Spin canting and orbital order in spinel vanadate thin films

Thompson, Christie; Reig-i-Plessis, Dalmau; Kish, Lasar; Aczel, A. A.; Zhang, Biwen; Karapetrova, Evguenia A.; MacDougall, Gregory J.; Beekman, Christiane

doi:10.1103/PhysRevMaterials.2.104411

Title: Spin canting and orbital order in spinel vanadate thin films

Abstract

Here, we report on the epitaxial film growth and characterization of CoV₂O₄, a near-itinerant spinel vanadate, grown on (001) SrTiO₃. The symmetry lowering of the unit cell from cubic in the bulk to orthorhombic in the films results in dramatic differences in the magnetic anisotropy compared to bulk, as determined from structural and magnetic characterization. Bulk cubic CoV₂O₄ has been found to defy predictions by showing orbital degeneracy seemingly lasting to very low temperatures, with only small anomalies in magnetization and neutron experiments signaling a possible spin/orbital glass transition at T = 90 K. In epitaxial thin films presented in this paper, structurally tuning the CoV₂O₄ away from cubic symmetry leads to a completely different low temperature noncollinear ground state. Via magnetization and neutron scattering measurements we show that the 90-K transition is associated with a major spin reorientation away from the ferrimagnetic easy axis [001] to the [110] direction. Furthermore, the V spins cant away from this direction with extracted perpendicular moments providing evidence of a larger canting angle compared to bulk. This result indicates that compressive strain pushes the system deeper into the insulating state, i.e., away from the localized-itinerant crossover regime.

Authors:

Thompson, Christie ^[1]; Reig-i-Plessis, Dalmau ^[2]; Kish, Lasar ^[2];

^[3]; Zhang, Biwen ^[1]; Karapetrova, Evguenia A. ^[4]; MacDougall, Gregory J. ^[2]; Beekman, Christiane ^[1]

Florida State Univ., Tallahassee, FL (United States)
Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Thu Oct 25 00:00:00 EDT 2018

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1524779

Alternate Identifier(s):: OSTI ID: 1479137; OSTI ID: 1486960

Grant/Contract Number:: AC02-06CH11357; AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review Materials

Additional Journal Information:: Journal Volume: 2; Journal Issue: 10; Journal ID: ISSN 2475-9953

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Thompson, Christie, Reig-i-Plessis, Dalmau, Kish, Lasar, Aczel, A. A., Zhang, Biwen, Karapetrova, Evguenia A., MacDougall, Gregory J., and Beekman, Christiane. Spin canting and orbital order in spinel vanadate thin films.  United States: N. p., 2018. 
Web.  doi:10.1103/PhysRevMaterials.2.104411.

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                    Thompson, Christie, Reig-i-Plessis, Dalmau, Kish, Lasar, Aczel, A. A., Zhang, Biwen, Karapetrova, Evguenia A., MacDougall, Gregory J., & Beekman, Christiane. Spin canting and orbital order in spinel vanadate thin films.  United States.  https://doi.org/10.1103/PhysRevMaterials.2.104411

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                    Thompson, Christie, Reig-i-Plessis, Dalmau, Kish, Lasar, Aczel, A. A., Zhang, Biwen, Karapetrova, Evguenia A., MacDougall, Gregory J., and Beekman, Christiane. Thu .  
"Spin canting and orbital order in spinel vanadate thin films".  United States.  https://doi.org/10.1103/PhysRevMaterials.2.104411.  https://www.osti.gov/servlets/purl/1524779.

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@article{osti_1524779,

  title        = {Spin canting and orbital order in spinel vanadate thin films},

  author       = {Thompson, Christie and Reig-i-Plessis, Dalmau and Kish, Lasar and Aczel, A. A. and Zhang, Biwen and Karapetrova, Evguenia A. and MacDougall, Gregory J. and Beekman, Christiane},

  abstractNote = {Here, we report on the epitaxial film growth and characterization of CoV2O4, a near-itinerant spinel vanadate, grown on (001) SrTiO3. The symmetry lowering of the unit cell from cubic in the bulk to orthorhombic in the films results in dramatic differences in the magnetic anisotropy compared to bulk, as determined from structural and magnetic characterization. Bulk cubic CoV2O4 has been found to defy predictions by showing orbital degeneracy seemingly lasting to very low temperatures, with only small anomalies in magnetization and neutron experiments signaling a possible spin/orbital glass transition at T = 90 K. In epitaxial thin films presented in this paper, structurally tuning the CoV2O4 away from cubic symmetry leads to a completely different low temperature noncollinear ground state. Via magnetization and neutron scattering measurements we show that the 90-K transition is associated with a major spin reorientation away from the ferrimagnetic easy axis [001] to the [110] direction. Furthermore, the V spins cant away from this direction with extracted perpendicular moments providing evidence of a larger canting angle compared to bulk. This result indicates that compressive strain pushes the system deeper into the insulating state, i.e., away from the localized-itinerant crossover regime.},

  doi          = {10.1103/PhysRevMaterials.2.104411},

  journal      = {Physical Review Materials},

  number       = 10,

  volume       = 2,

  place        = {United States},

  year         = {Thu Oct 25 00:00:00 EDT 2018},

  month        = {Thu Oct 25 00:00:00 EDT 2018}

}

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https://doi.org/10.1103/PhysRevMaterials.2.104411

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Cited by: 5 works

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Figures / Tables:

Figure 1: XRD scan of the 00L peaks of a 100 nm thick CoV₂O₄ film and the SrTiO₃ substrate. The film and substrate peaks are indicated with CVO and STO, respectively.

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Title: Spin canting and orbital order in spinel vanadate thin films

Abstract

Citation Formats

Figures / Tables:

Frustrated Magnetism and Cooperative Phase Transitions in Spinels journal, January 2010

Macroscopic Degeneracy and Emergent Frustration in a Honeycomb Lattice Magnet journal, August 2011

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Nature of the Transition between a Ferromagnetic Metal and a Spin-Glass Insulator in Pyrochlore Molybdates journal, August 2007

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Design and performance of the 33-BM beamline at the Advanced Photon Source journal, September 2011

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Preferred alignment of twin boundaries in YBa 2 Cu 3 O x thin films and YBa 2 Cu 3 O x /PrBa 2 Cu 3 O x superlattices on SrTiO 3 journal, May 1991

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Orbital and magnetic transitions in geometrically frustrated vanadium spinels: Monte Carlo study of an effective spin-orbital-lattice coupled model journal, November 2004

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Magnetic Field Induced Transition in Vanadium Spinels journal, January 2014

Orbital Order in ZnV 2 O 4 journal, September 2007

A -Type Antiferro-Orbital Ordering with I 4 1 / a Symmetry and Geometrical Frustration in the Spinel Vanadate MgV 2 O 4 journal, December 2013

Probing Spin Correlations with Phonons in the Strongly Frustrated Magnet ZnCr 2 O 4 journal, April 2005

Critical behaviour of SrTiO3 near the 105°K phase transition journal, September 1971

The lattice constant vs. temperature relation around the 105 K transition of a flux-grown SrTiO 3 crystal journal, September 1985

Frustrated Magnetism and Cooperative Phase Transitions in Spinels
journal, January 2010

Macroscopic Degeneracy and Emergent Frustration in a Honeycomb Lattice Magnet
journal, August 2011

Geometrical frustration
journal, February 2006

Strongly Geometrically Frustrated Magnets
journal, August 1994

Metallic Spin-Liquid Behavior of the Geometrically Frustrated Kondo Lattice $\Pr_{2} {Ir}_{2} O_{7}$
journal, March 2006

Nature of the Transition between a Ferromagnetic Metal and a Spin-Glass Insulator in Pyrochlore Molybdates
journal, August 2007

Emergence of a Diffusive Metal State with No Magnetic Order near the Mott Transition in Frustrated Pyrochlore-Type Molybdates
journal, April 2009

Frustration-Induced Insulating Chiral Spin State in Itinerant Triangular-Lattice Magnets
journal, November 2010

Thin films of the spin ice compound Ho ₂ Ti ₂ O ₇
journal, March 2014

Restoration of the third law in spin ice thin films
journal, March 2014

Magnetic, structural, and thermal properties of CoV ₂ O ₄
journal, January 2012

Strong competition between orbital ordering and itinerancy in a frustrated spinel vanadate
journal, January 2015

The nature of itineracy in CoV ₂ O ₄ : a first-principles study
journal, January 2014

$Co [V_{2}] O_{4}$ : A Spinel Approaching the Itinerant Electron Limit
journal, February 2011

Dielectric properties of single crystal spinels in the series FeV $_{2}$ O $_{4}$ , MnV $_{2}$ O $_{4}$ , and CoV $_{2}$ O $_{4}$ in high magnetic fields
journal, February 2013

Chemical pressure effects on structural, magnetic, and transport properties of Mn $_{1 - x}$ Co $_{x}$ V $_{2}$ O $_{4}$
journal, November 2011

Ordering process and ferroelectricity in a spinel derived from FeV $_{2}$ O $_{4}$
journal, February 2012

Orbital and Spin Chains in ${Z n V}_{2} O_{4}$
journal, October 2004

Magnetic and Structural Transitions in (Li _x Zn _{1 - x} )V ₂ O ₄ with the Spinel Structure
journal, March 1997

Structural and magnetic studies on vanadium spinel MgV2O4
journal, April 1997

A pseudotetramer in the geometrically frustrated spinel system CdV ₂ O ₄
journal, July 2002

Spin and orbital order in the vanadium spinel ${MgV}_{2} O_{4}$
journal, October 2010

Magnetic order and ice rules in the multiferroic spinel FeV $_{2}$ O $_{4}$
journal, August 2012

Magnetic and Magnetodielectric Properties of Epitaxial Iron Vanadate Thin Films
journal, December 2016

Magnetic Frustration Driven by Itinerancy in Spinel CoV2O4
journal, December 2017

Microscopic evidence of magnetic and structure phase transition in multiferroic spinel FeV ₂ O ₄
journal, May 2017

Enhanced Pressure Dependence of Magnetic Exchange in $A^{2 +} [V_{2}] O_{4}$ Spinels Approaching the Itinerant Electron Limit
journal, November 2007

Structural transition and orbital glass physics in near-itinerant ${CoV}_{2} O_{4}$
journal, January 2016

Orbital Glass State of the Nearly Metallic Spinel Cobalt Vanadate
journal, January 2016

Design and performance of the 33-BM beamline at the Advanced Photon Source
journal, September 2011

Angle calculations for 3- and 4-circle X-ray and neutron diffractometers
journal, April 1967

Preferred alignment of twin boundaries in YBa ₂ Cu ₃ O _x thin films and YBa ₂ Cu ₃ O _x /PrBa ₂ Cu ₃ O _x superlattices on SrTiO ₃
journal, May 1991

Crystallographic and magnetic structure of ZnV $\mathsf{_2}$ O $\mathsf{_4}$
journal, October 2003

Orbital and magnetic transitions in geometrically frustrated vanadium spinels: Monte Carlo study of an effective spin-orbital-lattice coupled model
journal, November 2004

Magnetic and Orbital Ordering in the Spinel ${MnV}_{2} O_{4}$
journal, February 2008

Proposed Orbital Ordering in ${MnV}_{2} O_{4}$ from First-Principles Calculations
journal, May 2009

Observation of a first order transition in the ferrimagnetic spinel MnV2O4
journal, October 1987

Local order and frustration in the geometrically frustrated spinels ${Cd}_{1 - x} {Zn}_{x} V_{2} O_{4}$
journal, July 2006

Successive Orbital Ordering Transitions in ${NaVO}_{2}$
journal, October 2008

Magnetic properties of ${LaVO}_{3}$
journal, November 1992

Orbital ordering in transition-metal spinels
journal, January 2005

Orbital Physics in Transition-Metal Oxides
journal, April 2000

Magnetic transition and orbital degrees of freedom in vanadium spinels
journal, August 2003

Small crystal distortion and long-range antiferro-orbital ordering in the spinel oxide $Co V_{2} O_{4}$
journal, October 2017

Magnetic Field Induced Transition in Vanadium Spinels
journal, January 2014

Orbital Order in ${ZnV}_{2} O_{4}$
journal, September 2007

$A$ -Type Antiferro-Orbital Ordering with $I 4_{1} / a$ Symmetry and Geometrical Frustration in the Spinel Vanadate ${MgV}_{2} O_{4}$
journal, December 2013

Probing Spin Correlations with Phonons in the Strongly Frustrated Magnet ${ZnCr}_{2} O_{4}$
journal, April 2005

Critical behaviour of SrTiO3 near the 105°K phase transition
journal, September 1971

The lattice constant vs. temperature relation around the 105 K transition of a flux-grown SrTiO ₃ crystal
journal, September 1985