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Title: Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes

Abstract

We present that hydrogen sulfide removal is a long-standing economic and environmental challenge faced by the oil and gas industries. H 2S separation using reactive and non-reactive absorption and adsorption, membranes, and cryogenic distillation are reviewed. A detailed discussion on new developments in adsorbents, such as metal oxides, metals, metal–organic frameworks, zeolites, carbon-based materials, and composite materials, absorbents, such as ionic liquids, and membrane technologies for H 2S removal, is presented. Here, this review attempts to exhaustively compile the existing literature on sour gas sweetening and to identify promising areas for future developments in the field.

Authors:
 [1];  [1]; ORCiD logo [2]
  1. Univ. of Minnesota, Minneapolis, MN (United States). Department of Chemical Engineering and Materials Science
  2. Univ. of Minnesota, Minneapolis, MN (United States). Department of Chemical Engineering and Materials Science and Department of Chemistry and Chemical Theory Center
Publication Date:
Research Org.:
Univ. of Minnesota, Minneapolis, MN (United States). Nanoporous Materials Genome Center; Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division
Contributing Org.:
Center for Gas Separations Relevant to Clean Energy Technologies
OSTI Identifier:
1477222
Grant/Contract Number:  
FG02-12ER16362; SC0008688
Resource Type:
Accepted Manuscript
Journal Name:
Chemical Reviews
Additional Journal Information:
Journal Volume: 117; Journal Issue: 14; Journal ID: ISSN 0009-2665
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Shah, Mansi S., Tsapatsis, Michael, and Siepmann, J. Ilja. Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes. United States: N. p., 2017. Web. doi:10.1021/acs.chemrev.7b00095.
Shah, Mansi S., Tsapatsis, Michael, & Siepmann, J. Ilja. Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes. United States. doi:10.1021/acs.chemrev.7b00095.
Shah, Mansi S., Tsapatsis, Michael, and Siepmann, J. Ilja. Wed . "Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes". United States. doi:10.1021/acs.chemrev.7b00095. https://www.osti.gov/servlets/purl/1477222.
@article{osti_1477222,
title = {Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes},
author = {Shah, Mansi S. and Tsapatsis, Michael and Siepmann, J. Ilja},
abstractNote = {We present that hydrogen sulfide removal is a long-standing economic and environmental challenge faced by the oil and gas industries. H2S separation using reactive and non-reactive absorption and adsorption, membranes, and cryogenic distillation are reviewed. A detailed discussion on new developments in adsorbents, such as metal oxides, metals, metal–organic frameworks, zeolites, carbon-based materials, and composite materials, absorbents, such as ionic liquids, and membrane technologies for H2S removal, is presented. Here, this review attempts to exhaustively compile the existing literature on sour gas sweetening and to identify promising areas for future developments in the field.},
doi = {10.1021/acs.chemrev.7b00095},
journal = {Chemical Reviews},
number = 14,
volume = 117,
place = {United States},
year = {2017},
month = {7}
}

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Works referencing / citing this record:

Isostructural lanthanide-based metal–organic frameworks: structure, photoluminescence and magnetic properties
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Phosphonium zwitterions for lighter and chemically-robust MOFs: highly reversible H 2 S capture and solvent-triggered release
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  • Reynolds, Joseph E.; Bohnsack, Alisha M.; Kristek, David J.
  • Journal of Materials Chemistry A, Vol. 7, Issue 28
  • DOI: 10.1039/c9ta05444h