Borate melt structure: Temperature-dependent B–O bond lengths and coordination numbers from high-energy X-ray diffraction

Alderman, Oliver L.  G.; Benmore, Chris J.; Lin, Alex; Tamalonis, Anthony; Weber, J. K.  Richard

doi:10.1111/jace.15529

Title: Borate melt structure: Temperature-dependent B–O bond lengths and coordination numbers from high-energy X-ray diffraction

Journal Article · 04 March 2018 · Journal of the American Ceramic Society

DOI: https://doi.org/10.1111/jace.15529 · OSTI ID:1480859

^[1]; Benmore, Chris J. ^[2]; Lin, Alex ^[3]; Tamalonis, Anthony ^[4]; Weber, J. K. Richard ^[1]

Materials Development, Inc., Arlington Heights, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-Ray Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-Ray Science Division
Materials Development, Inc., Arlington Heights, IL (United States); Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering, McCormick School of Engineering and Applied Science
Materials Development, Inc., Arlington Heights, IL (United States)

Borate melts containing <20 mol% Na₂O have been studied using high-energy synchrotron X-ray diffraction. Temperature dependencies of the mean B–O bond lengths are shown to vary strongly with soda content, by comparison to previous measurements on liquid B₂O₃ and Na₂B₄O₇. Whereas in liquid B₂O₃ linear thermal expansion of the BØ₃ units is observed, with coefficient α_BO = 3.7(2) × 10^-6 K^-1, this expansion is apparently slightly suppressed in melts containing <20 mol% Na₂O, and is dramatically reversed at the diborate composition. These effects are interpreted in terms of changes in the mean B–O coordination number, where the reaction BØ₄- + BØ₃ ⇌ BØ₃ + BØ₂O- shifts to the right with increasing temperature. The empirical bond-valence relationship is used to convert measured bond lengths, r_BO, to coordination numbers, n_BO, including a correction for the expected thermal expansion. This method is more accurate and precise than direct determination of n_BO from peak areas in the radial distribution functions. Gradients of Δn_BO/ΔT = -3.4(3) × 10^-4 K^-1 close to the diborate composition, and Δn_BO/ΔT = -0.3(1) × 10^-4 K^-1 for a 13(3) mol% Na₂O melt are observed, in reasonable agreement with Raman spectroscopic observations and thermodynamic modeling, with some quantitative differences. These observations go toward explaining isothermal viscosity maxima and changes in fragility across the sodium borate system.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357; SC0007564; SC0015241

OSTI ID:: 1480859

Alternate ID(s):: OSTI ID: 1429154

Journal Information:: Journal of the American Ceramic Society, Journal Name: Journal of the American Ceramic Society Journal Issue: 8 Vol. 101; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (78)

Separating the effects of composition and fictive temperature on Al and B coordination in Ca, La, Y aluminosilicate, aluminoborosilicate and aluminoborate glasses Morin, Elizabeth I.; Stebbins, Jonathan F. Journal of Non-Crystalline Solids, Vol. 432 https://doi.org/10.1016/j.jnoncrysol.2015.10.035	journal	January 2016
A molecular dynamics and neutron diffraction study of the structure of Na2OB2O3 melts Umesaki, Norimasa; Kita, Yoshifumi; Kirihara, Tadashi Journal of Non-Crystalline Solids, Vol. 177 https://doi.org/10.1016/0022-3093(94)90531-2	journal	November 1994
Spectral Absorption Coefficient of Molten Aluminum Oxide from.0.385 to 0.780 mum Weber, J. K. Richard; Krishnan, Shankar; Anderson, Collin D. Journal of the American Ceramic Society, Vol. 78, Issue 3 https://doi.org/10.1111/j.1151-2916.1995.tb08218.x	journal	March 1995
High Temperature Vaporization Behavior of Oxides. I. Alkali Metal Binary Oxides Lamoreaux, R. H.; Hildenbrand, D. L. Journal of Physical and Chemical Reference Data, Vol. 13, Issue 1, p. 151-173 https://doi.org/10.1063/1.555706	journal	January 1984
Borate melt structure: a short review Alderman, Oliver Physics and Chemistry of Glasses: European Journal of Glass Science and Technology Part B, Vol. 59, Issue 1 https://doi.org/10.13036/17533562.59.1.016	journal	February 2018
Boron Coordination in Rapidly Cooled and in Annealed Aluminum Borosilicate Glass Fibers Gupta, Prabhat K.; Lur, Ming L.; Bray, Philip J. Journal of the American Ceramic Society, Vol. 68, Issue 3 https://doi.org/10.1111/j.1151-2916.1985.tb09639.x	journal	March 1985
CO2 Retention in High-Alkali Borate Glasses Martin, Steve W.; Cooper, Emanuel I.; Angell, C. Austen Journal of the American Ceramic Society, Vol. 66, Issue 9 https://doi.org/10.1111/j.1151-2916.1983.tb10622.x	journal	September 1983
Temperature Effects on Structure and Dynamics in Borate and Borosilicate Liquids: High-Resolution and High-Temperature NMR Results Stebbins, Jonathan F.; Ellsworth, Susan E. Journal of the American Ceramic Society, Vol. 79, Issue 9 https://doi.org/10.1111/j.1151-2916.1996.tb08969.x	journal	September 1996
Structure and triclustering in Ba-Al-O glass Skinner, Lawrie B.; Barnes, Adrian C.; Salmon, Philip S. Physical Review B, Vol. 85, Issue 6 https://doi.org/10.1103/PhysRevB.85.064201	journal	February 2012
Strontium borate glass: potential biomaterial for bone regeneration Pan, H. B.; Zhao, X. L.; Zhang, X. Journal of The Royal Society Interface, Vol. 7, Issue 48 https://doi.org/10.1098/rsif.2009.0504	journal	December 2009
Temperature-induced boron coordination change in alkali borate glasses and melts Majérus, Odile; Cormier, Laurent; Calas, Georges Physical Review B, Vol. 67, Issue 2 https://doi.org/10.1103/PhysRevB.67.024210	journal	January 2003
Structure–composition trends in multicomponent borosilicate-based glasses deduced from molecular dynamics simulations with improved B–O and P–O force fields Stevensson, Baltzar; Yu, Yang; Edén, Mattias Physical Chemistry Chemical Physics, Vol. 20, Issue 12 https://doi.org/10.1039/C7CP08593A	journal	January 2018
First-principles study of a sodium borosilicate glass-former. II. The glass state Pedesseau, Laurent; Ispas, Simona; Kob, Walter Physical Review B, Vol. 91, Issue 13 https://doi.org/10.1103/PhysRevB.91.134202	journal	April 2015
Supercooled Barium Boric Oxide Melts: X-Ray Diffraction Measurements and Glass Formation Matsumura, Seiichi; Watanabe, Masahito; Mizuno, Akitoshi Journal of the American Ceramic Society, Vol. 90, Issue 3 https://doi.org/10.1111/j.1551-2916.2006.01475.x	journal	March 2007
Two-dimensional detector software: From real detector to idealised image or two-theta scan Hammersley, A. P.; Svensson, S. O.; Hanfland, M. High Pressure Research, Vol. 14, Issue 4-6, p. 235-248 https://doi.org/10.1080/08957959608201408	journal	January 1996
Laser hearth melt processing of ceramic materials Richard Weber, J. K.; Felten, J. J.; Nordine, Paul C. Review of Scientific Instruments, Vol. 67, Issue 2 https://doi.org/10.1063/1.1146631	journal	February 1996
Structural investigation of sodium borate glasses and melts by Raman spectroscopy. III. Relation between the rearrangement of super-structures and the properties of glass Yano, Tetsuji; Kunimine, Noboru; Shibata, Shuichi Journal of Non-Crystalline Solids, Vol. 321, Issue 3 https://doi.org/10.1016/S0022-3093(03)00160-1	journal	July 2003
Structure of glasses and melts in the Na2O-B2O3 system from high-temperature Raman spectroscopic data: I. Influence of temperature on the local structure of glasses and melts Osipov, A. A.; Osipova, L. M. Glass Physics and Chemistry, Vol. 35, Issue 2 https://doi.org/10.1134/S1087659609020011	journal	April 2009
Statistical mechanical model of boron coordination Araujo, Roger J. Journal of Non-Crystalline Solids, Vol. 42, Issue 1-3 https://doi.org/10.1016/0022-3093(80)90023-X	journal	October 1980
Borosilicate Glasses Abe, Tosio Journal of the American Ceramic Society, Vol. 35, Issue 11 https://doi.org/10.1111/j.1151-2916.1952.tb13051.x	journal	November 1952
Development and operating experience of a short-period superconducting undulator at the Advanced Photon Source Ivanyushenkov, Y.; Harkay, K.; Abliz, M. Physical Review Special Topics - Accelerators and Beams, Vol. 18, Issue 4 https://doi.org/10.1103/PhysRevSTAB.18.040703	journal	April 2015
Bond-valence parameters for solids Brese, N. E.; O'Keeffe, M. Acta Crystallographica Section B Structural Science, Vol. 47, Issue 2 https://doi.org/10.1107/S0108768190011041	journal	April 1991
First principles study of a sodium borosilicate glass-former II: The glass state Pedesseau, Laurent; Ispas, Simona; Kob, Walter arXiv https://doi.org/10.48550/arxiv.1408.5014	text	January 2014
Sealants for solid oxide fuel cells Fergus, Jeffrey W. Journal of Power Sources, Vol. 147, Issue 1-2, p. 46-57 https://doi.org/10.1016/j.jpowsour.2005.05.002	journal	September 2005
The thermodynamic origin of compositional nanoheterogeneity in glasses Vedishcheva, Natalia M.; Wright, Adrian C. Physics and Chemistry of Glasses: European Journal of Glass Science and Technology Part B, Vol. 58, Issue 4 https://doi.org/10.13036/17533562.58.4.150	journal	August 2017
Structure of M2O–B2O3 (M: Na and K) glasses and melts by neutron diffraction Handa, K.; Kita, Y.; Kohara, S. Journal of Physics and Chemistry of Solids, Vol. 60, Issue 8-9 https://doi.org/10.1016/S0022-3697(99)00143-2	journal	September 1999
Area detector corrections for high quality synchrotron X-ray structure factor measurements Skinner, Lawrie B.; Benmore, Chris J.; Parise, John B. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 662, Issue 1 https://doi.org/10.1016/j.nima.2011.09.031	journal	January 2012
Structural design of sealing glasses Brow, Richard K.; Tallant, David R. Journal of Non-Crystalline Solids, Vol. 222 https://doi.org/10.1016/S0022-3093(97)90142-3	journal	December 1997
Statistical mechanics of chemical disorder: application to alkali borate glasses Araujo, R. J. Journal of Non-Crystalline Solids, Vol. 58, Issue 2-3 https://doi.org/10.1016/0022-3093(83)90024-8	journal	November 1983
Structural investigation of sodium borate glasses and melts by Raman spectroscopy. II. Conversion between BO4 and BO2O− units at high temperature Yano, Tetsuji; Kunimine, Noboru; Shibata, Shuichi Journal of Non-Crystalline Solids, Vol. 321, Issue 3 https://doi.org/10.1016/S0022-3093(03)00159-5	journal	July 2003
High-temperature borate crystal chemistry Bubnova, R. S.; Filatov, S. K. Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue a1 https://doi.org/10.1107/s0108767308084122	journal	August 2008
Temperature-Driven Structural Transitions in Molten Sodium Borates Na ₂ O–B ₂ O ₃ : X-ray Diffraction, Thermodynamic Modeling, and Implications for Topological Constraint Theory Alderman, O. L. G.; Liška, M.; Macháček, J. The Journal of Physical Chemistry C, Vol. 120, Issue 1 https://doi.org/10.1021/acs.jpcc.5b10277	journal	December 2015
The thermodynamic properties of oxide glasses and glass-forming liquids and their chemical structure Shakhmatkin, Boris A.; Vedishcheva, Natalia M.; Shultz, Mikhail M. Journal of Non-Crystalline Solids, Vol. 177 https://doi.org/10.1016/0022-3093(94)90538-X	journal	November 1994
Temperature dependent structural changes in borate, borosilicate and boroaluminate liquids: high-resolution 11B, 29Si and 27Al NMR studies Sen, S.; Xu, Z.; Stebbins, J. F. Journal of Non-Crystalline Solids, Vol. 226, Issue 1-2 https://doi.org/10.1016/S0022-3093(97)00491-2	journal	May 1998
Temperature induced structural changes and transport mechanisms in borate, borosilicate and boroaluminate liquids: high-resolution and high-temperature NMR results Sen, S. Journal of Non-Crystalline Solids, Vol. 253, Issue 1-3 https://doi.org/10.1016/S0022-3093(99)00346-4	journal	August 1999
Thermodynamic optimization of the Na2O-B2O3 pseudo-binary system Wang, Chong; Yu, Hao; Liu, Huashan Journal of Phase Equilibria, Vol. 24, Issue 1 https://doi.org/10.1007/s11669-003-0003-7	journal	February 2003
FOURIER ANALYSIS OF X-RAY PATTERNS OF VITREOUS SiO ₂ AND B ₂ O ₂ Warren, B. E.; Krutter, H.; Morningstar, O. Journal of the American Ceramic Society, Vol. 19, Issue 1-12 https://doi.org/10.1111/j.1151-2916.1936.tb19822.x	journal	January 1936
Medium-Range Structural Organization of Phosphorus-Bearing Borosilicate Glasses Revealed by Advanced Solid-State NMR Experiments and MD Simulations: Consequences of B/Si Substitutions Yu, Yang; Stevensson, Baltzar; Edén, Mattias The Journal of Physical Chemistry B, Vol. 121, Issue 41 https://doi.org/10.1021/acs.jpcb.7b06654	journal	October 2017
High-temperature borate crystal chemistry Bubnova, Rimma S.; Filatov, Stanislav K. Zeitschrift für Kristallographie - Crystalline Materials, Vol. 228, Issue 9 https://doi.org/10.1524/zkri.2013.1646	journal	January 2013
X-Ray Diffraction Study of Soda-Boric Oxide Glass * Biscoe, J.; Warren, B. E. Journal of the American Ceramic Society, Vol. 21, Issue 8 https://doi.org/10.1111/j.1151-2916.1938.tb15777.x	journal	August 1938
High‐Temperature Vaporization Behavior of Oxides II. Oxides of Be, Mg, Ca, Sr, Ba, B, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Zn, Cd, and Hg Lamoreaux, R. H.; Hildenbrand, D. L.; Brewer, L. Journal of Physical and Chemical Reference Data, Vol. 16, Issue 3 https://doi.org/10.1063/1.555799	journal	July 1987
Structure model and properties of alkali borate melts Zhang, Z.; Reddy, R. G. Mineral Processing and Extractive Metallurgy, Vol. 114, Issue 3 https://doi.org/10.1179/037195505X63394	journal	September 2005
The potential of NMR techniques for studies of the effects of thermal history on glass structure Bray, P. J.; Holupka, E. J. Journal of Non-Crystalline Solids, Vol. 71, Issue 1-3 https://doi.org/10.1016/0022-3093(85)90312-6	journal	May 1985
Heats of Solution, Density, and Refractive Index Changes in Sodium Borate Glasses Subjected to High Pressure Stewart, Daniel R.; Rindone, Guy E.; Dachille, Frank Journal of the American Ceramic Society, Vol. 50, Issue 9 https://doi.org/10.1111/j.1151-2916.1967.tb15163.x	journal	September 1967
A comparison of various commonly used correlation functions for describing total scattering Keen, David A. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889800019993	journal	April 2001
First-Principles Molecular Dynamics Simulation and Conductivity Measurements of a Molten x Li ₂ O–(1 – x )B ₂ O ₃ System Ohkubo, Takahiro; Tsuchida, Eiji; Gobet, Mallory The Journal of Physical Chemistry B, Vol. 117, Issue 18 https://doi.org/10.1021/jp312486m	journal	April 2013
A neutron and X-ray diffraction study of Ca–Mg–Cu metallic glasses Barney, Emma R.; Hannon, Alex C.; Senkov, Oleg N. Intermetallics, Vol. 19, Issue 7 https://doi.org/10.1016/j.intermet.2011.02.001	journal	July 2011
High energy XRD investigations of liquids Neuefeind, J. Journal of Molecular Liquids, Vol. 98-99 https://doi.org/10.1016/S0167-7322(01)00312-9	journal	May 2002
Rings in Network Glasses: The $$\mathrm{B_2O_3}$$ Case Ferlat, Guillaume Molecular Dynamics Simulations of Disordered Materials https://doi.org/10.1007/978-3-319-15675-0_14	book	January 2015
A Review of High-Energy X-Ray Diffraction from Glasses and Liquids Benmore, C. J. ISRN Materials Science, Vol. 2012 https://doi.org/10.5402/2012/852905	journal	January 2012
Borate Glass Structure Griscom, David L. Borate Glasses https://doi.org/10.1007/978-1-4684-3357-9_2	book	January 1978
Structural study of Na ₂ O–B ₂ O ₃ –SiO ₂ glasses from molecular simulations using a polarizable force field Pacaud, Fabien; Delaye, Jean-Marc; Charpentier, Thibault The Journal of Chemical Physics, Vol. 147, Issue 16 https://doi.org/10.1063/1.4992799	journal	October 2017
Extracting the pair distribution function from white-beam X-ray total scattering data Soper, Alan K.; Barney, Emma R. Journal of Applied Crystallography, Vol. 44, Issue 4 https://doi.org/10.1107/S0021889811021455	journal	June 2011
Viscosity and Electrical Resistivity of Molten Alkali Borates Shartsis, L.; Capps, W.; Spinner, S. Journal of the American Ceramic Society, Vol. 36, Issue 10 https://doi.org/10.1111/j.1151-2916.1953.tb12808.x	journal	October 1953
MNDO studies of basicity in borate glasses Uchida, Nozomu; Maekawa, Takashi; Yokokawa, Toshio Journal of Non-Crystalline Solids, Vol. 85, Issue 3 https://doi.org/10.1016/0022-3093(86)90003-7	journal	August 1986
Structural investigation of sodium borate glasses and melts by Raman spectroscopy. Yano, Tetsuji; Kunimine, Noboru; Shibata, Shuichi Journal of Non-Crystalline Solids, Vol. 321, Issue 3 https://doi.org/10.1016/S0022-3093(03)00158-3	journal	July 2003
A new potential for radiation studies of borosilicate glass Alharbi, Amal F.; Jolley, Kenny; Smith, Roger Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 393 https://doi.org/10.1016/j.nimb.2016.12.007	journal	February 2017
Effects of system size and cooling rate on the structure and properties of sodium borosilicate glasses from molecular dynamics simulations Deng, Lu; Du, Jincheng The Journal of Chemical Physics, Vol. 148, Issue 2 https://doi.org/10.1063/1.5007083	journal	January 2018
Raman spectra of K2O–B2O3 glasses and melts Akagi, Ryuichi; Ohtori, Norikazu; Umesaki, Norimasa Journal of Non-Crystalline Solids, Vol. 293-295 https://doi.org/10.1016/S0022-3093(01)00752-9	journal	November 2001
The development of new NLO crystals in the borate series Chen, Chuangtian; Wu, Yicheng; Li, Rukang Journal of Crystal Growth, Vol. 99, Issue 1-4 https://doi.org/10.1016/S0022-0248(08)80028-0	journal	January 1990
First-principles study of a sodium borosilicate glass-former. I. The liquid state Pedesseau, Laurent; Ispas, Simona; Kob, Walter Physical Review B, Vol. 91, Issue 13 https://doi.org/10.1103/PhysRevB.91.134201	journal	April 2015
Modeling of the Structure of Sodium Borosilicate Glasses Using Pair Potentials Inoue, Hiroyuki; Masuno, Atsunobu; Watanabe, Yasuhiro The Journal of Physical Chemistry B, Vol. 116, Issue 40 https://doi.org/10.1021/jp3038126	journal	October 2012
Discovery of Ultra-Crack-Resistant Oxide Glasses with Adaptive Networks Januchta, Kacper; Youngman, Randall E.; Goel, Ashutosh Chemistry of Materials, Vol. 29, Issue 14 https://doi.org/10.1021/acs.chemmater.7b00921	journal	June 2017
Density and Expansivity of Alkali Borates and Density Characteristics of Some Other Binary Glasses Shartsis, L.; Capps, W.; Spinner, S. Journal of the American Ceramic Society, Vol. 36, Issue 2 https://doi.org/10.1111/j.1151-2916.1953.tb12833.x	journal	February 1953
Liquid B ₂ O ₃ up to 1700 K: x-ray diffraction and boroxol ring dissolution Alderman, O. L. G.; Ferlat, G.; Baroni, A. Journal of Physics: Condensed Matter, Vol. 27, Issue 45 https://doi.org/10.1088/0953-8984/27/45/455104	journal	October 2015
Development of empirical potentials for sodium borosilicate glass systems Kieu, Le-Hai; Delaye, Jean-Marc; Cormier, Laurent Journal of Non-Crystalline Solids, Vol. 357, Issue 18 https://doi.org/10.1016/j.jnoncrysol.2011.05.024	journal	September 2011
Bonding and structure in network glasses Hannon, Alex C. Journal of Non-Crystalline Solids, Vol. 451 https://doi.org/10.1016/j.jnoncrysol.2016.04.035	journal	November 2016
Molecular dynamics investigation of lithium borate glasses: Local structure and ion dynamics Varsamis, Cristos-Platon E.; Vegiri, Alice; Kamitsos, Efstratios I. Physical Review B, Vol. 65, Issue 10 https://doi.org/10.1103/PhysRevB.65.104203	journal	February 2002
Structure of glasses and melts in the Na2O-B2O3 system from high-temperature Raman spectroscopic data: II. Superstructural units in melts Osipov, A. A.; Osipova, L. M. Glass Physics and Chemistry, Vol. 35, Issue 2 https://doi.org/10.1134/S1087659609020023	journal	April 2009
Effect of temperature and thermal history on borosilicate glass structure Angeli, Frédéric; Villain, Olivier; Schuller, Sophie Physical Review B, Vol. 85, Issue 5 https://doi.org/10.1103/PhysRevB.85.054110	journal	February 2012
Rheological properties of boric oxide and alkali borate glasses Visser, T. J. M.; Stevels, J. M. Journal of Non-Crystalline Solids, Vol. 7, Issue 4 https://doi.org/10.1016/0022-3093(72)90272-4	journal	May 1972
Molecular dynamics calculations for boron oxide and sodium borate glasses Xu, Qiang; Kawamura, Katsuyuki; Yokokawa, Toshio Journal of Non-Crystalline Solids, Vol. 104, Issue 2-3 https://doi.org/10.1016/0022-3093(88)90397-3	journal	September 1988
Physical properties of alkaline-earth and alkali borate glasses prepared over an extended range of compositions Lower, Nathan P.; McRae, Justin L.; Feller, Heidi A. Journal of Non-Crystalline Solids, Vol. 293-295 https://doi.org/10.1016/S0022-3093(01)00768-2	journal	November 2001
Borate Materials in Nonlinear Optics Becker, Petra Advanced Materials, Vol. 10, Issue 13 https://doi.org/10.1002/(SICI)1521-4095(199809)10:13<979::AID-ADMA979>3.0.CO;2-N	journal	September 1998
Composition and temperature dependence of cesium-borate glasses by molecular dynamics Vegiri, Alice; Varsamis, Cristos-Platon E.; Kamitsos, Efstratios I. The Journal of Chemical Physics, Vol. 123, Issue 1 https://doi.org/10.1063/1.1943414	journal	July 2005
Radionuclides containment in nuclear glasses: an overview Gin, Stephane; Jollivet, Patrick; Tribet, Magaly Radiochimica Acta, Vol. 105, Issue 11 https://doi.org/10.1515/ract-2016-2658	journal	January 2017
Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database Brown, I. D.; Altermatt, D. Acta Crystallographica Section B Structural Science, Vol. 41, Issue 4 https://doi.org/10.1107/S0108768185002063	journal	August 1985
Borate Networks: Rigidity versus Dimensionality [English] Wright, Adrian C.; Vedishcheva, Natalia M. Physics and Chemistry of Glasses: European Journal of Glass Science and Technology Part B, Vol. 57, Issue 1 https://doi.org/10.13036/17533562.57.1.087	journal	February 2016

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Title: Borate melt structure: Temperature-dependent B–O bond lengths and coordination numbers from high-energy X-ray diffraction

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