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Title: Irradiated recycled plastic as a concrete additive for improved chemo-mechanical properties and lower carbon footprint

Abstract

Concrete production contributes heavily to greenhouse gas emissions, thus a need exists for the development of durable and sustainable concrete with a lower carbon footprint. This can be achieved when cement is partially replaced with another material, such as waste plastic, though normally with a tradeoff in compressive strength. This study discusses progress toward a high/medium strength concrete with a dense, cementitious matrix that contains an irradiated plastic additive, recovering the compressive strength while displacing concrete with waste materials to reduce greenhouse gas generation. Compressive strength tests showed that the addition of high dose (100 kGy) irradiated plastic in multiple concretes resulted in increased compressive strength as compared to samples containing regular, nonirradiated plastic. This suggests that irradiating plastic at a high dose is a viable potential solution for regaining some of the strength that is lost when plastic is added to cement paste. X-ray Diffraction (XRD), Backscattered Electron Microscopy (BSE), and X-ray microtomography explain the mechanisms for strength retention when using irradiated plastic as a filler for cement paste. By partially replacing Portland cement with a recycled waste plastic, this design may have a potential to contribute to reduced carbon emissions when scaled to the level of mass concretemore » production.« less

Authors:
 [1];  [1];  [1];  [2];  [1];  [1];  [1]
  1. Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1481413
Alternate Identifier(s):
OSTI ID: 1549365
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Waste Management
Additional Journal Information:
Journal Volume: 71; Journal Issue: C; Journal ID: ISSN 0956-053X
Publisher:
International Waste Working Group
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING; Irradiated plastic; Additives; Cement paste; Microstructure; Pore structure

Citation Formats

Schaefer, Carolyn E., Kupwade-Patil, Kunal, Ortega, Michael, Soriano, Carmen, Buyukozturk, Oral, White, Anne E., and Short, Michael P. Irradiated recycled plastic as a concrete additive for improved chemo-mechanical properties and lower carbon footprint. United States: N. p., 2017. Web. doi:10.1016/j.wasman.2017.09.033.
Schaefer, Carolyn E., Kupwade-Patil, Kunal, Ortega, Michael, Soriano, Carmen, Buyukozturk, Oral, White, Anne E., & Short, Michael P. Irradiated recycled plastic as a concrete additive for improved chemo-mechanical properties and lower carbon footprint. United States. https://doi.org/10.1016/j.wasman.2017.09.033
Schaefer, Carolyn E., Kupwade-Patil, Kunal, Ortega, Michael, Soriano, Carmen, Buyukozturk, Oral, White, Anne E., and Short, Michael P. Mon . "Irradiated recycled plastic as a concrete additive for improved chemo-mechanical properties and lower carbon footprint". United States. https://doi.org/10.1016/j.wasman.2017.09.033. https://www.osti.gov/servlets/purl/1481413.
@article{osti_1481413,
title = {Irradiated recycled plastic as a concrete additive for improved chemo-mechanical properties and lower carbon footprint},
author = {Schaefer, Carolyn E. and Kupwade-Patil, Kunal and Ortega, Michael and Soriano, Carmen and Buyukozturk, Oral and White, Anne E. and Short, Michael P.},
abstractNote = {Concrete production contributes heavily to greenhouse gas emissions, thus a need exists for the development of durable and sustainable concrete with a lower carbon footprint. This can be achieved when cement is partially replaced with another material, such as waste plastic, though normally with a tradeoff in compressive strength. This study discusses progress toward a high/medium strength concrete with a dense, cementitious matrix that contains an irradiated plastic additive, recovering the compressive strength while displacing concrete with waste materials to reduce greenhouse gas generation. Compressive strength tests showed that the addition of high dose (100 kGy) irradiated plastic in multiple concretes resulted in increased compressive strength as compared to samples containing regular, nonirradiated plastic. This suggests that irradiating plastic at a high dose is a viable potential solution for regaining some of the strength that is lost when plastic is added to cement paste. X-ray Diffraction (XRD), Backscattered Electron Microscopy (BSE), and X-ray microtomography explain the mechanisms for strength retention when using irradiated plastic as a filler for cement paste. By partially replacing Portland cement with a recycled waste plastic, this design may have a potential to contribute to reduced carbon emissions when scaled to the level of mass concrete production.},
doi = {10.1016/j.wasman.2017.09.033},
journal = {Waste Management},
number = C,
volume = 71,
place = {United States},
year = {2017},
month = {10}
}

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Works referenced in this record:

Recycling and recovery routes of plastic solid waste (PSW): A review
journal, October 2009


A review on emission analysis in cement industries
journal, June 2011

  • Ali, M. B.; Saidur, R.; Hossain, M. S.
  • Renewable and Sustainable Energy Reviews, Vol. 15, Issue 5
  • DOI: 10.1016/j.rser.2011.02.014

Novel lightweight concrete containing manufactured plastic aggregate
journal, September 2017


A 1° × 1° distribution of carbon dioxide emissions from fossil fuel consumption and cement manufacture, 1950-1990
journal, September 1996

  • Andres, Robert J.; Marland, Gregg; Fung, Inez
  • Global Biogeochemical Cycles, Vol. 10, Issue 3
  • DOI: 10.1029/96GB01523

Improvement of the mechanical properties of glass fibre reinforced plastic waste powder filled concrete
journal, April 2010


Effects on Mechanical Properties of Recycled PET in Cement-Based Composites
journal, January 2013

  • Ávila Córdoba, Liliana; Martínez-Barrera, Gonzalo; Barrera Díaz, Carlos
  • International Journal of Polymer Science, Vol. 2013
  • DOI: 10.1155/2013/763276

Use of selected waste materials in concrete mixes
journal, January 2007


Effects of waste PET bottles aggregate on the properties of concrete
journal, April 2005


Characteristics of mortar and concrete containing fine aggregate manufactured from recycled waste polyethylene terephthalate bottles
journal, August 2009


Recycled polyolefins waste as aggregates for lightweight concrete
journal, December 2016


Investigation on the use of foamed plastic waste as natural aggregates replacement in lightweight mortar
journal, August 2016


Emissions from Ships
journal, October 1997


Phase relations in the system CaOAl2O3SiO2H2O relevant to metakaolin - calcium hydroxide hydration
journal, May 1993


Mechanical and fracture characteristics of self-compacting concretes containing different percentage of plastic waste powder
journal, June 2017


Use of recycled plastics in concrete: A critical review
journal, May 2016


A thermodynamic and kinetic model for paste–aggregate interactions and the alkali–silica reaction
journal, October 2015


Physical and mechanical properties of mortars containing PET and PC waste aggregates
journal, November 2010


Recycled plastic aggregate in mortars composition: Effect on physical and mechanical properties
journal, December 2013


The effects of irradiation on physicochemical characteristics of PET packaging film
journal, December 2004


Crystallization of Polyethyleneterephthalate
journal, August 1995


Thermal behavior of gamma-irradiated amorphous poly (ethylene terephthalate) films
journal, August 2006

  • Kattan, Munzer
  • Polymer Engineering & Science, Vol. 46, Issue 10
  • DOI: 10.1002/pen.20616

Material and structural performance evaluation of recycled PET fiber reinforced concrete
journal, March 2010


Concrete reinforced with irradiated nylon fibers
journal, February 2006

  • Martínez-Barrera, Gonzalo; Menchaca-Campos, Carmina; Hernández-López, Susana
  • Journal of Materials Research, Vol. 21, Issue 2
  • DOI: 10.1557/jmr.2006.0058

Mechanical properties of polypropylene-fiber reinforced concrete after gamma irradiation
journal, May 2011

  • Martínez-Barrera, Gonzalo; Ureña-Nuñez, Fernando; Gencel, Osman
  • Composites Part A: Applied Science and Manufacturing, Vol. 42, Issue 5
  • DOI: 10.1016/j.compositesa.2011.01.016

Mechanical improvement of concrete by irradiated polypropylene fibers
journal, January 2005

  • Martínez-Barrera, Gonzalo; Vigueras-Santiago, Enrique; Hernández-López, Susana
  • Polymer Engineering & Science, Vol. 45, Issue 10
  • DOI: 10.1002/pen.20418

Valorization of post-consumer waste plastic in cementitious concrete composites
journal, January 2007


The influence of electron-beam irradiation on some mechanical properties of commercial multilayer flexible packaging materials
journal, July 2009


Mechanical properties of recycled PET fibers in concrete
journal, July 2012


Quantification of tortuosity in hardened cement pastes using synchrotron-based X-ray computed microtomography
journal, June 2009


Effect of silica fume, metakaolin, and low-calcium fly ash on chemical resistance of concrete
journal, December 2001


Waste polyethylene terephthalate as an aggregate in concrete
journal, February 2013


Use of plastic waste as aggregate in cement mortar and concrete preparation: A review
journal, September 2012


Backscattered electron imaging of cementitious microstructures: understanding and quantification
journal, November 2004


Use of recycled plastic in concrete: A review
journal, January 2008


Recycling of plastic solid waste: A state of art review and future applications
journal, April 2017


C ARBON D IOXIDE E MISSIONS FROM THE G LOBAL C EMENT I NDUSTRY
journal, November 2001


Works referencing / citing this record:

Risk Assessment in a Materials Recycling Facility: Perspectives for Reducing Operational Issues
journal, December 2018


Effect of Irradiated and Non-Irradiated Waste PET Based Cementitious Grouts on Flexural Strength of Semi-Flexible Pavement
journal, December 2019

  • Khan, Muhammad Imran; Huat, Huang Yong; Dun, Mohammad Haziq bin Muhamad
  • Materials, Vol. 12, Issue 24
  • DOI: 10.3390/ma12244133

Effect of Irradiated and Non-Irradiated Waste PET Based Cementitious Grouts on Flexural Strength of Semi-Flexible Pavement
journal, December 2019

  • Khan, Muhammad Imran; Huat, Huang Yong; Dun, Mohammad Haziq bin Muhamad
  • Materials, Vol. 12, Issue 24
  • DOI: 10.3390/ma12244133