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Title: Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction

Characterization of a Ni III species during reductive catalysis by [Ni(cyclam)] 2+ implicates an ECCE mechanism for hydrogen production in aqueous solution.
Authors:
 [1] ; ORCiD logo [2] ; ORCiD logo [3]
  1. Department of Chemistry and Biochemistry, The Ohio State University, Columbus, USA
  2. Ohio State Biochemistry Program, The Ohio State University, Columbus, USA
  3. Department of Chemistry and Biochemistry, The Ohio State University, Columbus, USA, Ohio State Biochemistry Program
Publication Date:
Grant/Contract Number:
SC0018020
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 42; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1477803

Behnke, Shelby L., Manesis, Anastasia C., and Shafaat, Hannah S.. Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction. United Kingdom: N. p., Web. doi:10.1039/C8DT02873G.
Behnke, Shelby L., Manesis, Anastasia C., & Shafaat, Hannah S.. Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction. United Kingdom. doi:10.1039/C8DT02873G.
Behnke, Shelby L., Manesis, Anastasia C., and Shafaat, Hannah S.. 2018. "Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction". United Kingdom. doi:10.1039/C8DT02873G.
@article{osti_1477803,
title = {Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction},
author = {Behnke, Shelby L. and Manesis, Anastasia C. and Shafaat, Hannah S.},
abstractNote = {Characterization of a Ni III species during reductive catalysis by [Ni(cyclam)] 2+ implicates an ECCE mechanism for hydrogen production in aqueous solution.},
doi = {10.1039/C8DT02873G},
journal = {Dalton Transactions},
number = 42,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {10}
}

Works referenced in this record:

Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
journal, August 1994
  • Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio
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A review of the aqueous electrochemical reduction of CO2 to hydrocarbons at copper
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Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
journal, September 1980
  • Fisher, Barbara J.; Eisenberg, Richard
  • Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363
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EasySpin, a comprehensive software package for spectral simulation and analysis in EPR
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