Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates

Pace, Kristen A.; Klepov, Vladislav V.; Morrison, Gregory; zur Loye, Hans-Conrad

doi:10.1039/C8CC07789D

Title: Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates

Abstract

The synthesis of five new U( iv , v ) and U( v , vi ) silicates points toward moderate supercritical synthesis as a new route to the stabilization of mixed-valent uranium compounds.

Authors:

^[1]; Klepov, Vladislav V. ^[2]; Morrison, Gregory ^[1];

^[1]

Department of Chemistry and Biochemistry, University of South Carolina, Columbia, USA, Center for Hierarchical Wasteform Materials, University of South Carolina
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, USA

Publication Date:: 2018-12-06

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1479120

Grant/Contract Number:: SC0016574

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Name: ChemComm Journal Volume: 54 Journal Issue: 98; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Pace, Kristen A., Klepov, Vladislav V., Morrison, Gregory, and zur Loye, Hans-Conrad. Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8CC07789D.

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                    Pace, Kristen A., Klepov, Vladislav V., Morrison, Gregory, & zur Loye, Hans-Conrad. Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates.  United Kingdom.  https://doi.org/10.1039/C8CC07789D

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                    Pace, Kristen A., Klepov, Vladislav V., Morrison, Gregory, and zur Loye, Hans-Conrad. Thu .  
"Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates".  United Kingdom.  https://doi.org/10.1039/C8CC07789D.

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@article{osti_1479120,

  title        = {Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates},

  author       = {Pace, Kristen A. and Klepov, Vladislav V. and Morrison, Gregory and zur Loye, Hans-Conrad},

  abstractNote = {The synthesis of five new U( iv , v ) and U( v , vi ) silicates points toward moderate supercritical synthesis as a new route to the stabilization of mixed-valent uranium compounds.},

  doi          = {10.1039/C8CC07789D},

  journal      = {ChemComm},

  number       = 98,

  volume       = 54,

  place        = {United Kingdom},

  year         = {2018},

  month        = {12}

}

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Title: Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates

Abstract

Citation Formats

Further Evidence for the Stabilization of U(V) within a Tetraoxo Core journal, May 2014

A Mixed-Valent Uranium Phosphonate Framework Containing U IV , U V , and U VI journal, July 2016

[Na7UIVO2(UVO)2(UV/VIO2)2Si4O16]: A Mixed-Valence Uranium Silicate journal, May 2010

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High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na 9 F 2 ][(U V O 2 )(U VI O 2 ) 2 (Si 2 O 7 ) 2 ] journal, May 2013

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Cs 2 K(UO) 2 Si 4 O 12 : A Mixed-Valence Uranium(IV,V) Silicate journal, October 2009

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Aspects of structure and activity in USboxide acrylonitrile catalysts journal, May 1972

Mixed-Valence Uranium Germanate and Silicate: Cs x (U V O)(U IV/V O) 2 (Ge 2 O 7 ) 2 ( x = 3.18) and Cs 4 (U V O)(U IV/V O) 2 (Si 2 O 7 ) 2 journal, April 2012

Further Evidence for the Stabilization of U(V) within a Tetraoxo Core
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A Mixed-Valent Uranium Phosphonate Framework Containing U ^IV , U ^V , and U ^VI
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[Na7UIVO2(UVO)2(UV/VIO2)2Si4O16]: A Mixed-Valence Uranium Silicate
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A ₃ (U ₂ O ₄ )(Ge ₂ O ₇ ) (A=Rb, Cs): Mixed-Valence Uranium(V,VI) Germanates
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X-ray photoemission spectroscopy study of hexavalent uranium compounds
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