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Title: Reduction of CO 2 by a masked two-coordinate cobalt( i ) complex and characterization of a proposed oxodicobalt( ii ) intermediate

The detailed mechanism of CO 2 reduction by a cobalt( i ) complex is investigated using computations and kinetics.
Authors:
ORCiD logo [1] ;  [2] ;  [3] ; ORCiD logo [4] ;  [5] ; ORCiD logo [5] ; ORCiD logo [6] ;  [4] ; ORCiD logo [2] ;  [7] ; ORCiD logo [7] ; ORCiD logo [3]
  1. Max Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr, Germany, CSIR Central Mechanical Engineering Research Institute, Durgapur 713209
  2. Department of Chemistry, University of Rochester, Rochester, USA
  3. Department of Chemistry, Yale University, New Haven, USA
  4. Max Planck Institute for Chemical Energy Conversion, Mülheim an der Ruhr, Germany
  5. Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, USA
  6. Department of Chemistry, Trinity University, San Antonio, USA
  7. Max Planck Institute for Coal Research, Mülheim an der Ruhr, Germany
Publication Date:
Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1481442

Roy, Lisa, Al-Afyouni, Malik H., DeRosha, Daniel E., Mondal, Bhaskar, DiMucci, Ida M., Lancaster, Kyle M., Shearer, Jason, Bill, Eckhard, Brennessel, William W., Neese, Frank, Ye, Shengfa, and Holland, Patrick L.. Reduction of CO 2 by a masked two-coordinate cobalt( i ) complex and characterization of a proposed oxodicobalt( ii ) intermediate. United Kingdom: N. p., Web. doi:10.1039/C8SC02599A.
Roy, Lisa, Al-Afyouni, Malik H., DeRosha, Daniel E., Mondal, Bhaskar, DiMucci, Ida M., Lancaster, Kyle M., Shearer, Jason, Bill, Eckhard, Brennessel, William W., Neese, Frank, Ye, Shengfa, & Holland, Patrick L.. Reduction of CO 2 by a masked two-coordinate cobalt( i ) complex and characterization of a proposed oxodicobalt( ii ) intermediate. United Kingdom. doi:10.1039/C8SC02599A.
Roy, Lisa, Al-Afyouni, Malik H., DeRosha, Daniel E., Mondal, Bhaskar, DiMucci, Ida M., Lancaster, Kyle M., Shearer, Jason, Bill, Eckhard, Brennessel, William W., Neese, Frank, Ye, Shengfa, and Holland, Patrick L.. 2019. "Reduction of CO 2 by a masked two-coordinate cobalt( i ) complex and characterization of a proposed oxodicobalt( ii ) intermediate". United Kingdom. doi:10.1039/C8SC02599A.
@article{osti_1481442,
title = {Reduction of CO 2 by a masked two-coordinate cobalt( i ) complex and characterization of a proposed oxodicobalt( ii ) intermediate},
author = {Roy, Lisa and Al-Afyouni, Malik H. and DeRosha, Daniel E. and Mondal, Bhaskar and DiMucci, Ida M. and Lancaster, Kyle M. and Shearer, Jason and Bill, Eckhard and Brennessel, William W. and Neese, Frank and Ye, Shengfa and Holland, Patrick L.},
abstractNote = {The detailed mechanism of CO 2 reduction by a cobalt( i ) complex is investigated using computations and kinetics.},
doi = {10.1039/C8SC02599A},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2019},
month = {1}
}

Works referenced in this record:

Electrochemical Reduction of CO2 to CO Catalyzed by a Bimetallic Palladium Complex
journal, July 2006
  • Raebiger, James W.; Turner, Jeffrey W.; Noll, Bruce C.
  • Organometallics, Vol. 25, Issue 14, p. 3345-3351
  • DOI: 10.1021/om060228g

A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions
journal, November 2006
  • Zhao, Yan; Truhlar, Donald G.
  • The Journal of Chemical Physics, Vol. 125, Issue 19, Article No. 194101
  • DOI: 10.1063/1.2370993

Cobalt�phosphate oxygen-evolving compound
journal, January 2009
  • Kanan, Matthew W.; Surendranath, Yogesh; Nocera, Daniel G.
  • Chemical Society Reviews, Vol. 38, Issue 1, p. 109-114
  • DOI: 10.1039/B802885K

Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
journal, September 1980
  • Fisher, Barbara J.; Eisenberg, Richard
  • Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363
  • DOI: 10.1021/ja00544a035

Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation
journal, December 2009
  • Rakowski Dubois, M.; Dubois, Daniel L.
  • Accounts of Chemical Research, Vol. 42, Issue 12, p. 1974-1982
  • DOI: 10.1021/ar900110c