From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal–Organic Frameworks

Islamoglu, Timur; Ray, Debmalya; Li, Peng; Majewski, Marek B.; Akpinar, Isil; Zhang, Xuan; Cramer, Christopher J.; Gagliardi, Laura; Farha, Omar K.

doi:10.1021/acs.inorgchem.8b01748

Title: From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal–Organic Frameworks

Journal Article · 08 October 2018 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.8b01748 · OSTI ID:1481367

^[1]; Ray, Debmalya ^[2];

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^[3]; Akpinar, Isil ^[3];

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Northwestern Univ., Evanston, IL (United States). Department of Chemistry; University of Notre Dame
Univ. of Minnesota, Minneapolis, MN (United States). Department of Chemistry, Chemical Theory Center and Minnesota Supercomputing Institute
Northwestern Univ., Evanston, IL (United States). Department of Chemistry
Northwestern Univ., Evanston, IL (United States). Department of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia)

In this study, isostructural metal-organic frameworks (MOFs) have been prepared from a variety of metal-oxide clusters, including transition metals, lanthanides, and actinides. Experimental and calculated shifts in O–H stretching frequencies for hydroxyl groups associated with the metal-oxide nodes reveal varying electronic properties for these units, thereby offering opportunities to tune support effects for other materials deposited onto these nodes.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Contributing Organization:: Univ. of Minnesota, Minneapolis, MN (United States)

Grant/Contract Number:: NA0003763; SC0012702

OSTI ID:: 1481367

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 21 Vol. 57; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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