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Title: Unimolecular decomposition kinetics of the stabilised Criegee intermediates CH 2OO and CD 2OO

Abstract

Decomposition kinetics of stabilised CH 2 OO and CD 2 OO Criegee intermediates have been investigated as a function of temperature (450–650 K) and pressure (2–350 Torr) using flash photolysis coupled with time-resolved cavity-enhanced broadband UV absorption spectroscopy.

Authors:
ORCiD logo [1];  [2];  [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [2]; ORCiD logo [2]
  1. Univ. of Leeds, Leeds (United Kingdom)
  2. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-CA), Livermore, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1477897
Alternate Identifier(s):
OSTI ID: 1471779; OSTI ID: 1474125
Report Number(s):
SAND-2018-8055J
Journal ID: ISSN 1463-9076; 666103
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Published Article
Journal Name:
Physical Chemistry Chemical Physics. PCCP (Print)
Additional Journal Information:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 20; Journal Issue: 38; Journal ID: ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Stone, Daniel, Au, Kendrew, Sime, Samantha, Medeiros, Diogo J., Blitz, Mark, Seakins, Paul W., Decker, Zachary, and Sheps, Leonid. Unimolecular decomposition kinetics of the stabilised Criegee intermediates CH2OO and CD2OO. United States: N. p., 2018. Web. doi:10.1039/c8cp05332d.
Stone, Daniel, Au, Kendrew, Sime, Samantha, Medeiros, Diogo J., Blitz, Mark, Seakins, Paul W., Decker, Zachary, & Sheps, Leonid. Unimolecular decomposition kinetics of the stabilised Criegee intermediates CH2OO and CD2OO. United States. doi:10.1039/c8cp05332d.
Stone, Daniel, Au, Kendrew, Sime, Samantha, Medeiros, Diogo J., Blitz, Mark, Seakins, Paul W., Decker, Zachary, and Sheps, Leonid. Wed . "Unimolecular decomposition kinetics of the stabilised Criegee intermediates CH2OO and CD2OO". United States. doi:10.1039/c8cp05332d.
@article{osti_1477897,
title = {Unimolecular decomposition kinetics of the stabilised Criegee intermediates CH2OO and CD2OO},
author = {Stone, Daniel and Au, Kendrew and Sime, Samantha and Medeiros, Diogo J. and Blitz, Mark and Seakins, Paul W. and Decker, Zachary and Sheps, Leonid},
abstractNote = {Decomposition kinetics of stabilised CH 2 OO and CD 2 OO Criegee intermediates have been investigated as a function of temperature (450–650 K) and pressure (2–350 Torr) using flash photolysis coupled with time-resolved cavity-enhanced broadband UV absorption spectroscopy.},
doi = {10.1039/c8cp05332d},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 38,
volume = 20,
place = {United States},
year = {2018},
month = {9}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/c8cp05332d

Citation Metrics:
Cited by: 1 work
Citation information provided by
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