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Title: A Review of Recent Advances in the Understanding of Liquid Metal Embrittlement

Abstract

Significant advances in the study of liquid metal embrittlement have occurred since 2000 but there have been few reviews of the liquid metal embrittlement literature since that time. This paper discusses recent advances in modelling and testing. Specific solid - liquid systems (including steel exposed to molten lead-bismuth and aluminum - gallium ) are reviewed. Relationships between various studies are considered and the need for careful test protocols is emphasized. The individual effects of wetting, crack initiation and propagation are discussed. Finally, mechanisms of liquid metal embrittlement including interatomic and mass-transport based phenomena are analyzed.

Authors:
 [1]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Publication Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1479997
Report Number(s):
LA-UR-18-24764
Journal ID: ISSN 0010-9312
Grant/Contract Number:  
AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Corrosion
Additional Journal Information:
Journal Volume: 75; Journal Issue: 1; Journal ID: ISSN 0010-9312
Publisher:
NACE International
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; liquid metal embrittlement; environmentally assisted cracking

Citation Formats

Kolman, David. A Review of Recent Advances in the Understanding of Liquid Metal Embrittlement. United States: N. p., 2018. Web. doi:10.5006/2904.
Kolman, David. A Review of Recent Advances in the Understanding of Liquid Metal Embrittlement. United States. https://doi.org/10.5006/2904
Kolman, David. Tue . "A Review of Recent Advances in the Understanding of Liquid Metal Embrittlement". United States. https://doi.org/10.5006/2904. https://www.osti.gov/servlets/purl/1479997.
@article{osti_1479997,
title = {A Review of Recent Advances in the Understanding of Liquid Metal Embrittlement},
author = {Kolman, David},
abstractNote = {Significant advances in the study of liquid metal embrittlement have occurred since 2000 but there have been few reviews of the liquid metal embrittlement literature since that time. This paper discusses recent advances in modelling and testing. Specific solid - liquid systems (including steel exposed to molten lead-bismuth and aluminum - gallium ) are reviewed. Relationships between various studies are considered and the need for careful test protocols is emphasized. The individual effects of wetting, crack initiation and propagation are discussed. Finally, mechanisms of liquid metal embrittlement including interatomic and mass-transport based phenomena are analyzed.},
doi = {10.5006/2904},
journal = {Corrosion},
number = 1,
volume = 75,
place = {United States},
year = {Tue Sep 18 00:00:00 EDT 2018},
month = {Tue Sep 18 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 24 works
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Figures / Tables:

Table 1 Table 1: References to recently studied solid metal – liquid metal couples

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Works referenced in this record:

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Fast penetration of Ga in Al: liquid metal embrittlement near the threshold of grain boundary wetting
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Preferential penetration path of gallium into grain boundary in practical aluminium alloy
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Penetration of liquid metals into solid metals and liquid metal embrittlement
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Penetration of liquid gallium into the grain boundaries of aluminium: a synchrotron radiation microtomographic investigation
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Localization of electromagnetic field on the “Brouwer-island” and liquid metal embrittlement
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Kinetic, volumetric and structural effects induced by liquid Ga penetration into ultrafine grained Al
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Molecular Dynamics Simulation of Ga Penetration along Grain Boundaries in Al: A Dislocation Climb Mechanism
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Effect of material properties on liquid metal embrittlement in the Al–Ga system
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Insight into the atomic-scale mechanism of liquid metal embrittlement
journal, September 2006

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Liquid metal embrittlement of aluminium by segregation of trace element gallium
journal, August 2014


Molecular Dynamics Simulation of Ga Penetration along Al Grain Boundaries under a Constant Strain Rate Condition
journal, January 2014


First-principles study of the effects of segregated Ga on an Al grain boundary
journal, May 2006


The activation of aluminium by mercury ions in non-aggressive media
journal, December 2006


A fluid flow based model to predict liquid metal induced embrittlement crack propagation rates
journal, November 2001


Experimental study of liquid metal embrittlement for the aluminum 7075–mercury couple
journal, April 2012


Failures of Structures and Components by Metal-Induced Embrittlement
journal, March 2008


Risk analysis for operation of aluminum heat exchangers contaminated by mercury
journal, September 2009


Time dependent embrittlement of poly crystalline Ag by liquid Ga
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Bismuth-induced embrittlement of copper grain boundaries
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The effect of stress on grain boundary interdiffusion in a semi-infinite bicrystal
journal, August 2007


Identification of a bilayer grain boundary complexion in Bi-doped Cu
journal, January 2013


The Role of a Bilayer Interfacial Phase on Liquid Metal Embrittlement
journal, September 2011


Bismuth embrittlement of copper is an atomic size effect
journal, December 2004

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Rapid penetration of bismuth from solid Bi2Te3 along grain boundaries in Cu and Cu-based alloys
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The effect of precipitation hardening on the Hg-induced embrittlement of a Cu–Be alloy
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The effect of tin on the susceptibility of a Cu–Al alloy to cracking in mercury
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Effect of test temperature on tensile properties ofα/βbrass containing lead
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A first principles investigation of zinc induced embrittlement at grain boundaries in bcc iron
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Gleeble Testing to Assess Solid/Liquid Metal Embrittlement of Gun Steels by Copper
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Liquid metal embrittlement of T91 and 316L steels by heavy liquid metals: A fracture mechanics assessment
journal, June 2008


Liquid metal embrittlement of an austenitic 316L type and a ferritic–martensitic T91 type steel by mercury
journal, June 2008


Liquid–metal-induced fracture mode of martensitic T91 steels
journal, July 2012


Compatibility of steel No. 1.4970 with liquid sodium at high temperatures
journal, May 2003


Effect of heat treatment on liquid sodium embrittlement of T91 martensitic steel
journal, December 2011


Effect of oxygen on liquid sodium embrittlement of T91 martensitic steel
journal, November 2013


Modelling of liquid sodium induced crack propagation in T91 martensitic steel: Competition with ductile fracture
journal, December 2016


Comparative study of the behavior of different highly alloyed steels in liquid sodium
journal, August 2017


Corrosion behavior and microstructural evolution of ASTM A182 Grade 92 steel in liquid sodium at 650°C
journal, August 2015


Evaluation of liquid metal embrittlement susceptibility of oxide dispersion strengthened steel MA956
journal, October 2014


Cavity formation and accelerated plastic strain in T91 steel in contact with liquid lead
journal, March 2004


Corrosion of ferritic–martensitic steels in the eutectic Pb–17Li
journal, December 2000


Behaviour of the steel T91 under uniaxial and multiaxial slow loading in contact with liquid lead
journal, November 2015


Mechanical properties of the steel T91 in contact with lead
journal, March 2015


LME induced failure of a combat aircraft gun
journal, October 2008


Influence of Exposure to Pb-Li on Microstructure and Mechanical Properties of 9Cr-ODS and CLAM Steels
journal, July 2011

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Influence of lead and Pb−Bi eutectic melts on the mechanical properties of 20Kh13 ferritic–martensitic steel
journal, November 2012


Effect of Lead and Lead–Bismuth Eutectic Melts on the Fatigue Life of Steels of the Martensitic and Austenitic Classes
journal, July 2014


Influence of Oxygen-Containing Lead Melts on the Fatigue Strength of AISI 409L Steel at Elevated Temperatures
journal, March 2015


Characteristics and Liquid Metal Embrittlement of the steel T91 in contact with Lead–Bismuth Eutectic
journal, April 2016


Effects of temperature and strain rate on the tensile behaviors of SIMP steel in static lead bismuth eutectic
journal, May 2016


Liquid metal embrittlement susceptibility of T91 steel by lead?bismuth
journal, June 2005


Role of oxidation on LME of T91 steel studied by small punch test
journal, June 2008


FeCrAlY and TiN coatings on T91 steel after irradiation with 72MeV protons in flowing LBE
journal, December 2012


Investigating liquid-metal embrittlement of T91 steel by fracture toughness tests
journal, April 2016


Tensile fracture behavior of notched 9Cr-1Mo ferritic-martensitic steel specimens in contact with liquid lead-bismuth eutectic at 350 °C
journal, April 2017


Temperature effect in the maximum propagation rate of a liquid metal filled crack: The T91 martensitic steel/Lead–Bismuth Eutectic system
journal, November 2009


Susceptibility to LME of 316L and T91 steels by LBE: Effect of strain rate
journal, June 2008


On the kinetics of LME for the ferritic–martensitic steel T91 immersed in liquid PbBi eutectic
journal, June 2011


Behaviour of pre-stressed T91 and ODS steels exposed to liquid lead-bismuth eutectic
journal, February 2018


Creep-to-rupture tests of T91 steel in flowing Pb–Bi eutectic melt at 550°C
journal, October 2009


Comparison of the mechanical properties of T91 steel from the MEGAPIE, and TWIN-ASTIR irradiation programs
journal, January 2016


Liquid Pb–Bi embrittlement effects on the T91 steel after different heat treatments
journal, June 2008


Liquid metal embrittlement of T91 martensitic steel evidenced by small punch test
journal, April 2007


Mechanical behavior of coated T91 steel in contact with lead–bismuth liquid alloy at 300°C
journal, June 2011


Influence of LBE long term exposure and simultaneous fast neutron irradiation on the mechanical properties of T91 and 316L
journal, May 2016


Liquid metal embrittlement susceptibility of ferritic–martensitic steel in liquid lead alloys
journal, June 2008


Compatibility of martensitic/austenitic steel welds with liquid lead bismuth eutectic environment
journal, April 2009


Fracture toughness assessment of ferritic–martensitic steel in liquid lead–bismuth eutectic
journal, March 2009


TWIN ASTIR: First tensile results of T91 and 316L steel after neutron irradiation in contact with liquid lead–bismuth eutectic
journal, March 2010


Compatibility of ferritic–martensitic steel T91 welds with liquid lead–bismuth eutectic: Comparison between TIG and EB welds
journal, January 2010


Liquid metal embrittlement of silicon enriched steel for nuclear applications
journal, March 2010


On the LME susceptibility of Si enriched steels
journal, October 2012


Mechanical behaviour of the T91 martensitic steel under monotonic and cyclic loadings in liquid metals
journal, November 2004


Brittle fracture of T91 steel in liquid lead–bismuth eutectic alloy
journal, December 2014


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Liquid metal embrittlement of tensile specimens of En19 steel by tin
journal, February 2003


Supercritical area and critical nugget diameter for liquid metal embrittlement of Zn-coated twining induced plasticity steels
journal, December 2015


Liquid metal embrittlement-free welds of Zn-coated twinning induced plasticity steels
journal, March 2016


Liquid zinc embrittlement of a high-manganese-content TWIP steel
journal, April 2011


Liquid zinc embrittlement of twinning-induced plasticity steel
journal, June 2012


Embrittlement of a zinc coated high manganese TWIP steel
journal, May 2012


Embrittlement of a High Manganese TWIP Steel in the Presence of Liquid Zinc
journal, January 2012


Microstructure of liquid metal embrittlement cracks on Zn-coated 22MnB5 press-hardened steel
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Liquid metal induced embrittlement of a nitrided clutch shell of a motorbike
journal, March 2016


Analyse der Einflüsse auf die Rissbildung infolge Flüssigmetallversprödung beim Feuerverzinken
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Liquid Zn assisted embrittlement of advanced high strength steels with different microstructures
journal, February 2016

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Zn Penetration in Liquid Metal Embrittled TWIP Steel
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Heating rate effect on liquid Zn-assisted embrittlement of high Mn austenitic steel
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On the influence of cold deformation on liquid metal embrittlement of a steel in a liquid zinc bath
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Liquid Metal Embrittlement of Steel with a Coating Obtained by Batch Hot Dip Method in a Zn + 2% Sn Bath
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Micro-crack in zinc coating layer on boron steel sheet in hot deep drawing process
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Liquid Metal Embrittlement of Hot Stamped Galvannealed Boron Steel Sheet – Effect of Heating Time on Crack Formation –
journal, January 2017


Characterization of Liquid Metal Embrittlement for the Hot Stamped Galvannealed Boron Steel Sheets
journal, January 2018


Liquid metal embrittlement in laser beam welding of Zn-coated 22MnB5 steel
journal, October 2018


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journal, November 2014


Quantification of fatigue crack propagation of an austenitic stainless steel in mercury embrittlement
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journal, August 2005


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Wetting by liquid sodium and fracture path analysis of sodium induced embrittlement of 304L stainless steel
journal, November 2017

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Investigation of crack propagation resistance of 304L, 316L and 316L(N) austenitic steels in liquid sodium
journal, August 2018


Liquid metal embrittlement of an austenitic stainless steel in liquid sodium
journal, June 2014


Mechanical and fatigue properties of martensitic Fe-13Cr steel in contact with lead and lead-bismuth melts
journal, January 2014


Effect of Chromium and Nickel Contents on Liquid Zinc Embrittlement in Heat Affected Zone of Austenitic Steels
journal, January 2012

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journal, April 2014


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journal, November 2015


Intergranular penetration and embrittlement of solid nickel through bismuth vapour condensation at 700°C
journal, July 2001


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journal, February 2015

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Insight into gallium behavior in aluminum grain boundaries from calculation on Σ=11 (113) boundary
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journal, April 2005

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Works referencing / citing this record:

Phenomenon of skin effect in metals due to hydrogen absorption
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