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Title: A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2

Abstract

Abstract Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO 2 /H 2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO 2 . We present a molybdenum phosphide catalyst for CO and CO 2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO 2 /H 2 feeds.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [1]
  1. SUNCAT Center for Interface Science and Catalysis Stanford University Stanford CA 94305 USA, SLAC National Accelerator Laboratory Menlo Park CA 94025 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1478125
Grant/Contract Number:  
DEAC02-76SF00515
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 46; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., and Jaramillo, Thomas F. A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2. Germany: N. p., 2018. Web. doi:10.1002/ange.201806583.
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., & Jaramillo, Thomas F. A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2. Germany. https://doi.org/10.1002/ange.201806583
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., and Jaramillo, Thomas F. Thu . "A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2". Germany. https://doi.org/10.1002/ange.201806583.
@article{osti_1478125,
title = {A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2},
author = {Duyar, Melis S. and Tsai, Charlie and Snider, Jonathan L. and Singh, Joseph A. and Gallo, Alessandro and Yoo, Jong Suk and Medford, Andrew J. and Abild‐Pedersen, Frank and Studt, Felix and Kibsgaard, Jakob and Bent, Stacey F. and Nørskov, Jens K. and Jaramillo, Thomas F.},
abstractNote = {Abstract Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO 2 /H 2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO 2 . We present a molybdenum phosphide catalyst for CO and CO 2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO 2 /H 2 feeds.},
doi = {10.1002/ange.201806583},
journal = {Angewandte Chemie},
number = 46,
volume = 130,
place = {Germany},
year = {Thu Oct 18 00:00:00 EDT 2018},
month = {Thu Oct 18 00:00:00 EDT 2018}
}

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