Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability
Abstract
Here, a simple and versatile strategy, borrowing ideas from the chemistry of MOFs and COFs, is developed for the synthesis of coordination-supported organic polymers (COPs) via coordination between Al3+ and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation. The COPs with high surface areas (up to 1123 m2 g-1) and abundant mesopores (2.5 nm or 14 nm) possess good crystalline and porous structure after being soaked in boiling water.
- Authors:
-
- Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering
- Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Jilin Univ., Changchun (China). State Key Lab. of Inorganic Synthesis and Preparative Chemistry
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Shanghai Jiao Tong Univ. (China)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Shanghai Pujiang Program (China); Young Thousand Talented Program (China); National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1479716
- Alternate Identifier(s):
- OSTI ID: 1441042
- Grant/Contract Number:
- AC05-00OR22725; 17PJ1403500; 21776174
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry Frontiers (Online)
- Additional Journal Information:
- Journal Name: Inorganic Chemistry Frontiers (Online); Journal Volume: 5; Journal Issue: 8; Journal ID: ISSN 2052-1553
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Chen, Dong, Zhang, Pengfei, Fang, Qianrong, Wan, Shun, Li, Hui, Yang, Shize, Huang, Caili, and Dai, Sheng. Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability. United States: N. p., 2018.
Web. doi:10.1039/c8qi00471d.
Chen, Dong, Zhang, Pengfei, Fang, Qianrong, Wan, Shun, Li, Hui, Yang, Shize, Huang, Caili, & Dai, Sheng. Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability. United States. https://doi.org/10.1039/c8qi00471d
Chen, Dong, Zhang, Pengfei, Fang, Qianrong, Wan, Shun, Li, Hui, Yang, Shize, Huang, Caili, and Dai, Sheng. Tue .
"Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability". United States. https://doi.org/10.1039/c8qi00471d. https://www.osti.gov/servlets/purl/1479716.
@article{osti_1479716,
title = {Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability},
author = {Chen, Dong and Zhang, Pengfei and Fang, Qianrong and Wan, Shun and Li, Hui and Yang, Shize and Huang, Caili and Dai, Sheng},
abstractNote = {Here, a simple and versatile strategy, borrowing ideas from the chemistry of MOFs and COFs, is developed for the synthesis of coordination-supported organic polymers (COPs) via coordination between Al3+ and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation. The COPs with high surface areas (up to 1123 m2 g-1) and abundant mesopores (2.5 nm or 14 nm) possess good crystalline and porous structure after being soaked in boiling water.},
doi = {10.1039/c8qi00471d},
journal = {Inorganic Chemistry Frontiers (Online)},
number = 8,
volume = 5,
place = {United States},
year = {Tue Jun 05 00:00:00 EDT 2018},
month = {Tue Jun 05 00:00:00 EDT 2018}
}
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Cited by: 7 works
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Figures / Tables:
Figure 1: Three classes of building blocks proposed for the design of porous organic materials. Type I: Organic Ligand for metal-organic framework. Type II: Organic Linker for porous polymer via covalent bonding formation Type III: Hybrid building block with both coordination point and covalent linkable group.
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