Studies of the homologs and pseudo-homologs of flerovium with crown ether based extraction chromatography resins

Despotopulos, John D.; Kmak, Kelly N.; Gharibyan, Narek; Moody, Kenton J.; Sudowe, Ralf; Shaughnessy, Dawn A.

doi:10.1007/s10967-018-6207-4

Title: Studies of the homologs and pseudo-homologs of flerovium with crown ether based extraction chromatography resins

Abstract

A crown-ether based extraction chromatography resin, Eichrom Pb, has been characterized for separations of the flerovium (Fl) pseudo-homolog Hg. Previous results on the batch uptake of Pb(II) and Sn(IV) are compared with newly investigated Hg(II) in HCl matrices. It was determined that all three elements can be strongly retained by the resin at different HCl concentrations. To assess the feasibility for performing an experiment on the chemical properties of Fl using this resin the extraction kinetics were studied. In conclusion, a separation method for the isolation of the homologs Pb(II) and Sn(IV) and pseudo-homolog Hg(II) has been established using 2 mL pre-packed Pb resin columns under vacuum flow.

Authors:

Despotopulos, John D. ^[1]; Kmak, Kelly N. ^[2]; Gharibyan, Narek ^[1]; Moody, Kenton J. ^[1]; Sudowe, Ralf ^[3]; Shaughnessy, Dawn A. ^[1]

Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Univ. of California Berkeley, Berkeley, CA (United States)
Colorado State Univ., Fort Collins, CO (United States)

Publication Date:: Wed Sep 26 00:00:00 EDT 2018

Research Org.:: Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1479086

Report Number(s):: LLNL-JRNL-725203
Journal ID: ISSN 0236-5731; 842746

Grant/Contract Number:: AC52-07NA27344

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Radioanalytical and Nuclear Chemistry

Additional Journal Information:: Journal Volume: 318; Journal Issue: 3; Journal ID: ISSN 0236-5731

Publisher:: Springer

Country of Publication:: United States

Language:: English

Subject:: 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; Macrocycles; Crown ethers; Extraction chromatography; Flerovium; Homologs; Heavy element; Mercury; Lead; Tin

Citation Formats


                    Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Moody, Kenton J., Sudowe, Ralf, and Shaughnessy, Dawn A. Studies of the homologs and pseudo-homologs of flerovium with crown ether based extraction chromatography resins.  United States: N. p., 2018. 
Web.  doi:10.1007/s10967-018-6207-4.

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                    Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Moody, Kenton J., Sudowe, Ralf, & Shaughnessy, Dawn A. Studies of the homologs and pseudo-homologs of flerovium with crown ether based extraction chromatography resins.  United States.  https://doi.org/10.1007/s10967-018-6207-4

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                    Despotopulos, John D., Kmak, Kelly N., Gharibyan, Narek, Moody, Kenton J., Sudowe, Ralf, and Shaughnessy, Dawn A. Wed .  
"Studies of the homologs and pseudo-homologs of flerovium with crown ether based extraction chromatography resins".  United States.  https://doi.org/10.1007/s10967-018-6207-4.  https://www.osti.gov/servlets/purl/1479086.

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@article{osti_1479086,

  title        = {Studies of the homologs and pseudo-homologs of flerovium with crown ether based extraction chromatography resins},

  author       = {Despotopulos, John D. and Kmak, Kelly N. and Gharibyan, Narek and Moody, Kenton J. and Sudowe, Ralf and Shaughnessy, Dawn A.},

  abstractNote = {A crown-ether based extraction chromatography resin, Eichrom Pb, has been characterized for separations of the flerovium (Fl) pseudo-homolog Hg. Previous results on the batch uptake of Pb(II) and Sn(IV) are compared with newly investigated Hg(II) in HCl matrices. It was determined that all three elements can be strongly retained by the resin at different HCl concentrations. To assess the feasibility for performing an experiment on the chemical properties of Fl using this resin the extraction kinetics were studied. In conclusion, a separation method for the isolation of the homologs Pb(II) and Sn(IV) and pseudo-homolog Hg(II) has been established using 2 mL pre-packed Pb resin columns under vacuum flow.},

  doi          = {10.1007/s10967-018-6207-4},

  journal      = {Journal of Radioanalytical and Nuclear Chemistry},

  number       = 3,

  volume       = 318,

  place        = {United States},

  year         = {Wed Sep 26 00:00:00 EDT 2018},

  month        = {Wed Sep 26 00:00:00 EDT 2018}

}

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Works referenced in this record:

Are elements 112, 114, and 118 relatively inert gases?
journal, July 1975

Pitzer, Kenneth S.
The Journal of Chemical Physics, Vol. 63, Issue 2
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Production and isolation of homologs of flerovium and element 115 at the Lawrence Livermore National Laboratory Center for Accelerator Mass Spectrometry
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Despotopulos, John D.; Kmak, Kelly N.; Gharibyan, Narek
Journal of Radioanalytical and Nuclear Chemistry, Vol. 308, Issue 2
DOI: 10.1007/s10967-015-4500-z

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A lead-selective extraction chromatographic resin and its application to the isolation of lead from geological samples
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Angewandte Chemie International Edition, Vol. 37, Issue 18
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Cyclic polyethers and their complexes with metal salts
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Pedersen, Charles J.
Journal of the American Chemical Society, Vol. 89, Issue 26
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Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in hydrochloric acid
journal, June 2016

Despotopulos, John D.; Kmak, Kelly N.; Gharibyan, Narek
Journal of Radioanalytical and Nuclear Chemistry, Vol. 310, Issue 3
DOI: 10.1007/s10967-016-4917-z

Atomic and Molecular Properties of Elements 112, 114, and 118
journal, April 2005

Nash, Clinton S.
The Journal of Physical Chemistry A, Vol. 109, Issue 15
DOI: 10.1021/jp050736o

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Title: Studies of the homologs and pseudo-homologs of flerovium with crown ether based extraction chromatography resins

Abstract

Citation Formats

Are elements 112, 114, and 118 relatively inert gases? journal, July 1975

Production and isolation of homologs of flerovium and element 115 at the Lawrence Livermore National Laboratory Center for Accelerator Mass Spectrometry journal, October 2015

Crystalline Salt Complexes of Macrocyclic Polyethers journal, January 1970

A lead-selective extraction chromatographic resin and its application to the isolation of lead from geological samples journal, July 1994

The preparation, performance and factors affecting band spreading of high efficiency extraction chromatographic columns for actinide separations journal, December 1972

The Stability of the Oxidation State +4 in Group 14 Compounds from Carbon to Element 114 journal, October 1998

Cyclic polyethers and their complexes with metal salts journal, December 1967

Characterization of the homologs of flerovium with crown ether based extraction chromatography resins: studies in hydrochloric acid journal, June 2016

Atomic and Molecular Properties of Elements 112, 114, and 118 journal, April 2005

Are elements 112, 114, and 118 relatively inert gases?
journal, July 1975

Production and isolation of homologs of flerovium and element 115 at the Lawrence Livermore National Laboratory Center for Accelerator Mass Spectrometry
journal, October 2015

Crystalline Salt Complexes of Macrocyclic Polyethers
journal, January 1970

A lead-selective extraction chromatographic resin and its application to the isolation of lead from geological samples
journal, July 1994

The preparation, performance and factors affecting band spreading of high efficiency extraction chromatographic columns for actinide separations
journal, December 1972

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journal, April 2005