Determination of elemental composition of shale rocks by laser induced breakdown spectroscopy
Abstract
Laser induced breakdown spectroscopy (LIBS) is used for elemental characterization of outcrop samples from the Marcellus Shale. Powdered samples were pressed to form pellets and used for LIBS analysis. Partial least squares regression (PLS-R) and univariate calibration curves were used for quantification of analytes. The matrix effect is substantially reduced using the partial least squares calibration method. Predicted results with LIBS are compared to ICP-OES results for Si, Al, Ti, Mg, and Ca. As for C, its results are compared to those obtained by a carbon analyzer. Relative errors of the LIBS measurements are in the range of 1.7 to 12.6%. The limits of detection (LODs) obtained for Si, Al, Ti, Mg and Ca are 60.9, 33.0, 15.6, 4.2 and 0.03 ppm, respectively. An LOD of 0.4 wt.% was obtained for carbon. Finally, this study shows that the LIBS method can provide a rapid analysis of shale samples and can potentially benefit depleted gas shale carbon storage research.
- Authors:
-
- Mississippi State Univ., Mississippi State, MS (United States). Inst. for Clean Energy Technology
- National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
- Applied Spectra, Inc., Fremont, CA (United States)
- National Energy Technology Lab. (NETL), Morgantown, WV (United States)
- Publication Date:
- Research Org.:
- National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1480827
- Alternate Identifier(s):
- OSTI ID: 1359838
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Spectrochimica Acta. Part B, Atomic Spectroscopy
- Additional Journal Information:
- Journal Volume: 122; Journal ID: ISSN 0584-8547
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES; LIBS; shale rock; elemental analysis
Citation Formats
Sanghapi, Hervé K., Jain, Jinesh, Bol'shakov, Alexander, Lopano, Christina, McIntyre, Dustin, and Russo, Richard. Determination of elemental composition of shale rocks by laser induced breakdown spectroscopy. United States: N. p., 2016.
Web. doi:10.1016/j.sab.2016.05.011.
Sanghapi, Hervé K., Jain, Jinesh, Bol'shakov, Alexander, Lopano, Christina, McIntyre, Dustin, & Russo, Richard. Determination of elemental composition of shale rocks by laser induced breakdown spectroscopy. United States. https://doi.org/10.1016/j.sab.2016.05.011
Sanghapi, Hervé K., Jain, Jinesh, Bol'shakov, Alexander, Lopano, Christina, McIntyre, Dustin, and Russo, Richard. Wed .
"Determination of elemental composition of shale rocks by laser induced breakdown spectroscopy". United States. https://doi.org/10.1016/j.sab.2016.05.011. https://www.osti.gov/servlets/purl/1480827.
@article{osti_1480827,
title = {Determination of elemental composition of shale rocks by laser induced breakdown spectroscopy},
author = {Sanghapi, Hervé K. and Jain, Jinesh and Bol'shakov, Alexander and Lopano, Christina and McIntyre, Dustin and Russo, Richard},
abstractNote = {Laser induced breakdown spectroscopy (LIBS) is used for elemental characterization of outcrop samples from the Marcellus Shale. Powdered samples were pressed to form pellets and used for LIBS analysis. Partial least squares regression (PLS-R) and univariate calibration curves were used for quantification of analytes. The matrix effect is substantially reduced using the partial least squares calibration method. Predicted results with LIBS are compared to ICP-OES results for Si, Al, Ti, Mg, and Ca. As for C, its results are compared to those obtained by a carbon analyzer. Relative errors of the LIBS measurements are in the range of 1.7 to 12.6%. The limits of detection (LODs) obtained for Si, Al, Ti, Mg and Ca are 60.9, 33.0, 15.6, 4.2 and 0.03 ppm, respectively. An LOD of 0.4 wt.% was obtained for carbon. Finally, this study shows that the LIBS method can provide a rapid analysis of shale samples and can potentially benefit depleted gas shale carbon storage research.},
doi = {10.1016/j.sab.2016.05.011},
journal = {Spectrochimica Acta. Part B, Atomic Spectroscopy},
number = ,
volume = 122,
place = {United States},
year = {Wed May 25 00:00:00 EDT 2016},
month = {Wed May 25 00:00:00 EDT 2016}
}
Web of Science
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Works referencing / citing this record:
Determination of Heating Value of Estonian Oil Shale by Laser-Induced Breakdown Spectroscopy
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Real-Time Analysis of Potassium in Infant Formula Powder by Data-Driven Laser-Induced Breakdown Spectroscopy
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