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Title: Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction

Abstract

Characterization of a Ni III species during reductive catalysis by [Ni(cyclam)] 2+ implicates an ECCE mechanism for hydrogen production in aqueous solution.

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Department of Chemistry and Biochemistry, The Ohio State University, Columbus, USA
  2. Ohio State Biochemistry Program, The Ohio State University, Columbus, USA
  3. Department of Chemistry and Biochemistry, The Ohio State University, Columbus, USA, Ohio State Biochemistry Program
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1477803
Grant/Contract Number:  
SC0018020
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 42; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Behnke, Shelby L., Manesis, Anastasia C., and Shafaat, Hannah S. Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT02873G.
Behnke, Shelby L., Manesis, Anastasia C., & Shafaat, Hannah S. Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction. United Kingdom. doi:10.1039/C8DT02873G.
Behnke, Shelby L., Manesis, Anastasia C., and Shafaat, Hannah S. Tue . "Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction". United Kingdom. doi:10.1039/C8DT02873G.
@article{osti_1477803,
title = {Spectroelectrochemical investigations of nickel cyclam indicate different reaction mechanisms for electrocatalytic CO 2 and H + reduction},
author = {Behnke, Shelby L. and Manesis, Anastasia C. and Shafaat, Hannah S.},
abstractNote = {Characterization of a Ni III species during reductive catalysis by [Ni(cyclam)] 2+ implicates an ECCE mechanism for hydrogen production in aqueous solution.},
doi = {10.1039/C8DT02873G},
journal = {Dalton Transactions},
number = 42,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8DT02873G

Citation Metrics:
Cited by: 2 works
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