Effects of Chlorine in Ash on the Corrosion Performance of Ni-Based Alloys in a Simulated Oxy-Fuel Environment

Zeng, Zuotao; Natesan, Ken; Cai, Zhonghou; Gosztola, David J.

doi:10.1021/acs.energyfuels.8b02233

Title: Effects of Chlorine in Ash on the Corrosion Performance of Ni-Based Alloys in a Simulated Oxy-Fuel Environment

Abstract

Coal ash can severely attack alloy materials at high temperature. To understand coal ash corrosion, a critical study is needed to determine the effect of the elements in ash on corrosion and find an approach to reduce the corrosion rates in an ash environment at high temperature. Chlorine is a harmful element in coal. The role of chlorine in ash corrosion is investigated in simulated oxy-fuel environments. Long time tests up to 3000 hours were performed on various structural alloys at 750°C. Detailed results are presented on weight change, scale thickness, internal penetration, microstructural characteristics of corrosion products, and the cracking of scales for the alloys after exposure at 750°C for 3000h. In addition, we performed synchrotron nanobeam Furthermore X-ray analysis to study the phase and chemical composition of the oxide layers on the alloy surface. Results from these studies are used to address the role of chlorine in ash in the long-term corrosion performance of alloys. Nanobeam X-ray and SEM analyses indicate that chlorine can modify the diffusion mechanism near alloy surface, and increase corrosion rate.

Authors:

^[1]; Natesan, Ken ^[1]; Cai, Zhonghou ^[1];

^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Thu Sep 20 00:00:00 EDT 2018

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Fossil Energy (FE)

OSTI Identifier:: 1481860

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Energy and Fuels

Additional Journal Information:: Journal Volume: 32; Journal Issue: 10; Journal ID: ISSN 0887-0624

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 01 COAL, LIGNITE, AND PEAT; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; ash corrosion; chlorine; long term test; oxy-fuel

Citation Formats


                    Zeng, Zuotao, Natesan, Ken, Cai, Zhonghou, and Gosztola, David J. Effects of Chlorine in Ash on the Corrosion Performance of Ni-Based Alloys in a Simulated Oxy-Fuel Environment.  United States: N. p., 2018. 
Web.  doi:10.1021/acs.energyfuels.8b02233.

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                    Zeng, Zuotao, Natesan, Ken, Cai, Zhonghou, & Gosztola, David J. Effects of Chlorine in Ash on the Corrosion Performance of Ni-Based Alloys in a Simulated Oxy-Fuel Environment.  United States.  https://doi.org/10.1021/acs.energyfuels.8b02233

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                    Zeng, Zuotao, Natesan, Ken, Cai, Zhonghou, and Gosztola, David J. Thu .  
"Effects of Chlorine in Ash on the Corrosion Performance of Ni-Based Alloys in a Simulated Oxy-Fuel Environment".  United States.  https://doi.org/10.1021/acs.energyfuels.8b02233.  https://www.osti.gov/servlets/purl/1481860.

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@article{osti_1481860,

  title        = {Effects of Chlorine in Ash on the Corrosion Performance of Ni-Based Alloys in a Simulated Oxy-Fuel Environment},

  author       = {Zeng, Zuotao and Natesan, Ken and Cai, Zhonghou and Gosztola, David J.},

  abstractNote = {Coal ash can severely attack alloy materials at high temperature. To understand coal ash corrosion, a critical study is needed to determine the effect of the elements in ash on corrosion and find an approach to reduce the corrosion rates in an ash environment at high temperature. Chlorine is a harmful element in coal. The role of chlorine in ash corrosion is investigated in simulated oxy-fuel environments. Long time tests up to 3000 hours were performed on various structural alloys at 750°C. Detailed results are presented on weight change, scale thickness, internal penetration, microstructural characteristics of corrosion products, and the cracking of scales for the alloys after exposure at 750°C for 3000h. In addition, we performed synchrotron nanobeam Furthermore X-ray analysis to study the phase and chemical composition of the oxide layers on the alloy surface. Results from these studies are used to address the role of chlorine in ash in the long-term corrosion performance of alloys. Nanobeam X-ray and SEM analyses indicate that chlorine can modify the diffusion mechanism near alloy surface, and increase corrosion rate.},

  doi          = {10.1021/acs.energyfuels.8b02233},

  journal      = {Energy and Fuels},

  number       = 10,

  volume       = 32,

  place        = {United States},

  year         = {Thu Sep 20 00:00:00 EDT 2018},

  month        = {Thu Sep 20 00:00:00 EDT 2018}

}

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Journal Article:

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https://doi.org/10.1021/acs.energyfuels.8b02233

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Cited by: 7 works

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Table 1: Alloy nominal composition (in wt.%)

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High‐temperature corrosion behaviors of typical nickel alloy coatings in a simulated boiler coal ash/gas environment in the Zhundong region
journal, January 2020

Wu, Jun; Wu, Xiaojiang; Cheng, Peize
Materials and Corrosion, Vol. 71, Issue 7
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Title: Effects of Chlorine in Ash on the Corrosion Performance of Ni-Based Alloys in a Simulated Oxy-Fuel Environment

Abstract

Citation Formats

Figures / Tables:

Influence of novel cycle concepts on the high-temperature corrosion of power plants journal, May 2008

High-temperature oxidation of Fe-Cr alloys in wet oxygen journal, October 1997

Type 304 Stainless Steel vs Flowing CO 2 At Atmospheric Pressure and 1100-1800F journal, March 1965

Effect of Element Diffusion Through Metallic Networks During Oxidation of Type 321 Stainless Steel journal, February 2014

Sulphur impacts during pulverised coal combustion in oxy-fuel technology for carbon capture and storage journal, February 2011

High Temperature Corrosion of Chromium–Manganese Steels in Sulfur Dioxide journal, December 2005

Fireside corrosion of superheaters: Effects of air and oxy-firing of coal and biomass journal, November 2012

Fireside Corrosion of Austenitic Tube Materials for Advanced USC Boilers journal, September 2011

Laboratory-simulated fuel-ash corrosion of superheater tubes in coal-fired ultra-supercritical-boilers journal, November 2000

The corrosion of INCONEL alloy 740 in simulated environments for pulverized coal-fired boiler journal, April 2005

Superheater fireside corrosion mechanisms in MSWI plants: Lab-scale study and on-site results: Superheater fireside corrosion mechanisms in MSWI plants journal, October 2010

Fireside Corrosion in Oxy-fuel Combustion of Coal journal, February 2013

Effect of temperature on coal ash hot corrosion resistance of Inconel 740 superalloy journal, May 2014

Effect of coal ash on the performance of alloys in simulated oxy-fuel environments journal, January 2014

Effects of calcium in ash on the corrosion performance of Ni-based alloys in simulated oxy-fuel environment journal, August 2016

Corrosion Performance of Fe-Based Alloys in Simulated Oxy-Fuel Environment journal, September 2016

Chlorine in Solid Fuels Fired in Pulverized Fuel Boilers — Sources, Forms, Reactions, and Consequences: a Literature Review † journal, July 2009

Corrosivities in a pilot-scale combustor of a British and two Illinois coals with varying chlorine contents journal, May 2000

The implications of chlorine-associated corrosion on the operation of biomass-fired boilers journal, June 2000

Lab-Scale Investigations of High-Temperature Corrosion Phenomena in Straw-Fired Boilers journal, November 1999

Corrosion in biomass combustion: A materials selection analysis and its interaction with corrosion mechanisms and mitigation strategies journal, November 2013

High-temperature tube corrosion upon the interaction with Victorian brown coal fly ash under the oxy-fuel combustion condition journal, January 2017

A New Method to Minimize High-Temperature Corrosion Resulting from Alkali Sulfate and Chloride Deposition in Combustion Systems. I. Tungsten Salts † journal, January 2003

New Method To Minimize High-Temperature Corrosion Resulting from Alkali Sulfate and Chloride Deposition in Combustion Systems. II. Molybdenum Salts journal, September 2005

Two strategies to reduce gaseous KCl and chlorine in deposits during biomass combustion — injection of ammonium sulphate and co-combustion with peat journal, January 2013

The Effect of Chlorine and Sulfur on the Composition of Ash Deposits in a Fluidized Bed Combustion System journal, September 2000

Corrosion Mechanism of Alloy 310 Austenitic Steel beneath NaCl Deposit under Varying SO 2 Concentrations in an Oxy-fuel Combustion Atmosphere journal, July 2013

Influence of gaseous SO2 and sulphate-bearing ash deposits on the high-temperature corrosion of heat exchanger tube during oxy-fuel combustion journal, December 2017

Preventing chlorine deposition on heat transfer surfaces with aluminium–silicon rich biomass residue and additive journal, July 2004

Importance of coal ash composition in protecting the boiler against chlorine deposition during combustion of chlorine-rich biomass journal, January 2005

The chemical nature of combustion deposition and corrosion: The case of alkali chlorides journal, May 2012

An overview on oxyfuel coal combustion—State of the art research and technology development journal, August 2009

Impact of the oxy-fuel combustion on the corrosion behavior of advanced austenitic superheater materials journal, January 2011

Chlorine in coal: A review journal, May 2006

Characterization of surface oxides by Raman spectroscopy journal, November 1980

In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals journal, February 1988

Spectroscopic characterization of oxide films on type 304 SS exposed to water at 289° C: correlation with the Fe-Cr-H2O pourbaix diagram journal, June 1990

Raman Spectra of Possible Corrosion Products of Iron journal, November 1978

The effects of chlorides, hydrogen chloride, and sulfur dioxide in the oxidation of steels below deposits journal, July 1995

Molten Salts Data: Diffusion Coefficients in Single and Multi‐Component Salt Systems journal, July 1982

The reduction of HCl dissolved in LiCl-KCl eutectic journal, January 1975

Auger Sputter Profiling and Secondary Ion Mass Spectrometry Studies of SiO2 Grown in O 2 / HCl Mixtures journal, April 1984

The role of metal nanoparticles and nanonetworks in alloy degradation journal, July 2008

Chlorine ion mobility in Cl-mayenite (Ca12Al14O32Cl2): An investigation combining high-temperature neutron powder diffraction, impedance spectroscopy and quantum-chemical calculations journal, January 2014

High‐temperature corrosion behaviors of typical nickel alloy coatings in a simulated boiler coal ash/gas environment in the Zhundong region journal, January 2020

Influence of novel cycle concepts on the high-temperature corrosion of power plants
journal, May 2008

High-temperature oxidation of Fe-Cr alloys in wet oxygen
journal, October 1997

Type 304 Stainless Steel vs Flowing CO ₂ At Atmospheric Pressure and 1100-1800F
journal, March 1965

Effect of Element Diffusion Through Metallic Networks During Oxidation of Type 321 Stainless Steel
journal, February 2014

Sulphur impacts during pulverised coal combustion in oxy-fuel technology for carbon capture and storage
journal, February 2011

High Temperature Corrosion of Chromium–Manganese Steels in Sulfur Dioxide
journal, December 2005

Fireside corrosion of superheaters: Effects of air and oxy-firing of coal and biomass
journal, November 2012

Fireside Corrosion of Austenitic Tube Materials for Advanced USC Boilers
journal, September 2011

Laboratory-simulated fuel-ash corrosion of superheater tubes in coal-fired ultra-supercritical-boilers
journal, November 2000

The corrosion of INCONEL alloy 740 in simulated environments for pulverized coal-fired boiler
journal, April 2005

Superheater fireside corrosion mechanisms in MSWI plants: Lab-scale study and on-site results: Superheater fireside corrosion mechanisms in MSWI plants
journal, October 2010

Fireside Corrosion in Oxy-fuel Combustion of Coal
journal, February 2013

Effect of temperature on coal ash hot corrosion resistance of Inconel 740 superalloy
journal, May 2014

Effect of coal ash on the performance of alloys in simulated oxy-fuel environments
journal, January 2014

Effects of calcium in ash on the corrosion performance of Ni-based alloys in simulated oxy-fuel environment
journal, August 2016

Corrosion Performance of Fe-Based Alloys in Simulated Oxy-Fuel Environment
journal, September 2016

Chlorine in Solid Fuels Fired in Pulverized Fuel Boilers — Sources, Forms, Reactions, and Consequences: a Literature Review ^†
journal, July 2009

Corrosivities in a pilot-scale combustor of a British and two Illinois coals with varying chlorine contents
journal, May 2000

The implications of chlorine-associated corrosion on the operation of biomass-fired boilers
journal, June 2000

Lab-Scale Investigations of High-Temperature Corrosion Phenomena in Straw-Fired Boilers
journal, November 1999

Corrosion in biomass combustion: A materials selection analysis and its interaction with corrosion mechanisms and mitigation strategies
journal, November 2013

High-temperature tube corrosion upon the interaction with Victorian brown coal fly ash under the oxy-fuel combustion condition
journal, January 2017

A New Method to Minimize High-Temperature Corrosion Resulting from Alkali Sulfate and Chloride Deposition in Combustion Systems. I. Tungsten Salts ^†
journal, January 2003

New Method To Minimize High-Temperature Corrosion Resulting from Alkali Sulfate and Chloride Deposition in Combustion Systems. II. Molybdenum Salts
journal, September 2005

Two strategies to reduce gaseous KCl and chlorine in deposits during biomass combustion — injection of ammonium sulphate and co-combustion with peat
journal, January 2013

The Effect of Chlorine and Sulfur on the Composition of Ash Deposits in a Fluidized Bed Combustion System
journal, September 2000

Corrosion Mechanism of Alloy 310 Austenitic Steel beneath NaCl Deposit under Varying SO ₂ Concentrations in an Oxy-fuel Combustion Atmosphere
journal, July 2013

Influence of gaseous SO2 and sulphate-bearing ash deposits on the high-temperature corrosion of heat exchanger tube during oxy-fuel combustion
journal, December 2017

Preventing chlorine deposition on heat transfer surfaces with aluminium–silicon rich biomass residue and additive
journal, July 2004

Importance of coal ash composition in protecting the boiler against chlorine deposition during combustion of chlorine-rich biomass
journal, January 2005

The chemical nature of combustion deposition and corrosion: The case of alkali chlorides
journal, May 2012

An overview on oxyfuel coal combustion—State of the art research and technology development
journal, August 2009

Impact of the oxy-fuel combustion on the corrosion behavior of advanced austenitic superheater materials
journal, January 2011

Chlorine in coal: A review
journal, May 2006

Characterization of surface oxides by Raman spectroscopy
journal, November 1980

In‐Situ Raman Spectroscopy Combined with X‐Ray Photoelectron Spectroscopy and Nuclear Microanalysis for Studies of Anodic Corrosion Film Formation on Fe‐Cr Single Crystals
journal, February 1988

Spectroscopic characterization of oxide films on type 304 SS exposed to water at 289° C: correlation with the Fe-Cr-H2O pourbaix diagram
journal, June 1990

Raman Spectra of Possible Corrosion Products of Iron
journal, November 1978

The effects of chlorides, hydrogen chloride, and sulfur dioxide in the oxidation of steels below deposits
journal, July 1995

Molten Salts Data: Diffusion Coefficients in Single and Multi‐Component Salt Systems
journal, July 1982

The reduction of HCl dissolved in LiCl-KCl eutectic
journal, January 1975

Auger Sputter Profiling and Secondary Ion Mass Spectrometry Studies of SiO2 Grown in O 2 / HCl Mixtures
journal, April 1984

The role of metal nanoparticles and nanonetworks in alloy degradation
journal, July 2008

Chlorine ion mobility in Cl-mayenite (Ca12Al14O32Cl2): An investigation combining high-temperature neutron powder diffraction, impedance spectroscopy and quantum-chemical calculations
journal, January 2014

High‐temperature corrosion behaviors of typical nickel alloy coatings in a simulated boiler coal ash/gas environment in the Zhundong region
journal, January 2020