Nuclearity effects in supported, single-site Fe(ii) hydrogenation pre-catalysts

Langeslay, Ryan R.; Sohn, Hyuntae; Hu, Bo; Mohar, Jacob S.; Ferrandon, Magali; Liu, Cong; Kim, Hacksung; Kropf, A. Jeremy; Yang, Ce; Niklas, Jens; Poluektov, Oleg G.; Alp, E. Ercan; Ignacio-de Leon, Patricia; Sattelberger, Alfred P.; Hock, Adam S.; Delferro, Massimiliano

doi:10.1039/c8dt02720j

Title: Nuclearity effects in supported, single-site Fe(ii) hydrogenation pre-catalysts

Journal Article · 17 July 2018 · Dalton Transactions

DOI: https://doi.org/10.1039/c8dt02720j · OSTI ID:1477505

^[1]; Sohn, Hyuntae ^[1]; Hu, Bo ^[2]; Mohar, Jacob S. ^[1]; Ferrandon, Magali ^[1]; Liu, Cong ^[1]; Kim, Hacksung ^[3]; Kropf, A. Jeremy ^[1];

^[1];

^[1]; Alp, E. Ercan ^[1]; Ignacio-de Leon, Patricia ^[1]; Sattelberger, Alfred P. ^[1]; Hock, Adam S. ^[2];

^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Illinois Institute of Technology, Chicago, IL (United States)
Argonne National Lab. (ANL), Lemont, IL (United States); Northwestern Univ., Evanston, IL (United States)

Dimeric and monomeric supported single-site Fe(II) pre-catalysts on SiO₂ have been prepared via organometallic grafting and characterized with advanced spectroscopic techniques. Manipulation of the surface hydroxyl concentration on the support influences monomer/dimer formation. While both pre-catalysts are highly active in liquid-phase hydrogenation, the dimeric pre-catalyst is ~3× faster than the monomer. Here, preliminary XAS experiments on the H₂-activated samples suggest the active species are isolated Fe(II) sites.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1477505

Alternate ID(s):: OSTI ID: 1460591

Journal Information:: Dalton Transactions, Vol. 47, Issue 32; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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