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Title: Thin Film RuO 2 Lithiation: Fast Lithium-Ion Diffusion along the Interface

Authors:
ORCiD logo [1];  [2];  [3];  [2]; ORCiD logo [2];  [1]; ORCiD logo [4]; ORCiD logo [3]
  1. Department of Materials Science and Engineering, Northwestern University, Evanston IL 60208 USA, NU ANCE Center, Northwestern University, Evanston IL 60208 USA, Department of Materials Science and Engineering, Clemson University, Clemson SC 29634 USA
  2. Department of Materials Science and Engineering, Northwestern University, Evanston IL 60208 USA
  3. Department of Materials Science and Engineering, Northwestern University, Evanston IL 60208 USA, NU ANCE Center, Northwestern University, Evanston IL 60208 USA
  4. Department of Materials Science and Engineering, Northwestern University, Evanston IL 60208 USA, NU ANCE Center, Northwestern University, Evanston IL 60208 USA, State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Nanostructure Research Centre, Wuhan University of Technology, Wuhan 430070 China
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1481438
Grant/Contract Number:  
DEAC02-06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 28 Journal Issue: 52; Journal ID: ISSN 1616-301X
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Kim, Sungkyu, Evmenenko, Guennadi, Xu, Yaobin, Buchholz, Donald Bruce, Bedzyk, Michael, He, Kai, Wu, Jinsong, and Dravid, Vinayak P. Thin Film RuO 2 Lithiation: Fast Lithium-Ion Diffusion along the Interface. Germany: N. p., 2018. Web. doi:10.1002/adfm.201805723.
Kim, Sungkyu, Evmenenko, Guennadi, Xu, Yaobin, Buchholz, Donald Bruce, Bedzyk, Michael, He, Kai, Wu, Jinsong, & Dravid, Vinayak P. Thin Film RuO 2 Lithiation: Fast Lithium-Ion Diffusion along the Interface. Germany. doi:10.1002/adfm.201805723.
Kim, Sungkyu, Evmenenko, Guennadi, Xu, Yaobin, Buchholz, Donald Bruce, Bedzyk, Michael, He, Kai, Wu, Jinsong, and Dravid, Vinayak P. Fri . "Thin Film RuO 2 Lithiation: Fast Lithium-Ion Diffusion along the Interface". Germany. doi:10.1002/adfm.201805723.
@article{osti_1481438,
title = {Thin Film RuO 2 Lithiation: Fast Lithium-Ion Diffusion along the Interface},
author = {Kim, Sungkyu and Evmenenko, Guennadi and Xu, Yaobin and Buchholz, Donald Bruce and Bedzyk, Michael and He, Kai and Wu, Jinsong and Dravid, Vinayak P.},
abstractNote = {},
doi = {10.1002/adfm.201805723},
journal = {Advanced Functional Materials},
number = 52,
volume = 28,
place = {Germany},
year = {2018},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1002/adfm.201805723

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Works referenced in this record:

Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics
journal, January 2017

  • Evmenenko, Guennadi; Fister, Timothy T.; Buchholz, D. Bruce
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 30
  • DOI: 10.1039/C7CP02448G

6 Li MAS NMR Investigation of Electrochemical Lithiation of RuO 2 : Evidence for an Interfacial Storage Mechanism
journal, March 2009

  • Bekaert, Emilie; Balaya, Palani; Murugavel, Sevi
  • Chemistry of Materials, Vol. 21, Issue 5
  • DOI: 10.1021/cm8028005

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Novel Modified Graphite as Anode Material for Lithium-Ion Batteries
journal, January 2002

  • Pan, Qinmin; Guo, Kunkun; Wang, Lingzhi
  • Journal of The Electrochemical Society, Vol. 149, Issue 9
  • DOI: 10.1149/1.1499499

Recent developments in nanostructured anode materials for rechargeable lithium-ion batteries
journal, January 2011

  • Ji, Liwen; Lin, Zhan; Alcoutlabi, Mataz
  • Energy & Environmental Science, Vol. 4, Issue 8, p. 2682-2699
  • DOI: 10.1039/c0ee00699h

Recent development and application of Li4Ti5O12 as anode material of lithium ion battery
journal, September 2010

  • Yi, Ting-Feng; Jiang, Li-Juan; Shu, J.
  • Journal of Physics and Chemistry of Solids, Vol. 71, Issue 9, p. 1236-1242
  • DOI: 10.1016/j.jpcs.2010.05.001

Co-refinement of multiple-contrast neutron/X-ray reflectivity data using MOTOFIT
journal, March 2006


Electrochemistry of Selenium with Sodium and Lithium: Kinetics and Reaction Mechanism
journal, August 2016


Highly Reversible Conversion-Type FeOF Composite Electrode with Extended Lithium Insertion by Atomic Layer Deposition LiPON Protection
journal, October 2017


The role of graphene for electrochemical energy storage
journal, December 2014

  • Raccichini, Rinaldo; Varzi, Alberto; Passerini, Stefano
  • Nature Materials, Vol. 14, Issue 3
  • DOI: 10.1038/nmat4170

Probing the Additional Capacity and Reaction Mechanism of the RuO 2 Anode in Lithium Rechargeable Batteries
journal, June 2015


Strain Coupling of Conversion-type Fe 3 O 4 Thin Films for Lithium Ion Batteries
journal, May 2017

  • Hwang, Sooyeon; Meng, Qingping; Chen, Ping-Fan
  • Angewandte Chemie International Edition, Vol. 56, Issue 27
  • DOI: 10.1002/anie.201703168

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

Interfacial strain effects on lithium diffusion pathways in the spinel solid electrolyte Li-doped MgAl 2 O 4
journal, April 2018


Fabrication and characterization of SnO2–RuO2 composite anode thin film for lithium ion batteries
journal, November 2004


Solid Electrolyte Lithium Phosphous Oxynitride as a Protective Nanocladding Layer for 3D High-Capacity Conversion Electrodes
journal, January 2016


Expanded graphite as superior anode for sodium-ion batteries
journal, June 2014

  • Wen, Yang; He, Kai; Zhu, Yujie
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5033

Morphological Evolution of Multilayer Ni/NiO Thin Film Electrodes during Lithiation
journal, July 2016

  • Evmenenko, Guennadi; Fister, Timothy T.; Buchholz, D. Bruce
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 31
  • DOI: 10.1021/acsami.6b05040

Real-Time Observations of Interfacial Lithiation in a Metal Silicide Thin Film
journal, October 2012

  • Fister, Tim T.; Long, Brandon R.; Gewirth, Andrew A.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 42
  • DOI: 10.1021/jp305465j

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Comparison of Storage Mechanisms in RuO 2 , SnO 2 , and SnS 2 for Lithium-Ion Battery Anode Materials
journal, January 2016

  • Hassan, Ayorinde S.; Moyer, Kathleen; Ramachandran, B. Ramu
  • The Journal of Physical Chemistry C, Vol. 120, Issue 4
  • DOI: 10.1021/acs.jpcc.5b09078

Origin of Fracture-Resistance to Large Volume Change in Cu-Substituted Co 3 O 4 Electrodes
journal, December 2017


Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity
journal, August 2003


In Situ Transmission Electron Microscopy Study of Electrochemical Lithiation and Delithiation Cycling of the Conversion Anode RuO 2
journal, June 2013

  • Gregorczyk, Keith E.; Liu, Yang; Sullivan, John P.
  • ACS Nano, Vol. 7, Issue 7
  • DOI: 10.1021/nn402451s

Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005

  • Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
  • Nature Materials, Vol. 4, Issue 5, p. 366-377
  • DOI: 10.1038/nmat1368

Fabrication of 3D Core–Shell Multiwalled Carbon Nanotube@RuO 2 Lithium-Ion Battery Electrodes through a RuO 2 Atomic Layer Deposition Process
journal, December 2014

  • Gregorczyk, Keith E.; Kozen, Alexander C.; Chen, Xinyi
  • ACS Nano, Vol. 9, Issue 1
  • DOI: 10.1021/nn505644q

Reversible Li-Ion Conversion Reaction for a Ti x Ge Alloy in a Ti/Ge Multilayer
journal, February 2017

  • Chen, Xiao; Fister, Tim T.; Esbenshade, Jennifer
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 9
  • DOI: 10.1021/acsami.6b14783

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Track batteries degrading in real time
journal, June 2017

  • Mai, Liqiang; Yan, Mengyu; Zhao, Yunlong
  • Nature, Vol. 546, Issue 7659
  • DOI: 10.1038/546469a

Chemical and Electrochemical Li-Insertion into the Li 4 Ti 5 O 12 Spinel
journal, December 2004

  • Aldon, L.; Kubiak, P.; Womes, M.
  • Chemistry of Materials, Vol. 16, Issue 26
  • DOI: 10.1021/cm0488837

Enhanced Potential of Amorphous Electrode Materials: Case Study of RuO2
journal, February 2008


Microstructure of Ruthenium Dioxide Films Grown on α–Al 2 O 3 (0001), α–Al 2 O 3 (1 1 02), and SrTiO 3 (100) Using Reactive Sputtering
journal, April 1997

  • Wang, Q.; Gilmer, Dave; Fan, Yue
  • Journal of Materials Research, Vol. 12, Issue 4
  • DOI: 10.1557/JMR.1997.0139

Alkaline earth metal vanadates as sodium-ion battery anodes
journal, September 2017


Zero-Strain Insertion Material of Li[Li[sub 1∕3]Ti[sub 5∕3]]O[sub 4] for Rechargeable Lithium Cells
journal, January 1995

  • Ohzuku, Tsutomu
  • Journal of The Electrochemical Society, Vol. 142, Issue 5
  • DOI: 10.1149/1.2048592

Three-Dimensionally Ordered Macroporous Li4Ti5O12:  Effect of Wall Structure on Electrochemical Properties
journal, December 2005

  • Sorensen, Erin M.; Barry, Scott J.; Jung, Ha-Kyun
  • Chemistry of Materials, Vol. 18, Issue 2, p. 482-489
  • DOI: 10.1021/cm052203y

Dimensionally Controlled Lithiation of Chromium Oxide
journal, December 2015


Atomic resolution observation of conversion-type anode RuO 2 during the first electrochemical lithiation
journal, March 2015


Dynamic imaging of metastable reaction pathways in lithiated cobalt oxide electrodes
journal, February 2018


PEDOT Encapsulated FeOF Nanorod Cathodes for High Energy Lithium-Ion Batteries
journal, October 2015