A Dynamically Stabilized Single‐Nickel Electrocatalyst for Selective Reduction of Oxygen to Hydrogen Peroxide

Wang, Tingting; Zeng, Zhongming; Cao, Lingyun; Li, Zhe; Hu, Xuefu; An, Bing; Wang, Cheng; Lin, Wenbin

doi:10.1002/chem.201804312

Title: A Dynamically Stabilized Single‐Nickel Electrocatalyst for Selective Reduction of Oxygen to Hydrogen Peroxide

Journal Article · 09 November 2018 · Chemistry - A European Journal

DOI: https://doi.org/10.1002/chem.201804312 · OSTI ID:1481440

Wang, Tingting ^[1]; Zeng, Zhongming ^[1]; Cao, Lingyun ^[1]; Li, Zhe ^[2]; Hu, Xuefu ^[1]; An, Bing ^[1];

^[1]; Lin, Wenbin ^[3]

Collaborative Innovation Center of Chemistry for Energy Materials State Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 P. R. China
Collaborative Innovation Center of Chemistry for Energy Materials State Key Laboratory of Physical Chemistry of Solid Surfaces Department of Chemistry College of Chemistry and Chemical Engineering Xiamen University Xiamen 361005 P. R. China, Department of Chemistry University of Chicago Chicago Illinois 60637 USA
Department of Chemistry University of Chicago Chicago Illinois 60637 USA

Abstract On‐location electrochemical generation of H ₂ O ₂ is of great current interest. Herein, selective two‐electron reduction of O ₂ to H ₂ O ₂ by a single [Ni ^II (H ₂ O) ₆ ] ²⁺ cation that is dynamically associated with a negatively charged metal–organic layer (MOL) by hydrogen bonding and coulombic interactions is reported. In contrast, Ni ^II centers covalently immobilized on the MOL reduce O ₂ to H ₂ O in a four‐ electron process. Oxygen adsorption by [Ni ^II (H ₂ O) ₆ ] ²⁺ followed by two‐electron reduction generates neutral [Ni ^II (H ₂ O) ₄ (OH)(OOH)] ⁰ , which momentarily disconnects from the negatively charged MOL to avoid the injection of additional electrons. Release of H ₂ O ₂ from [Ni ^II (H ₂ O) ₄ (OH)(OOH)] ⁰ regenerates [Ni ^II (H ₂ O) ₆ ] ²⁺ , which regains affinity to the MOL. Such dynamically associated Ni ^II single‐metal electrocatalysts ensure high selectivity and represent a new strategy for generating selective catalysts for electrochemical production of important chemicals.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1481440

Journal Information:: Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Journal Issue: 64 Vol. 24; ISSN 0947-6539

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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