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Title: Variable coordination of carbazolyl-bis(tetrazole) ligands in lanthanide chemistry

Abstract

Lanthanide complexes of 1,8-bis(2′-isopropyltetrazo-5′-yl)-3,6-di- tert -butylcarbazolide adopt geometries that include planar, buckled and tetrazolyl-bridged tridentate, as well as bidentate, bonding modes.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [2]
  1. Department of Chemistry, University of Victoria, Victoria BC V8W 2Y2, Canada
  2. Department of Chemistry & Biochemistry, University of Notre Dame, Notre Dame, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1478263
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 43; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Gajecki, Leah, Berg, David J., Hoenisch, Josh, and Oliver, Allen G. Variable coordination of carbazolyl-bis(tetrazole) ligands in lanthanide chemistry. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT02757A.
Gajecki, Leah, Berg, David J., Hoenisch, Josh, & Oliver, Allen G. Variable coordination of carbazolyl-bis(tetrazole) ligands in lanthanide chemistry. United Kingdom. https://doi.org/10.1039/C8DT02757A
Gajecki, Leah, Berg, David J., Hoenisch, Josh, and Oliver, Allen G. Tue . "Variable coordination of carbazolyl-bis(tetrazole) ligands in lanthanide chemistry". United Kingdom. https://doi.org/10.1039/C8DT02757A.
@article{osti_1478263,
title = {Variable coordination of carbazolyl-bis(tetrazole) ligands in lanthanide chemistry},
author = {Gajecki, Leah and Berg, David J. and Hoenisch, Josh and Oliver, Allen G.},
abstractNote = {Lanthanide complexes of 1,8-bis(2′-isopropyltetrazo-5′-yl)-3,6-di- tert -butylcarbazolide adopt geometries that include planar, buckled and tetrazolyl-bridged tridentate, as well as bidentate, bonding modes.},
doi = {10.1039/C8DT02757A},
journal = {Dalton Transactions},
number = 43,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {11}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C8DT02757A

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Cited by: 2 works
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Works referenced in this record:

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

  • Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M.
  • Journal of Applied Crystallography, Vol. 48, Issue 1
  • DOI: 10.1107/S1600576714022985

Highly Active, Chemo- and Regioselective Yb II and Sm II Catalysts for the Hydrophosphination of Styrene with Phenylphosphine
journal, March 2015

  • Basalov, Ivan V.; Dorcet, Vincent; Fukin, Georgy K.
  • Chemistry - A European Journal, Vol. 21, Issue 16
  • DOI: 10.1002/chem.201500380

Anionic phenoxy-amido rare-earth complexes as efficient catalysts for amidation of aldehydes with amines
journal, January 2015

  • Wang, Chao; Huang, Lingling; Lu, Min
  • RSC Adv., Vol. 5, Issue 115
  • DOI: 10.1039/C5RA20285J

A N 2 3– Radical-Bridged Terbium Complex Exhibiting Magnetic Hysteresis at 14 K
journal, September 2011

  • Rinehart, Jeffrey D.; Fang, Ming; Evans, William J.
  • Journal of the American Chemical Society, Vol. 133, Issue 36
  • DOI: 10.1021/ja206286h

A cascade reaction: ring-opening insertion of dioxaphospholane into lutetium alkyl bonds
journal, January 2014

  • Johnson, Kevin R. D.; Hayes, Paul G.
  • Dalton Trans., Vol. 43, Issue 6
  • DOI: 10.1039/C3DT52790E

Synthesis, Structure, and Reactivity of Lanthanide Complexes Incorporating Indolyl Ligands in Novel Hapticities
journal, July 2013

  • Feng, Zhijun; Zhu, Xiancui; Wang, Shaoyin
  • Inorganic Chemistry, Vol. 52, Issue 16
  • DOI: 10.1021/ic401515q

Bis(pyrazolyl)carbazole as a Versatile Ligand for Supporting Lutetium Alkyl and Hydride Complexes
journal, June 2014

  • Johnson, Kevin R. D.; Kamenz, Breanne L.; Hayes, Paul G.
  • Organometallics, Vol. 33, Issue 12
  • DOI: 10.1021/om500226t

Self-assembly of highly luminescent lanthanide complexes promoted by pyridine-tetrazolate ligands
journal, January 2012

  • Andreiadis, Eugen S.; Imbert, Daniel; Pécaut, Jacques
  • Dalton Trans., Vol. 41, Issue 4
  • DOI: 10.1039/C1DT11627D

Organolutetium-Mediated Dearomatization and Functionalization of Pyrimidine Rings
journal, July 2013

  • Johnson, Kevin R. D.; Hayes, Paul G.
  • Organometallics, Vol. 32, Issue 15
  • DOI: 10.1021/om400413e

Phosphinomethanid-komplexe der lanthanoide
journal, November 1994

  • Karsch, Hans H.; Ferazin, Gunter; Kooijman, Huub
  • Journal of Organometallic Chemistry, Vol. 482, Issue 1-2
  • DOI: 10.1016/0022-328X(94)88197-9

Rare earth metal bisamido complexes with an NNO tridentate ligand and catalytic activity for the selective polymerization of isoprene
journal, January 2017

  • Gu, Xiaoxia; Wang, Shaowu; Wei, Yun
  • New Journal of Chemistry, Vol. 41, Issue 15
  • DOI: 10.1039/C7NJ01454F

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053273314026370

Cerium(IV) Imido Complexes: Structural, Computational, and Reactivity Studies
journal, February 2017

  • Solola, Lukman A.; Zabula, Alexander V.; Dorfner, Walter L.
  • Journal of the American Chemical Society, Vol. 139, Issue 6
  • DOI: 10.1021/jacs.6b12369

Migration of amide to imine group of lanthanide Schiff base complexes: effect of amido group
journal, January 2009

  • Qin, Duwei; Han, Fubin; Yao, Yingming
  • Dalton Transactions, Issue 28
  • DOI: 10.1039/b904580e

Synthesis, Structure, and Coordination Chemistry of a Tridentate, Six-Electron-Donor Amidinate Ligand
journal, December 1999

  • Kincaid, Kristi; Gerlach, Christopher P.; Giesbrecht, Garth R.
  • Organometallics, Vol. 18, Issue 25
  • DOI: 10.1021/om990365w

Unprecedented Application of Flexible Bis(pyridyl-tetrazole) Ligands To Construct Helix/Loop Subunits To Modify Polyoxometalate Anions
journal, June 2014

  • Wang, Xiu-Li; Li, Na; Tian, Ai-Xiang
  • Inorganic Chemistry, Vol. 53, Issue 14
  • DOI: 10.1021/ic403153f

Regioselective Oxidation Approaches to Concise Synthesis of (±)-Canabisin D
journal, March 2015


Ytterbium amides of linked bis(amidinate): synthesis, molecular structures, and reactivity for the polymerization of l-lactide
journal, January 2007

  • Wang, Junfeng; Cai, Tao; Yao, Yingming
  • Dalton Transactions, Issue 45
  • DOI: 10.1039/b709310a

Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction
journal, March 2008

  • Datta, Simmi; Gamer, Michael T.; Roesky, Peter W.
  • Organometallics, Vol. 27, Issue 6
  • DOI: 10.1021/om701014d

Synthesis, structure, and catalytic activity of organolanthanides with chiral biphenyl-based tridentate amidate ligands
journal, May 2011


Magnetic and magnetocaloric properties of an unusual family of carbonate-panelled [LnIII6ZnII2] cages
journal, January 2015

  • Sethi, Waqas; Sanz, Sergio; Pedersen, Kasper S.
  • Dalton Transactions, Vol. 44, Issue 22
  • DOI: 10.1039/C5DT01240F

N-Substituted Guanidinate Anions as Ancillary Ligands in Organolanthanide Chemistry. Synthesis and Characterization of {CyNC[N(SiMe 3 ) 2 ]NCy} 2 SmCH(SiMe 3 ) 2
journal, September 1998

  • Zhou, Yuanlin; Yap, Glenn P. A.; Richeson, Darrin S.
  • Organometallics, Vol. 17, Issue 20
  • DOI: 10.1021/om980480r

A series of lanthanoid selenidoantimonates( v ): rare examples of lanthanoid selenidoantimonates based on dinuclear lanthanide complexes
journal, January 2015

  • Xiao, Hong-Ping; Zhou, Jian; Zhao, Rong-Qing
  • Dalton Transactions, Vol. 44, Issue 13
  • DOI: 10.1039/C5DT00146C

Rare-earth metal complexes having an unusual indolyl-1,2-dianion through C–H activation with a novel η1:(μ2–η1:η1) bonding with metals
journal, January 2012

  • Zhu, Xiancui; Zhou, Shuangliu; Wang, Shaowu
  • Chemical Communications, Vol. 48, Issue 98
  • DOI: 10.1039/c2cc36045d

(NH4)2Ce(NO3)6 as an inexpensive, eco-friendly, efficient catalyst for the synthesis of 5-substituted 1-H tetrazoles from nitriles
journal, October 2014


Direct synthesis of a tetranuclear erbium(III) hydroxo cluster bearing a saturated Schiff base
journal, September 2002


Synthesis and Structure of Lanthanide Complexes Derived from the O,N-Chelating, Bis(methylpyridine)-Substituted Alcohol HOC(CMe3)(2-CH2NC5H3Me-6)2
journal, July 1995

  • Evans, William J.; Anwander, Reiner; Berlekamp, Uwe H.
  • Inorganic Chemistry, Vol. 34, Issue 14
  • DOI: 10.1021/ic00118a004

Ring opening polymerisation of lactide with uranium( iv ) and cerium( iv ) phosphinoaryloxide complexes
journal, January 2017

  • Sinclair, Fern; Hlina, Johann A.; Wells, Jordann A. L.
  • Dalton Transactions, Vol. 46, Issue 33
  • DOI: 10.1039/C7DT02167D

Space groups P 1 and Cc : how are they doing?
journal, November 2009


Preparation and Study of 1,8-Di(pyrid-2′-yl)carbazoles
journal, September 2008

  • Mudadu, Maria S.; Singh, Ajay N.; Thummel, Randolph P.
  • The Journal of Organic Chemistry, Vol. 73, Issue 17
  • DOI: 10.1021/jo801132w

Ytterbium(III) Complexes Coordinated by Dianionic 1,4-Diazabutadiene Ligands
journal, April 2015

  • Shestakov, Boris G.; Mahrova, Tatyana V.; Larionova, Joulia
  • Organometallics, Vol. 34, Issue 7
  • DOI: 10.1021/om501121s

Ligand Recognition Processes in the Formation of Homochiral C 3 -Symmetric LnL 3 Complexes of a Chiral Alkoxide
journal, August 2009

  • Arnold, Polly L.; Buffet, Jean-Charles; Blaudeck, Robert
  • Chemistry - A European Journal, Vol. 15, Issue 33
  • DOI: 10.1002/chem.200900522

Synthesis, structure, and catalytic activity of organolanthanide complexes with chiral biaryl Schiff-base ligands
journal, May 2014


Carbon−Carbon Bond Formation Using Yttrium(III) and the Lanthanide Elements
journal, April 2001

  • Fryzuk, Michael D.; Jafarpour, Laleh; Kerton, Francesca M.
  • Organometallics, Vol. 20, Issue 7
  • DOI: 10.1021/om000755e

Solvothermal syntheses and optical properties of hexathiostannates containing samarium(III) complexes with different ethylene polyamines
journal, April 2010


Ligand influence on intramolecular cyclometalation in bis(phosphinimine) rare earth alkyl complexes
journal, April 2016

  • Johnson, Kevin R. D.; Kamenz, Breanne L.; Hayes, Paul G.
  • Canadian Journal of Chemistry, Vol. 94, Issue 4
  • DOI: 10.1139/cjc-2015-0368

Bimetallic Complexes of Ytterbium and Europium Stabilized by Sterically Demanding Dipyridylamides
journal, March 2009

  • Dietel, Anna M.; Döring, Christian; Glatz, Germund
  • European Journal of Inorganic Chemistry, Vol. 2009, Issue 8
  • DOI: 10.1002/ejic.200801055

Kinetic and Mechanistic Investigation of Metallacycle Ring Opening in an Ortho-Metalated Lutetium Aryl Complex
journal, January 2011

  • Johnson, Kevin R. D.; Hayes, Paul G.
  • Organometallics, Vol. 30, Issue 1
  • DOI: 10.1021/om100814h

Low co-ordination numbers in lanthanide and actinide compounds. Part I. The preparation and characterization of tris{bis(trimethylsilyl)-amido}lanthanides
journal, January 1973

  • Bradley, Donald C.; Ghotra, Joginder S.; Hart, F. Alan
  • Journal of the Chemical Society, Dalton Transactions, Issue 10
  • DOI: 10.1039/dt9730001021

Bis(amidinate) ligands in early lanthanide chemistry – synthesis, structures, and hydroamination catalysis
journal, January 2017

  • Kazeminejad, Neda; Munzel, Denise; Gamer, Michael T.
  • Chemical Communications, Vol. 53, Issue 6
  • DOI: 10.1039/C6CC08958E

Synthesis and Reactivity of Dialkyl Lutetium Complexes Supported by a Novel Bis(phosphinimine)carbazole Pincer Ligand
journal, November 2009

  • Johnson, Kevin R. D.; Hayes, Paul G.
  • Organometallics, Vol. 28, Issue 21
  • DOI: 10.1021/om900731x

Yttrium and scandium complexes of a bulky bis(phosphinimine)carbazole ligand
journal, October 2014


Fully Metalated Silsesquioxanes: Building Blocks for the Construction of Catalyst Models
journal, September 2004

  • Lorenz, Volker; Gießmann, Stephan; Gun'ko, Yurii K.
  • Angewandte Chemie International Edition, Vol. 43, Issue 35
  • DOI: 10.1002/anie.200454094

Mononuclear, Five-Coordinate Lanthanide Amido and Aryloxide Complexes Bearing Tetradentate (N 2 O 2 ) Schiff Bases
journal, October 2004

  • Schuetz, Steven A.; Silvernail, Carter M.; Incarvito, Christopher D.
  • Inorganic Chemistry, Vol. 43, Issue 20
  • DOI: 10.1021/ic040006f