Giant negative thermal expansion in Fe-Mn-Ga magnetic shape memory alloys

Sun, X. M.; Cong, D. Y.; Ren, Y.; Brown, D. E.; Li, R. G.; Li, S. H.; Yang, Z.; Xiong, W. X.; Nie, Z. H.; Wang, L.; Wang, Y. D.

doi:10.1063/1.5038860

Title: Giant negative thermal expansion in Fe-Mn-Ga magnetic shape memory alloys

Abstract

Fe-Mn-Ga magnetic shape memory alloys can undergo martensitic transformation (MT) from a paramagnetic cubic phase to a ferromagnetic tetragonal phase. The MT is accompanied by a large volume change; yet, these alloys have never been explored for technological applications as negative thermal expansion (NTE) materials. Here, by careful chemical modification, tunable NTE characteristics including wide operating temperature windows (Delta T) and large negative linear coefficients of thermal expansion (alpha(l)) have been achieved in Fe_44-xMn₂₈Ga_28+x (x = 1, 2, and 2.5) alloys. Typically, a giant NTE Delta T of 81 K and alpha(l =) -50.2 x 10(-6) K-1 were realized in the Fe43Mn28Ga29 alloy upon cooling from 290 K. The relationships between the NTE features, the MT, and the substitution of Ga for Fe were discussed. Furthermore, the Fe-Mn-Ga alloys possess excellent mechanical properties, high electrical conductivity and high thermal conductivity. With these advantages, the Fe-Mn-Ga magnetic shape memory alloys show promising prospects for use as advanced NTE materials.

Authors:

Sun, X. M. ^[1]; Cong, D. Y. ^[1]; Ren, Y. ^[2]; Brown, D. E. ^[3];

^[1]; Li, S. H. ^[1];

^[1]; Xiong, W. X. ^[1]; Nie, Z. H. ^[4]; Wang, L. ^[4]; Wang, Y. D. ^[1]

Univ. of Science and Technology Beijing, Beijing (China). State Key Lab. for Advanced Metals and Materials
Argonne National Lab. (ANL), Argonne, IL (United States). X-Ray Sciences Division
Northern Illinois Univ., DeKalb, IL (United States). Dept. of Physics
Beijing Inst. of Technology, Beijing (China). School of Materials Science and Engineering

Publication Date:: 2018-07-23

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC); Chinese Academy of Sciences (CAS)

OSTI Identifier:: 1480852

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Applied Physics Letters

Additional Journal Information:: Journal Volume: 113; Journal Issue: 4; Journal ID: ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Sun, X. M., Cong, D. Y., Ren, Y., Brown, D. E., Li, R. G., Li, S. H., Yang, Z., Xiong, W. X., Nie, Z. H., Wang, L., and Wang, Y. D. Giant negative thermal expansion in Fe-Mn-Ga magnetic shape memory alloys.  United States: N. p., 2018. 
Web.  doi:10.1063/1.5038860.

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                    Sun, X. M., Cong, D. Y., Ren, Y., Brown, D. E., Li, R. G., Li, S. H., Yang, Z., Xiong, W. X., Nie, Z. H., Wang, L., & Wang, Y. D. Giant negative thermal expansion in Fe-Mn-Ga magnetic shape memory alloys.  United States.  https://doi.org/10.1063/1.5038860

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                    Sun, X. M., Cong, D. Y., Ren, Y., Brown, D. E., Li, R. G., Li, S. H., Yang, Z., Xiong, W. X., Nie, Z. H., Wang, L., and Wang, Y. D. Mon .  
"Giant negative thermal expansion in Fe-Mn-Ga magnetic shape memory alloys".  United States.  https://doi.org/10.1063/1.5038860.  https://www.osti.gov/servlets/purl/1480852.

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@article{osti_1480852,

  title        = {Giant negative thermal expansion in Fe-Mn-Ga magnetic shape memory alloys},

  author       = {Sun, X. M. and Cong, D. Y. and Ren, Y. and Brown, D. E. and Li, R. G. and Li, S. H. and Yang, Z. and Xiong, W. X. and Nie, Z. H. and Wang, L. and Wang, Y. D.},

  abstractNote = {Fe-Mn-Ga magnetic shape memory alloys can undergo martensitic transformation (MT) from a paramagnetic cubic phase to a ferromagnetic tetragonal phase. The MT is accompanied by a large volume change; yet, these alloys have never been explored for technological applications as negative thermal expansion (NTE) materials. Here, by careful chemical modification, tunable NTE characteristics including wide operating temperature windows (Delta T) and large negative linear coefficients of thermal expansion (alpha(l)) have been achieved in Fe44-xMn28Ga28+x (x = 1, 2, and 2.5) alloys. Typically, a giant NTE Delta T of 81 K and alpha(l =) -50.2 x 10(-6) K-1 were realized in the Fe43Mn28Ga29 alloy upon cooling from 290 K. The relationships between the NTE features, the MT, and the substitution of Ga for Fe were discussed. Furthermore, the Fe-Mn-Ga alloys possess excellent mechanical properties, high electrical conductivity and high thermal conductivity. With these advantages, the Fe-Mn-Ga magnetic shape memory alloys show promising prospects for use as advanced NTE materials.},

  doi          = {10.1063/1.5038860},

  journal      = {Applied Physics Letters},

  number       = 4,

  volume       = 113,

  place        = {United States},

  year         = {2018},

  month        = {7}

}

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Title: Giant negative thermal expansion in Fe-Mn-Ga magnetic shape memory alloys

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Negative thermal expansion and magnetocaloric effect in Mn-Co-Ge-In thin films
journal, January 2018

Magnetocrystalline anisotropy in Fe–Mn–Ga magnetic shape memory alloy
journal, April 2011

Martensitic transformation and magnetic field-induced strain in Fe–Mn–Ga shape memory alloy
journal, August 2009

Magnetic-field-induced transformation in FeMnGa alloys
journal, November 2009

Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
journal, June 2011

Size effects on negative thermal expansion in cubic ScF ₃
journal, July 2016

Magnetic-field-induced shape recovery by reverse phase transformation
journal, February 2006

Magnetic field-induced martensitic transformation and large magnetoresistance in NiCoMnSb alloys
journal, June 2007

Large Magnetostriction and Negative Thermal Expansion in the Frustrated Antiferromagnet ${ZnCr}_{2} {Se}_{4}$
journal, April 2007

Nanoporosity and Exceptional Negative Thermal Expansion in Single-Network Cadmium Cyanide
journal, February 2008

Prediction of fully compensated ferrimagnetic spin-gapless semiconducting FeMnGa/Al/In half Heusler alloys
journal, May 2019