≡N triple bond by Ta 2 N + via degenerate ligand exchange at ambient temperature: A perfect catalytic cycle
journal, October 2019
- Geng, Caiyun; Li, Jilai; Weiske, Thomas
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 43
Investigating the operation parameters for ammonia synthesis in dielectric barrier discharge reactors
journal, October 2019
- Li, S.; van Raak, T.; Gallucci, F.
- Journal of Physics D: Applied Physics, Vol. 53, Issue 1