DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Probing spatial coupling of resistive modes in porous intercalation electrodes through impedance spectroscopy

Journal Article · · Physical Chemistry Chemical Physics. PCCP
DOI: https://doi.org/10.1039/C8CP05109G · OSTI ID:1478674

The spatial coupling between the pore-scale microstructural resistances and the electrode-scale measurements is detailed via a physics-based, mechanistic description.

Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)
Grant/Contract Number:
CAEBAT III
OSTI ID:
1478674
Journal Information:
Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Vol. 21 Journal Issue: 7; ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 23 works
Citation information provided by
Web of Science

References (37)

Analysis of Long-Range Interaction in Lithium-Ion Battery Electrodes
  • Mistry, Aashutosh; Juarez-Robles, Daniel; Stein, Malcolm
  • Journal of Electrochemical Energy Conversion and Storage, Vol. 13, Issue 3 https://doi.org/10.1115/1.4035198
journal August 2016
Issues and challenges facing rechargeable lithium batteries journal November 2001
A comprehensive understanding of electrode thickness effects on the electrochemical performances of Li-ion battery cathodes journal June 2012
Transport-Geometry Interactions in Li-Ion Cathode Materials Imaged Using X-ray Nanotomography journal January 2017
Cooperation between Active Material, Polymeric Binder and Conductive Carbon Additive in Lithium Ion Battery Cathode journal February 2012
Electrochemistry Coupled Mesoscale Complexations in Electrodes Lead to Thermo-Electrochemical Extremes journal August 2018
Enabling fast charging – A battery technology gap assessment journal November 2017
Three-Phase Multiscale Modeling of a LiCoO 2 Cathode: Combining the Advantages of FIB-SEM Imaging and X-Ray Tomography journal November 2014
Mechanistic Understanding of the Role of Evaporation in Electrode Processing journal January 2017
Particles and Polymer Binder Interaction: A Controlling Factor in Lithium-Ion Electrode Performance journal January 2012
Electrochemistry and the Future of the Automobile journal June 2010
Calendering effects on the physical and electrochemical properties of Li[Ni1/3Mn1/3Co1/3]O2 cathode journal June 2012
Cathode Performance as a Function of Inactive Material and Void Fractions journal January 2010
Challenges in the development of advanced Li-ion batteries: a review journal January 2011
X-Ray Tomography for Lithium Ion Battery Research: A Practical Guide journal July 2017
Understanding limiting factors in thick electrode performance as applied to high energy density Li-ion batteries journal February 2017
A Combination of X-Ray Tomography and Carbon Binder Modeling: Reconstructing the Three Phases of LiCoO 2 Li-Ion Battery Cathodes journal January 2014
State-of-health monitoring of 18650 4S packs with a single-point impedance diagnostic journal November 2014
Comparison of three-dimensional analysis and stereological techniques for quantifying lithium-ion battery electrode microstructures: COMPARISON AND TECHNIQUES FOR QUANTIFYING LITHIUM-ION BATTERY journal March 2016
Building better batteries journal February 2008
X-Ray Tomography of Porous, Transition Metal Oxide Based Lithium Ion Battery Electrodes journal March 2013
Influence of Microstructure on Impedance Response in Intercalation Electrodes journal January 2015
Reversible Mg-Ion Insertion in a Metastable One-Dimensional Polymorph of V2O5 journal March 2018
Electrical Energy Storage for the Grid: A Battery of Choices journal November 2011
Defining Diffusion Pathways in Intercalation Cathode Materials: Some Lessons from V 2 O 5 on Directing Cation Traffic journal March 2018
Impedance Spectroscopy Characterization of Porous Electrodes under Different Electrode Thickness Using a Symmetric Cell for High-Performance Lithium-Ion Batteries journal February 2015
Electrolytes and Interphases in Li-Ion Batteries and Beyond journal October 2014
Is There a Benefit in Employing Graded Electrodes for Lithium-Ion Batteries? journal January 2017
Multi Length Scale Microstructural Investigations of a Commercially Available Li-Ion Battery Electrode journal January 2012
The use of contrast enhancement techniques in X-ray imaging of lithium–ion battery electrodes journal November 2016
Design of Battery Electrodes with Dual-Scale Porosity to Minimize Tortuosity and Maximize Performance journal December 2012
Secondary-Phase Stochastics in Lithium-Ion Battery Electrodes journal January 2018
A Guide to Li-Ion Coin-Cell Electrode Making for Academic Researchers journal January 2011
The Li-Ion Rechargeable Battery: A Perspective journal January 2013
Enabling fast charging – Vehicle considerations journal November 2017
Thick electrodes for Li-ion batteries: A model based analysis journal December 2016
Batteries for Electric and Hybrid-Electric Vehicles journal June 2010