Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates

Pace, Kristen A.; Klepov, Vladislav V.; Morrison, Gregory; zur Loye, Hans-Conrad

doi:10.1039/C8CC07789D

Title: Moderate supercritical synthesis as a facile route to mixed-valent uranium( iv , v ) and ( v , vi ) silicates

Journal Article · 05 December 2018 · ChemComm

DOI: https://doi.org/10.1039/C8CC07789D · OSTI ID:1479120

^[1]; Klepov, Vladislav V. ^[2]; Morrison, Gregory ^[1];

^[1]

Department of Chemistry and Biochemistry, University of South Carolina, Columbia, USA, Center for Hierarchical Wasteform Materials, University of South Carolina
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, USA

The synthesis of five new U( iv , v ) and U( v , vi ) silicates points toward moderate supercritical synthesis as a new route to the stabilization of mixed-valent uranium compounds.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0016574

OSTI ID:: 1479120

Alternate ID(s):: OSTI ID: 1566628

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 98 Vol. 54; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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