skip to main content

DOE PAGESDOE PAGES

This content will become publicly available on June 5, 2019

Title: Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability

Here, a simple and versatile strategy, borrowing ideas from the chemistry of MOFs and COFs, is developed for the synthesis of coordination-supported organic polymers (COPs) via coordination between Al 3+ and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation. The COPs with high surface areas (up to 1123 m 2 g -1) and abundant mesopores (2.5 nm or 14 nm) possess good crystalline and porous structure after being soaked in boiling water.
Authors:
ORCiD logo [1] ; ORCiD logo [2] ; ORCiD logo [3] ;  [4] ;  [3] ; ORCiD logo [4] ; ORCiD logo [4] ; ORCiD logo [5]
  1. Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering
  2. Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
  3. Jilin Univ., Changchun (China). State Key Lab. of Inorganic Synthesis and Preparative Chemistry
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
  5. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Publication Date:
Grant/Contract Number:
AC05-00OR22725; 17PJ1403500; 21776174
Type:
Accepted Manuscript
Journal Name:
Inorganic Chemistry Frontiers (Online)
Additional Journal Information:
Journal Name: Inorganic Chemistry Frontiers (Online); Journal Volume: 5; Journal Issue: 8; Journal ID: ISSN 2052-1553
Publisher:
Royal Society of Chemistry
Research Org:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Shanghai Jiao Tong Univ. (China)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Shanghai Pujiang Program (China); Young Thousand Talented Program (China); National Natural Science Foundation of China (NNSFC)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
OSTI Identifier:
1479716

Chen, Dong, Zhang, Pengfei, Fang, Qianrong, Wan, Shun, Li, Hui, Yang, Shize, Huang, Caili, and Dai, Sheng. Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability. United States: N. p., Web. doi:10.1039/c8qi00471d.
Chen, Dong, Zhang, Pengfei, Fang, Qianrong, Wan, Shun, Li, Hui, Yang, Shize, Huang, Caili, & Dai, Sheng. Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability. United States. doi:10.1039/c8qi00471d.
Chen, Dong, Zhang, Pengfei, Fang, Qianrong, Wan, Shun, Li, Hui, Yang, Shize, Huang, Caili, and Dai, Sheng. 2018. "Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability". United States. doi:10.1039/c8qi00471d.
@article{osti_1479716,
title = {Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability},
author = {Chen, Dong and Zhang, Pengfei and Fang, Qianrong and Wan, Shun and Li, Hui and Yang, Shize and Huang, Caili and Dai, Sheng},
abstractNote = {Here, a simple and versatile strategy, borrowing ideas from the chemistry of MOFs and COFs, is developed for the synthesis of coordination-supported organic polymers (COPs) via coordination between Al3+ and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation. The COPs with high surface areas (up to 1123 m2 g-1) and abundant mesopores (2.5 nm or 14 nm) possess good crystalline and porous structure after being soaked in boiling water.},
doi = {10.1039/c8qi00471d},
journal = {Inorganic Chemistry Frontiers (Online)},
number = 8,
volume = 5,
place = {United States},
year = {2018},
month = {6}
}

Works referenced in this record:

A homochiral metal�organic porous material for enantioselective separation and catalysis
journal, April 2000
  • Seo, Jung Soo; Whang, Dongmok; Lee, Hyoyoung
  • Nature, Vol. 404, Issue 6781, p. 982-986
  • DOI: 10.1038/35010088

Metal�Organic Frameworks as Efficient Materials for Drug Delivery
journal, September 2006
  • Horcajada, Patricia; Serre, Christian; Vallet-Reg�, Mar�a
  • Angewandte Chemie International Edition, Vol. 45, Issue 36, p. 5974-5978
  • DOI: 10.1002/anie.200601878

Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005
  • C�t�, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
  • Science, Vol. 310, Issue 5751, p. 1166-1170
  • DOI: 10.1126/science.1120411

Scintillating Metal-Organic Frameworks: A New Class of Radiation Detection Materials
journal, January 2009
  • Doty, F. P.; Bauer, C. A.; Skulan, A. J.
  • Advanced Materials, Vol. 21, Issue 1, p. 95-101
  • DOI: 10.1002/adma.200801753

Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage
journal, January 2006
  • McKeown, Neil B.; Budd, Peter M.
  • Chemical Society Reviews, Vol. 35, Issue 8, p. 675-683
  • DOI: 10.1039/b600349d

Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area
journal, November 2009
  • Ben, Teng; Ren, Hao; Ma, Shengqian
  • Angewandte Chemie International Edition, Vol. 48, Issue 50, p. 9457-9460
  • DOI: 10.1002/anie.200904637

Porous Organic Polymers in Catalysis Opportunities and Challenges
journal, May 2011
  • Kaur, Parminder; Hupp, Joseph T.; Nguyen, SonBinh T.
  • ACS Catalysis, Vol. 1, Issue 7, p. 819-835
  • DOI: 10.1021/cs200131g

Water Stability and Adsorption in Metal�Organic Frameworks
journal, September 2014
  • Burtch, Nicholas C.; Jasuja, Himanshu; Walton, Krista S.
  • Chemical Reviews, Vol. 114, Issue 20, p. 10575-10612
  • DOI: 10.1021/cr5002589

Water Adsorption in Porous Metal�Organic Frameworks and Related Materials
journal, March 2014
  • Furukawa, Hiroyasu; G�ndara, Felipe; Zhang, Yue-Biao
  • Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381
  • DOI: 10.1021/ja500330a

Porous materials with optimal adsorption thermodynamics and kinetics for CO2 separation
journal, February 2013
  • Nugent, Patrick; Belmabkhout, Youssef; Burd, Stephen D.
  • Nature, Vol. 495, Issue 7439, p. 80-84
  • DOI: 10.1038/nature11893

Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage/Separation
journal, November 2010
  • Lu, Weigang; Yuan, Daqiang; Zhao, Dan
  • Chemistry of Materials, Vol. 22, Issue 21, p. 5964-5972
  • DOI: 10.1021/cm1021068

The Chemistry and Applications of Metal-Organic Frameworks
journal, August 2013
  • Furukawa, H.; Cordova, K. E.; O'Keeffe, M.
  • Science, Vol. 341, Issue 6149, p. 1230444-1230444
  • DOI: 10.1126/science.1230444