A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2
Abstract
Abstract Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO 2 /H 2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO 2 . We present a molybdenum phosphide catalyst for CO and CO 2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO 2 /H 2 feeds.
- Authors:
-
- SUNCAT Center for Interface Science and Catalysis Stanford University Stanford CA 94305 USA, SLAC National Accelerator Laboratory Menlo Park CA 94025 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1478125
- Grant/Contract Number:
- DEAC02-76SF00515
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Angewandte Chemie
- Additional Journal Information:
- Journal Name: Angewandte Chemie Journal Volume: 130 Journal Issue: 46; Journal ID: ISSN 0044-8249
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., and Jaramillo, Thomas F. A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2. Germany: N. p., 2018.
Web. doi:10.1002/ange.201806583.
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., & Jaramillo, Thomas F. A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2. Germany. https://doi.org/10.1002/ange.201806583
Duyar, Melis S., Tsai, Charlie, Snider, Jonathan L., Singh, Joseph A., Gallo, Alessandro, Yoo, Jong Suk, Medford, Andrew J., Abild‐Pedersen, Frank, Studt, Felix, Kibsgaard, Jakob, Bent, Stacey F., Nørskov, Jens K., and Jaramillo, Thomas F. Thu .
"A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2". Germany. https://doi.org/10.1002/ange.201806583.
@article{osti_1478125,
title = {A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2},
author = {Duyar, Melis S. and Tsai, Charlie and Snider, Jonathan L. and Singh, Joseph A. and Gallo, Alessandro and Yoo, Jong Suk and Medford, Andrew J. and Abild‐Pedersen, Frank and Studt, Felix and Kibsgaard, Jakob and Bent, Stacey F. and Nørskov, Jens K. and Jaramillo, Thomas F.},
abstractNote = {Abstract Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO 2 /H 2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO 2 . We present a molybdenum phosphide catalyst for CO and CO 2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO 2 /H 2 feeds.},
doi = {10.1002/ange.201806583},
journal = {Angewandte Chemie},
number = 46,
volume = 130,
place = {Germany},
year = {Thu Oct 18 00:00:00 EDT 2018},
month = {Thu Oct 18 00:00:00 EDT 2018}
}
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