Electrochemical Applications of Microphase-Separated Block Copolymer Thin Films

Ito, Takashi; Ghimire, Govinda

doi:10.1002/celc.201800576

Title: Electrochemical Applications of Microphase-Separated Block Copolymer Thin Films

Journal Article · 15 July 2018 · ChemElectroChem

DOI: https://doi.org/10.1002/celc.201800576 · OSTI ID:1478305

^[1]; Ghimire, Govinda ^[2]

Kansas State Univ., Manhattan, KS (United States). Department of Chemistry; Kansas State University
Kansas State Univ., Manhattan, KS (United States). Department of Chemistry

In this work, we discuss electrochemical applications of electrode-supported thin films derived from microphase-separated block copolymers (BCPs). In contrast to conventional homopolymers used for electrode modification, BCPs afford periodic nanoscale structures (microdomains) of uniform dimensions (5-100 nm) and predictable morphologies, which can be controlled by adjusting the lengths of individual homopolymer segments. BCPs usable for electrochemical applications consist of two or more segments that form solute-permeable, redox-active or etchable microdomains and a chemically inert matrix. The resulting microdomains afford nanoscale molecular/charge transport pathways toward the underlying electrode, whereas the matrix serves as a scaffold to improve film stability in a solution. In conclusion, these polymeric thin films provide a unique means for fabricating nanowire arrays via template-based electrochemical synthesis, designing electrochemical sensors with unique selectivity, and constructing electrochemically-tunable functional materials.

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Research Organization:: Kansas State Univ., Manhattan, KS (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: SC0002362

OSTI ID:: 1478305

Alternate ID(s):: OSTI ID: 1461705

Journal Information:: ChemElectroChem, Journal Name: ChemElectroChem Journal Issue: 20 Vol. 5; ISSN 2196-0216

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Ultrahigh density array of CdSe nanorods for CdSe/polymer hybrid solar cells: enhancement in short-circuit current density Kwon, Seungchul; Shim, Myungsun; Lee, Jeung In Journal of Materials Chemistry, Vol. 21, Issue 33 https://doi.org/10.1039/c1jm11990g	journal	January 2011
Multidimensional performance optimization of conducting polymer-based supercapacitor electrodes Fong, Kara D.; Wang, Tiesheng; Smoukov, Stoyan K. Sustainable Energy & Fuels, Vol. 1, Issue 9 https://doi.org/10.1039/C7SE00339K	journal	January 2017
Ordered Network Mesostructures in Block Polymer Materials Meuler, Adam J.; Hillmyer, Marc A.; Bates, Frank S. Macromolecules, Vol. 42, Issue 19 https://doi.org/10.1021/ma9009593	journal	October 2009
Block Copolymer-Derived Monolithic Polymer Films and Membranes Comprising Self-Organized Cylindrical Nanopores for Chemical Sensing and Separations Ito, Takashi Chemistry - An Asian Journal, Vol. 9, Issue 10 https://doi.org/10.1002/asia.201402136	journal	June 2014
One step fabrication of nanoelectrode ensembles formed via amphiphilic block copolymers self-assembly and selective voltammetric detection of uric acid in the presence of high ascorbic acid content Wang, Chengyin; Liu, Qingxiu; Shao, Xiaoqiu Talanta, Vol. 71, Issue 1 https://doi.org/10.1016/j.talanta.2006.03.055	journal	January 2007
Poly(3-hexyl thiophene)- b -poly( N -isopropyl acrylamide): Synthesis and its composition dependent structural, solubility, thermoresponsive, electrochemical, and electronic properties Kumari, Pallavi; Khawas, Koomkoom; Hazra, Sunit Journal of Polymer Science Part A: Polymer Chemistry, Vol. 54, Issue 12 https://doi.org/10.1002/pola.28040	journal	January 2016

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Block Copolymer‐Derived Recessed Nanodisk‐Array Electrodes as Platforms for Folding‐Based Electrochemical DNA Sensors Harandizadeh, Zeinab; Ito, Takashi ChemElectroChem, Vol. 6, Issue 22 https://doi.org/10.1002/celc.201901562	journal	October 2019
Non‐Native Block Copolymer Thin Film Nanostructures Derived from Iterative Self‐Assembly Processes Demazy, Nils; Cummins, Cian; Aissou, Karim Advanced Materials Interfaces, Vol. 7, Issue 5 https://doi.org/10.1002/admi.201901747	journal	December 2019
Characterisation of the PS-PMMA Interfaces in Microphase Separated Block Copolymer Thin Films by Analytical (S)TEM Bürger, Julius; Kunnathully, Vinay S.; Kool, Daniel Nanomaterials, Vol. 10, Issue 1 https://doi.org/10.3390/nano10010141	journal	January 2020
Electrochemical Manipulation of Aligned Block Copolymer Templates Liu, Sherri S. Y.; Ludwigs, Sabine Macromolecular Rapid Communications, Vol. 41, Issue 1 https://doi.org/10.1002/marc.201900485	journal	November 2019
Nanoscale Block Copolymer Self‐Assembly and Microscale Polymer Film Dewetting: Progress in Understanding the Role of Interfacial Energies in the Formation of Hierarchical Nanostructures Brassat, Katharina; Lindner, Jörg K. N. Advanced Materials Interfaces, Vol. 7, Issue 5 https://doi.org/10.1002/admi.201901565	journal	December 2019

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