Formaldehyde–isobutene Prins condensation over MFI-type zeolites

Vasiliadou, Efterpi S.; Li, Sha; Caratzoulas, Stavros; Lobo, Raul F.

doi:10.1039/C8CY01667D

Title: Formaldehyde–isobutene Prins condensation over MFI-type zeolites

Abstract

H-ZSM-5 was identified as the most efficient catalyst for the liquid phase Prins condensation of formaldehyde with isobutene to 3-methyl-3-buten-1-ol and subsequently isoprene.

Authors:

^[1]; Li, Sha ^[1]; Caratzoulas, Stavros ^[1];

^[1]

Department of Chemical and Biomolecular Engineering, Catalysis Center for Energy Innovation, University of Delaware, Newark, USA

Publication Date:: 2018-11-13

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1477894

Grant/Contract Number:: SC0001004

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Catalysis Science and Technology

Additional Journal Information:: Journal Name: Catalysis Science and Technology Journal Volume: 8 Journal Issue: 22; Journal ID: ISSN 2044-4753

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Vasiliadou, Efterpi S., Li, Sha, Caratzoulas, Stavros, and Lobo, Raul F. Formaldehyde–isobutene Prins condensation over MFI-type zeolites.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8CY01667D.

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                    Vasiliadou, Efterpi S., Li, Sha, Caratzoulas, Stavros, & Lobo, Raul F. Formaldehyde–isobutene Prins condensation over MFI-type zeolites.  United Kingdom.  https://doi.org/10.1039/C8CY01667D

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                    Vasiliadou, Efterpi S., Li, Sha, Caratzoulas, Stavros, and Lobo, Raul F. Tue .  
"Formaldehyde–isobutene Prins condensation over MFI-type zeolites".  United Kingdom.  https://doi.org/10.1039/C8CY01667D.

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@article{osti_1477894,

  title        = {Formaldehyde–isobutene Prins condensation over MFI-type zeolites},

  author       = {Vasiliadou, Efterpi S. and Li, Sha and Caratzoulas, Stavros and Lobo, Raul F.},

  abstractNote = {H-ZSM-5 was identified as the most efficient catalyst for the liquid phase Prins condensation of formaldehyde with isobutene to 3-methyl-3-buten-1-ol and subsequently isoprene.},

  doi          = {10.1039/C8CY01667D},

  journal      = {Catalysis Science and Technology},

  number       = 22,

  volume       = 8,

  place        = {United Kingdom},

  year         = {2018},

  month        = {11}

}

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Title: Formaldehyde–isobutene Prins condensation over MFI-type zeolites

Abstract

Citation Formats

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A Combined Kinetic−Quantum Mechanical Model for Assessment of Catalytic Cycles: Application to Cross-Coupling and Heck Reactions journal, March 2006

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The Ene Reaction journal, August 1969

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Transition Structures of the Ene Reactions of Cyclopropene journal, July 1997

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Adsorption in zeolites using mechanically embedded ONIOM clusters
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Tandem Diels-Alder Reaction of Dimethylfuran and Ethylene and Dehydration to para -Xylene Catalyzed by Zeotypic Lewis Acids
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Role of Frontier Orbitals in Chemical Reactions
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Catalytic performance of Metal-Organic-Frameworks vs. extra-large pore zeolite UTL in condensation reactions
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A Combined Kinetic−Quantum Mechanical Model for Assessment of Catalytic Cycles: Application to Cross-Coupling and Heck Reactions
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Isoprene by Prins Condensation over Acidic Molecular Sieves
journal, August 1997

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Theoretical Prediction of a Perepoxide Intermediate for the Reaction of Singlet Oxygen with trans -Cyclooctene Contrasts with the Two-Step No-Intermediate Ene Reaction for Acyclic Alkenes
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The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals
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“Turning Over” Definitions in Catalytic Cycles
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The Ene Reaction
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Catalytic reaction of 1,3-butanediol over solid acids
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Chemocatalytic Conversion of Ethanol into Butadiene and Other Bulk Chemicals
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Transition Structures of the Ene Reactions of Cyclopropene
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Catalysis of the Diels–Alder Reaction of Furan and Methyl Acrylate in Lewis Acidic Zeolites
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Vapor-phase synthesis of isoprene from formaldehyde and isobutylene over CuSO4−MOx/SiO2 catalysts
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Enhanced activity of MCM-48 based tin catalyst for synthesis of 3-methylbut-3-en-1-ol by adjusting the mesochannel environment
journal, November 2014

Isoprene synthesis from formaldehyde and isobutene over Keggin-type heteropolyacids supported on silica
journal, January 2016