Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11

Kunz Wille, Elizabeth L.; Jo, Na Hyun; Fettinger, James C.; Canfield, Paul C.; Kauzlarich, Susan M.

doi:10.1039/c8cc05471a

Title: Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb₁₄MgSb₁₁

Abstract

Here, large crystals of Yb₁₄MgSb₁₁ were grown through a Sn flux method. Magnetic susceptibility measurements yield an effective magnetic moment of 3.4(1) μ_B, revealing the presence of both divalent and trivalent Yb in Yb₁₄MgSb₁₁. Previously assumed to only contain Yb²⁺ as in Yb₁₄MnSb₁₁, the mixed valency demonstrates that Yb₁₄MgSb₁₁ is a Zintl phase.

Authors:

Kunz Wille, Elizabeth L. ^[1]; Jo, Na Hyun ^[2];

^[1]; Canfield, Paul C. ^[2];

^[1]

Univ. of California, Davis, CA (United States)
Ames Lab. and Iowa State Univ., Ames, IA (United States)

Publication Date:: Thu Oct 25 00:00:00 EDT 2018

Research Org.:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1481869

Alternate Identifier(s):: OSTI ID: 1480150

Report Number(s):: IS-J-9796
Journal ID: ISSN 1359-7345; CHCOFS

Grant/Contract Number:: Grant GBMF4411; SC0014664; AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 54; Journal Issue: 92; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Kunz Wille, Elizabeth L., Jo, Na Hyun, Fettinger, James C., Canfield, Paul C., and Kauzlarich, Susan M. Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11.  United States: N. p., 2018. 
Web.  doi:10.1039/c8cc05471a.

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                    Kunz Wille, Elizabeth L., Jo, Na Hyun, Fettinger, James C., Canfield, Paul C., & Kauzlarich, Susan M. Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11.  United States.  https://doi.org/10.1039/c8cc05471a

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                    Kunz Wille, Elizabeth L., Jo, Na Hyun, Fettinger, James C., Canfield, Paul C., and Kauzlarich, Susan M. Thu .  
"Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11".  United States.  https://doi.org/10.1039/c8cc05471a.  https://www.osti.gov/servlets/purl/1481869.

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@article{osti_1481869,

  title        = {Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11},

  author       = {Kunz Wille, Elizabeth L. and Jo, Na Hyun and Fettinger, James C. and Canfield, Paul C. and Kauzlarich, Susan M.},

  abstractNote = {Here, large crystals of Yb14MgSb11 were grown through a Sn flux method. Magnetic susceptibility measurements yield an effective magnetic moment of 3.4(1) μB, revealing the presence of both divalent and trivalent Yb in Yb14MgSb11. Previously assumed to only contain Yb2+ as in Yb14MnSb11, the mixed valency demonstrates that Yb14MgSb11 is a Zintl phase.},

  doi          = {10.1039/c8cc05471a},

  journal      = {ChemComm},

  number       = 92,

  volume       = 54,

  place        = {United States},

  year         = {Thu Oct 25 00:00:00 EDT 2018},

  month        = {Thu Oct 25 00:00:00 EDT 2018}

}

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Journal Article:

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https://doi.org/10.1039/c8cc05471a

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Cited by: 15 works

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Figures / Tables:

Figure 1: A view down the c axis of Yb₁₄MgSb₁₁ (tetragonal, I4₁/acd). The Yb atoms are shown in blue, Sb in gold, and the grey tetrahedra are MgSb₄.

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Works referencing / citing this record:

Synthesis, crystal structure and physical properties of the solid solutions Ca 14– x RE x CdSb 11 ( RE = La–Nd, Sm, Gd–Yb, x ≈ 0.85 ± 0.15)
journal, June 2019

Baranets, Sviatoslav; Voss, Leonard; Stoyko, Stanislav
Journal of Applied Physics, Vol. 125, Issue 24
DOI: 10.1063/1.5099632

Hydride assisted synthesis of the high temperature thermoelectric phase: Yb 14 MgSb 11
journal, October 2019

Justl, Andrew P.; Cerretti, Giacomo; Bux, Sabah K.
Journal of Applied Physics, Vol. 126, Issue 16
DOI: 10.1063/1.5117291

Seebeck and Figure of Merit Enhancement by Rare Earth Doping in Yb14-xRExZnSb11 (x = 0.5)
journal, March 2019

Kunz Wille, Elizabeth; Grewal, Navtej; Bux, Sabah
Materials, Vol. 12, Issue 5
DOI: 10.3390/ma12050731

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dataset (1)

Title: Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11

Abstract

Citation Formats

Figures / Tables:

Yb 14 ZnSb 11 : Charge Balance in Zintl Compounds as a Route to Intermediate Yb Valence journal, July 2000

Thermochemistry study and improved thermal stability of Yb 14 MnSb 11 alloyed by Ln 3+ (La–Lu) journal, January 2016

Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples journal, December 2015

Tuning Magnetism of [MnSb 4 ] 9– Cluster in Yb 14 MnSb 11 through Chemical Substitutions on Yb Sites: Appearance and Disappearance of Spin Reorientation journal, September 2016

XMCD Characterization of the Ferromagnetic State of Yb 14 MnSb 11 journal, August 2002

X-ray photoelectron spectroscopy studies of Yb14MnSb11 and Yb14ZnSb11 journal, January 2005

Thermoelectric materials: Energy conversion between heat and electricity journal, June 2015

Principles of crystal growth of intermetallic and oxide compounds from molten solutions journal, July 2012

Complex thermoelectric materials journal, February 2008

Effects of Sc and Y substitution on the structure and thermoelectric properties of Yb14MnSb11 journal, October 2016

Traversing the Metal-Insulator Transition in a Zintl Phase: Rational Enhancement of Thermoelectric Efficiency in Yb 14 Mn 1− x Al x Sb 11 journal, September 2008

A 14 MgBi 11 ( A = Ca, Sr, Eu): Magnesium Bismuth Based Zintl Phases as Potential Thermoelectric Materials journal, August 2017

Structure, Magnetism, and Thermoelectric Properties of Magnesium-Containing Antimonide Zintl Phases Sr 14 MgSb 11 and Eu 14 MgSb 11 journal, January 2017

The effect of light rare earth element substitution in Yb 14 MnSb 11 on thermoelectric properties journal, January 2015

Thermodynamic and transport properties of single-crystal Yb 14 MnSb 11 journal, June 1999

Growth of single crystals from metallic fluxes journal, June 1992

Valence-fluctuation behavior of Yb ions and YbCuGa journal, August 1990

Lifshitz transition from valence fluctuations in YbAl3 journal, October 2017

Yb14−xTmxMnSb11 (0<x<0.5): Structure and magnetic properties journal, March 2014

Yb 14 MgBi 11 : structure, thermoelectric properties and the effect of the structure on low lattice thermal conductivity journal, January 2017

Strong Valence Fluctuation in the Quantum Critical Heavy Fermion Superconductor β − YbAlB 4 : A Hard X-Ray Photoemission Study journal, June 2010

Yb 14 MnSb 11 : New High Efficiency Thermoelectric Material for Power Generation journal, April 2006

Magnetic and structural effects of partial Ce substitution in Y b 14 MnSb 11 journal, April 2015

Yb 14 MgSb 11 and Ca 14 MgSb 11 —New Mg-Containing Zintl Compounds and Their Structures, Bonding, and Thermoelectric Properties journal, December 2014

Complex thermoelectric materials book, October 2010

Principles of crystal growth of intermetallic and oxide compounds from molten solutions text, January 2012

Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples text, January 2015

Synthesis, crystal structure and physical properties of the solid solutions Ca 14– x RE x CdSb 11 ( RE = La–Nd, Sm, Gd–Yb, x ≈ 0.85 ± 0.15) journal, June 2019

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Title: Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb₁₄MgSb₁₁

${Yb}_{14} {ZnSb}_{11}$ : Charge Balance in Zintl Compounds as a Route to Intermediate Yb Valence
journal, July 2000

Thermochemistry study and improved thermal stability of Yb ₁₄ MnSb ₁₁ alloyed by Ln ³⁺ (La–Lu)
journal, January 2016

Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples
journal, December 2015

Tuning Magnetism of [MnSb ₄ ] ^9– Cluster in Yb ₁₄ MnSb ₁₁ through Chemical Substitutions on Yb Sites: Appearance and Disappearance of Spin Reorientation
journal, September 2016

XMCD Characterization of the Ferromagnetic State of Yb ₁₄ MnSb ₁₁
journal, August 2002

X-ray photoelectron spectroscopy studies of Yb14MnSb11 and Yb14ZnSb11
journal, January 2005

Thermoelectric materials: Energy conversion between heat and electricity
journal, June 2015

Principles of crystal growth of intermetallic and oxide compounds from molten solutions
journal, July 2012

Complex thermoelectric materials
journal, February 2008

Effects of Sc and Y substitution on the structure and thermoelectric properties of Yb14MnSb11
journal, October 2016

Traversing the Metal-Insulator Transition in a Zintl Phase: Rational Enhancement of Thermoelectric Efficiency in Yb ₁₄ Mn _{1− x} Al _x Sb ₁₁
journal, September 2008

A ₁₄ MgBi ₁₁ ( A = Ca, Sr, Eu): Magnesium Bismuth Based Zintl Phases as Potential Thermoelectric Materials
journal, August 2017

Structure, Magnetism, and Thermoelectric Properties of Magnesium-Containing Antimonide Zintl Phases Sr ₁₄ MgSb ₁₁ and Eu ₁₄ MgSb ₁₁
journal, January 2017

The effect of light rare earth element substitution in Yb ₁₄ MnSb ₁₁ on thermoelectric properties
journal, January 2015

Thermodynamic and transport properties of single-crystal ${Yb}_{14} {MnSb}_{11}$
journal, June 1999

Growth of single crystals from metallic fluxes
journal, June 1992

Valence-fluctuation behavior of Yb ions and YbCuGa
journal, August 1990

Lifshitz transition from valence fluctuations in YbAl3
journal, October 2017

Yb14−xTmxMnSb11 (0<x<0.5): Structure and magnetic properties
journal, March 2014

Yb ₁₄ MgBi ₁₁ : structure, thermoelectric properties and the effect of the structure on low lattice thermal conductivity
journal, January 2017

Strong Valence Fluctuation in the Quantum Critical Heavy Fermion Superconductor $β − {YbAlB}_{4}$ : A Hard X-Ray Photoemission Study
journal, June 2010

Yb ₁₄ MnSb ₁₁ : New High Efficiency Thermoelectric Material for Power Generation
journal, April 2006

Magnetic and structural effects of partial Ce substitution in Y b ₁₄ MnSb ₁₁
journal, April 2015

Yb ₁₄ MgSb ₁₁ and Ca ₁₄ MgSb ₁₁ —New Mg-Containing Zintl Compounds and Their Structures, Bonding, and Thermoelectric Properties
journal, December 2014

Complex thermoelectric materials
book, October 2010

Principles of crystal growth of intermetallic and oxide compounds from molten solutions
text, January 2012

Use of frit-disc crucibles for routine and exploratory solution growth of single crystalline samples
text, January 2015

Synthesis, crystal structure and physical properties of the solid solutions Ca 14– x RE x CdSb 11 ( RE = La–Nd, Sm, Gd–Yb, x ≈ 0.85 ± 0.15)
journal, June 2019

Hydride assisted synthesis of the high temperature thermoelectric phase: Yb 14 MgSb 11
journal, October 2019

Seebeck and Figure of Merit Enhancement by Rare Earth Doping in Yb14-xRExZnSb11 (x = 0.5)
journal, March 2019