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Title: Probing spatial coupling of resistive modes in porous intercalation electrodes through impedance spectroscopy

Abstract

The spatial coupling between the pore-scale microstructural resistances and the electrode-scale measurements is detailed via a physics-based, mechanistic description.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. School of Mechanical Engineering, Purdue University, West Lafayette, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
OSTI Identifier:
1478674
Grant/Contract Number:  
CAEBAT III
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print) Journal Volume: 21 Journal Issue: 7; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Mistry, Aashutosh N., and Mukherjee, Partha P. Probing spatial coupling of resistive modes in porous intercalation electrodes through impedance spectroscopy. United Kingdom: N. p., 2019. Web. doi:10.1039/C8CP05109G.
Mistry, Aashutosh N., & Mukherjee, Partha P. Probing spatial coupling of resistive modes in porous intercalation electrodes through impedance spectroscopy. United Kingdom. doi:10.1039/C8CP05109G.
Mistry, Aashutosh N., and Mukherjee, Partha P. Wed . "Probing spatial coupling of resistive modes in porous intercalation electrodes through impedance spectroscopy". United Kingdom. doi:10.1039/C8CP05109G.
@article{osti_1478674,
title = {Probing spatial coupling of resistive modes in porous intercalation electrodes through impedance spectroscopy},
author = {Mistry, Aashutosh N. and Mukherjee, Partha P.},
abstractNote = {The spatial coupling between the pore-scale microstructural resistances and the electrode-scale measurements is detailed via a physics-based, mechanistic description.},
doi = {10.1039/C8CP05109G},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 7,
volume = 21,
place = {United Kingdom},
year = {2019},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8CP05109G

Citation Metrics:
Cited by: 11 works
Citation information provided by
Web of Science

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Works referenced in this record:

Analysis of Long-Range Interaction in Lithium-Ion Battery Electrodes
journal, August 2016

  • Mistry, Aashutosh; Juarez-Robles, Daniel; Stein, Malcolm
  • Journal of Electrochemical Energy Conversion and Storage, Vol. 13, Issue 3
  • DOI: 10.1115/1.4035198

Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

A comprehensive understanding of electrode thickness effects on the electrochemical performances of Li-ion battery cathodes
journal, June 2012


Transport-Geometry Interactions in Li-Ion Cathode Materials Imaged Using X-ray Nanotomography
journal, January 2017

  • Nelson, George J.; Ausderau, Logan J.; Shin, SeungYoon
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.0261707jes

Cooperation between Active Material, Polymeric Binder and Conductive Carbon Additive in Lithium Ion Battery Cathode
journal, February 2012

  • Zheng, Honghe; Yang, Ruizhi; Liu, Gao
  • The Journal of Physical Chemistry C, Vol. 116, Issue 7
  • DOI: 10.1021/jp208428w

Electrochemistry Coupled Mesoscale Complexations in Electrodes Lead to Thermo-Electrochemical Extremes
journal, August 2018

  • Mistry, Aashutosh N.; Smith, Kandler; Mukherjee, Partha P.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 34
  • DOI: 10.1021/acsami.8b08993

Enabling fast charging – A battery technology gap assessment
journal, November 2017


Three-Phase Multiscale Modeling of a LiCoO 2 Cathode: Combining the Advantages of FIB-SEM Imaging and X-Ray Tomography
journal, November 2014

  • Zielke, Lukas; Hutzenlaub, Tobias; Wheeler, Dean R.
  • Advanced Energy Materials, Vol. 5, Issue 5
  • DOI: 10.1002/aenm.201401612

Mechanistic Understanding of the Role of Evaporation in Electrode Processing
journal, January 2017

  • Stein, Malcolm; Mistry, Aashutosh; Mukherjee, Partha P.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1271707jes

Particles and Polymer Binder Interaction: A Controlling Factor in Lithium-Ion Electrode Performance
journal, January 2012

  • Liu, G.; Zheng, H.; Song, X.
  • Journal of The Electrochemical Society, Vol. 159, Issue 3
  • DOI: 10.1149/2.024203jes

Electrochemistry and the Future of the Automobile
journal, June 2010

  • Wagner, Frederick T.; Lakshmanan, Balasubramanian; Mathias, Mark F.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 14
  • DOI: 10.1021/jz100553m

Calendering effects on the physical and electrochemical properties of Li[Ni1/3Mn1/3Co1/3]O2 cathode
journal, June 2012


Cathode Performance as a Function of Inactive Material and Void Fractions
journal, January 2010

  • Zheng, Honghe; Liu, Gao; Song, Xiangyun
  • Journal of The Electrochemical Society, Vol. 157, Issue 10
  • DOI: 10.1149/1.3459878

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

X-Ray Tomography for Lithium Ion Battery Research: A Practical Guide
journal, July 2017


Understanding limiting factors in thick electrode performance as applied to high energy density Li-ion batteries
journal, February 2017


A Combination of X-Ray Tomography and Carbon Binder Modeling: Reconstructing the Three Phases of LiCoO 2 Li-Ion Battery Cathodes
journal, January 2014

  • Zielke, Lukas; Hutzenlaub, Tobias; Wheeler, Dean R.
  • Advanced Energy Materials, Vol. 4, Issue 8
  • DOI: 10.1002/aenm.201301617

State-of-health monitoring of 18650 4S packs with a single-point impedance diagnostic
journal, November 2014


Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

X-Ray Tomography of Porous, Transition Metal Oxide Based Lithium Ion Battery Electrodes
journal, March 2013

  • Ebner, Martin; Geldmacher, Felix; Marone, Federica
  • Advanced Energy Materials, Vol. 3, Issue 7
  • DOI: 10.1002/aenm.201200932

Influence of Microstructure on Impedance Response in Intercalation Electrodes
journal, January 2015

  • Cho, Seongkoo; Chen, Chien-Fan; Mukherjee, Partha P.
  • Journal of The Electrochemical Society, Vol. 162, Issue 7
  • DOI: 10.1149/2.0331507jes

Reversible Mg-Ion Insertion in a Metastable One-Dimensional Polymorph of V2O5
journal, March 2018


Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011


Defining Diffusion Pathways in Intercalation Cathode Materials: Some Lessons from V 2 O 5 on Directing Cation Traffic
journal, March 2018


Impedance Spectroscopy Characterization of Porous Electrodes under Different Electrode Thickness Using a Symmetric Cell for High-Performance Lithium-Ion Batteries
journal, February 2015

  • Ogihara, Nobuhiro; Itou, Yuichi; Sasaki, Tsuyoshi
  • The Journal of Physical Chemistry C, Vol. 119, Issue 9
  • DOI: 10.1021/jp512564f

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014


Is There a Benefit in Employing Graded Electrodes for Lithium-Ion Batteries?
journal, January 2017

  • Qi, Yanbo; Jang, Taejin; Ramadesigan, Venkatasailanathan
  • Journal of The Electrochemical Society, Vol. 164, Issue 13
  • DOI: 10.1149/2.1051713jes

Multi Length Scale Microstructural Investigations of a Commercially Available Li-Ion Battery Electrode
journal, January 2012

  • Shearing, P. R.; Brandon, N. P.; Gelb, J.
  • Journal of The Electrochemical Society, Vol. 159, Issue 7
  • DOI: 10.1149/2.053207jes

The use of contrast enhancement techniques in X-ray imaging of lithium–ion battery electrodes
journal, November 2016

  • Taiwo, Oluwadamilola O.; Finegan, Donal P.; Gelb, Jeff
  • Chemical Engineering Science, Vol. 154
  • DOI: 10.1016/j.ces.2016.04.023

Design of Battery Electrodes with Dual-Scale Porosity to Minimize Tortuosity and Maximize Performance
journal, December 2012

  • Bae, Chang-Jun; Erdonmez, Can K.; Halloran, John W.
  • Advanced Materials, Vol. 25, Issue 9
  • DOI: 10.1002/adma.201204055

Secondary-Phase Stochastics in Lithium-Ion Battery Electrodes
journal, January 2018

  • Mistry, Aashutosh N.; Smith, Kandler; Mukherjee, Partha P.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 7
  • DOI: 10.1021/acsami.7b17771

A Guide to Li-Ion Coin-Cell Electrode Making for Academic Researchers
journal, January 2011

  • Marks, Thomas; Trussler, Simon; Smith, A. J.
  • Journal of The Electrochemical Society, Vol. 158, Issue 1
  • DOI: 10.1149/1.3515072

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

Enabling fast charging – Vehicle considerations
journal, November 2017


Thick electrodes for Li-ion batteries: A model based analysis
journal, December 2016


Batteries for Electric and Hybrid-Electric Vehicles
journal, June 2010