Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO2 Tolerance in Methane Combustion

Peng, Honggen; Rao, Cheng; Zhang, Ning; Wang, Xiang; Liu, Wenming; Mao, Wenting; Han, Lu; Zhang, Pengfei; Dai, Sheng

doi:10.1002/anie.201803393

Title: Confined Ultrathin Pd-Ce Nanowires with Outstanding Moisture and SO₂ Tolerance in Methane Combustion

Journal Article · 22 May 2018 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.201803393 · OSTI ID:1479715

Peng, Honggen ^[1]; Rao, Cheng ^[2]; Zhang, Ning ^[2]; Wang, Xiang ^[2]; Liu, Wenming ^[2]; Mao, Wenting ^[3];

^[3]; Zhang, Pengfei ^[4];

^[5]

Nanchang Univ. (China). Inst. of Applied Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Nanchang Univ. (China). Inst. of Applied Chemistry
Shanghai Jiao Tong Univ. (China)
Shanghai Jiao Tong Univ. (China); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Abstract An efficient strategy (enhanced metal oxide interaction and core–shell confinement to inhibit the sintering of noble metal) is presented confined ultrathin Pd‐CeO _x nanowire (2.4 nm) catalysts for methane combustion, which enable CH ₄ total oxidation at a low temperature of 350 °C, much lower than that of a commercial Pd/Al ₂ O ₃ catalyst (425 °C). Importantly, unexpected stability was observed even under harsh conditions (800 °C, water vapor, and SO ₂ ), owing to the confinement and shielding effect of the porous silica shell together with the promotion of CeO ₂ . Pd‐CeO _x solid solution nanowires (Pd‐Ce NW) as cores and porous silica as shells (Pd‐CeNW@SiO ₂ ) were rationally prepared by a facile and direct self‐assembly strategy for the first time. This strategy is expected to inspire more active and stable catalysts for use under severe conditions (vehicle emissions control, reforming, and water–gas shift reaction).

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States); Nanchang Univ. (China); Shanghai Jiao Tong Univ. (China)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China; National Natural Science Foundation of China (NSFC); Natural Science Foundation of Jiangxi Province; Foundation of State Key Lab. of Coal Clean Utilization and Ecological Chemical Engineering, China

Grant/Contract Number:: AC05-00OR22725; 2016YFC0205900; 21503106; 21567016; 21773106; 20171BCB23016; 20171BAB203024; 2016-15

OSTI ID:: 1479715

Alternate ID(s):: OSTI ID: 1459724

Journal Information:: Angewandte Chemie (International Edition), Vol. 57, Issue 29; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 121 works

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