Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures

Hlova, Ihor Z.; Dolotko, Oleksandr; Boote, Brett W.; Pathak, Arjun K.; Smith, Emily A.; Pecharsky, Vitalij K.; Balema, Viktor P.

doi:10.1039/C8CC06766J

Title: Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures

Abstract

Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. As a result, physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.

Authors:

Hlova, Ihor Z. ^[1]; Dolotko, Oleksandr ^[1]; Boote, Brett W. ^[1];

^[1];

^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States)

Publication Date:: 2018-09-24

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1477202

Alternate Identifier(s):: OSTI ID: 1475079

Report Number(s):: IS-J-9760
Journal ID: ISSN 1359-7345

Grant/Contract Number:: AC02-07CH11358; Laboratory Directed Research and Development (LDRD) program

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 54; Journal Issue: 89; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., and Balema, Viktor P.. Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures.  United States: N. p., 2018. 
Web.  doi:10.1039/C8CC06766J.

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                    Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., & Balema, Viktor P.. Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures.  United States.  https://doi.org/10.1039/C8CC06766J

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                    Hlova, Ihor Z., Dolotko, Oleksandr, Boote, Brett W., Pathak, Arjun K., Smith, Emily A., Pecharsky, Vitalij K., and Balema, Viktor P.. Mon .  
"Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures".  United States.  https://doi.org/10.1039/C8CC06766J.  https://www.osti.gov/servlets/purl/1477202.

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@article{osti_1477202,

  title        = {Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures},

  author       = {Hlova, Ihor Z. and Dolotko, Oleksandr and Boote, Brett W. and Pathak, Arjun K. and Smith, Emily A. and Pecharsky, Vitalij K. and Balema, Viktor P.},

  abstractNote = {Transition metal dichalcogenides combining multiple principal elements in their structures are synthesized via mechanochemical exfoliation and spontaneous reassembly of binary precursors into 3D-heterostructures that are converted into single-phase layered materials by high-temperature reactive fusion. As a result, physical and chemical events enabling these transformations are summarized in the form of a conceivable reaction mechanism.},

  doi          = {10.1039/C8CC06766J},

  journal      = {ChemComm},

  number       = 89,

  volume       = 54,

  place        = {United States},

  year         = {2018},

  month        = {9}

}

Copy to clipboard

Journal Article:

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https://doi.org/10.1039/C8CC06766J

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Cited by: 7 works

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Figures / Tables:

Fig. 1: (Mo_0.5W_0.5)S₂. (a) XRD patterns and (b) Raman spectra of as-milled and milled then fused equimolar mixtures of MoS₂ and WS₂. Vertical bars in (a) indicate the Bragg peak positions of starting materials. Chart (b) also shows the Raman spectra of MoS₂ and WS₂.

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Title: Multi-principal element transition metal dichalcogenides via reactive fusion of 3D-heterostructures

Abstract

Citation Formats

Figures / Tables:

Mechanical alloying and milling journal, January 2001

Solid state phase transformations in LiAlH4 during high-energy ball-milling journal, December 2000

Freestanding van der Waals Heterostructures of Graphene and Transition Metal Dichalcogenides journal, May 2015

Bandgap-tunable lateral and vertical heterostructures based on monolayer Mo1-x W x S2 alloys journal, August 2015

Van der Waals heterostructures journal, July 2013

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides journal, November 2012

Facile self-assembly of Fe3O4 nanoparticles@WS2 nanosheets: A promising candidate for supercapacitor electrode journal, October 2016

Facile Synthesis of WS 2 Nanosheets-Carbon Composites Anodes for Sodium and Lithium Ion Batteries journal, August 2016

Mechanically delaminated few layered MoS2 nanosheets based high performance wire type solid-state symmetric supercapacitors journal, July 2016

A critical review of high entropy alloys and related concepts journal, January 2017

Raman study of 2H-Mo1−xWxS2 layered mixed crystals journal, September 2010

Influence of Milling Media on Mechanically Exfoliated MoS 2 journal, January 2014

Low-temperature Synthesis of Heterostructures of Transition Metal Dichalcogenide Alloys (W x Mo 1– x S 2 ) and Graphene with Superior Catalytic Performance for Hydrogen Evolution journal, April 2017

Solution-Based Processing of Monodisperse Two-Dimensional Nanomaterials journal, February 2017

2D materials and van der Waals heterostructures journal, July 2016

Synthesis and characterization of molybdenum-tungsten mixed sulphoselenide, Mo0.5W0.5S x Se2?x (0 ? x ? 2) journal, January 1996

Quaternary 2D Transition Metal Dichalcogenides (TMDs) with Tunable Bandgap journal, July 2017

Distorted MoS2 nanostructures: An efficient catalyst for the electrochemical hydrogen evolution reaction journal, September 2013

Recent development of two-dimensional transition metal dichalcogenides and their applications journal, April 2017

Synthetic approaches to two-dimensional transition metal dichalcogenide nanosheets journal, August 2017

Temperature-Mediated Selective Growth of MoS 2 /WS 2 and WS 2 /MoS 2 Vertical Stacks on Au Foils for Direct Photocatalytic Applications journal, October 2016

In Situ TEM Characterization of Shear-Stress-Induced Interlayer Sliding in the Cross Section View of Molybdenum Disulfide journal, December 2014

Lateral Built-In Potential of Monolayer MoS 2 -WS 2 In-Plane Heterostructures by a Shortcut Growth Strategy journal, September 2015

Two Cation Disulfide Layers in the WxMo(1−x)S2 Lamellar Solid Solution journal, August 2001

Mo x W 1− x S 2 Solid Solutions as 3D Electrodes for Hydrogen Evolution Reaction journal, April 2015

Centimeter Scale Patterned Growth of Vertically Stacked Few Layer Only 2D MoS2/WS2 van der Waals Heterostructure journal, May 2016

Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides journal, October 2015

Monolayers of W x Mo 1−x S 2 alloy heterostructure with in-plane composition variations journal, February 2015

Establishment of 2D Crystal Heterostructures by Sulfurization of Sequential Transition Metal Depositions: Preparation, Characterization, and Selective Growth journal, October 2016

Mechanical Alloying and Milling journal, May 1995

2D materials and van der Waals heterostructures text, January 2016

Mechanical alloying and milling
journal, January 2001

Solid state phase transformations in LiAlH4 during high-energy ball-milling
journal, December 2000

Freestanding van der Waals Heterostructures of Graphene and Transition Metal Dichalcogenides
journal, May 2015

Bandgap-tunable lateral and vertical heterostructures based on monolayer Mo1-x W x S2 alloys
journal, August 2015

Van der Waals heterostructures
journal, July 2013

Electronics and optoelectronics of two-dimensional transition metal dichalcogenides
journal, November 2012

Facile self-assembly of Fe3O4 nanoparticles@WS2 nanosheets: A promising candidate for supercapacitor electrode
journal, October 2016

Facile Synthesis of WS ₂ Nanosheets-Carbon Composites Anodes for Sodium and Lithium Ion Batteries
journal, August 2016

Mechanically delaminated few layered MoS2 nanosheets based high performance wire type solid-state symmetric supercapacitors
journal, July 2016

A critical review of high entropy alloys and related concepts
journal, January 2017

Raman study of 2H-Mo1−xWxS2 layered mixed crystals
journal, September 2010

Influence of Milling Media on Mechanically Exfoliated MoS ₂
journal, January 2014

Low-temperature Synthesis of Heterostructures of Transition Metal Dichalcogenide Alloys (W _x Mo _{1– x} S ₂ ) and Graphene with Superior Catalytic Performance for Hydrogen Evolution
journal, April 2017

Solution-Based Processing of Monodisperse Two-Dimensional Nanomaterials
journal, February 2017

2D materials and van der Waals heterostructures
journal, July 2016

Synthesis and characterization of molybdenum-tungsten mixed sulphoselenide, Mo0.5W0.5S x Se2?x (0 ? x ? 2)
journal, January 1996

Quaternary 2D Transition Metal Dichalcogenides (TMDs) with Tunable Bandgap
journal, July 2017

Distorted MoS2 nanostructures: An efficient catalyst for the electrochemical hydrogen evolution reaction
journal, September 2013

Recent development of two-dimensional transition metal dichalcogenides and their applications
journal, April 2017

Synthetic approaches to two-dimensional transition metal dichalcogenide nanosheets
journal, August 2017

Temperature-Mediated Selective Growth of MoS ₂ /WS ₂ and WS ₂ /MoS ₂ Vertical Stacks on Au Foils for Direct Photocatalytic Applications
journal, October 2016

In Situ TEM Characterization of Shear-Stress-Induced Interlayer Sliding in the Cross Section View of Molybdenum Disulfide
journal, December 2014

Lateral Built-In Potential of Monolayer MoS ₂ -WS ₂ In-Plane Heterostructures by a Shortcut Growth Strategy
journal, September 2015

Two Cation Disulfide Layers in the WxMo(1−x)S2 Lamellar Solid Solution
journal, August 2001

Mo _x W _{1− x} S ₂ Solid Solutions as 3D Electrodes for Hydrogen Evolution Reaction
journal, April 2015

Centimeter Scale Patterned Growth of Vertically Stacked Few Layer Only 2D MoS2/WS2 van der Waals Heterostructure
journal, May 2016

Electrochemistry of Nanostructured Layered Transition-Metal Dichalcogenides
journal, October 2015

Monolayers of W _x Mo _1−x S ₂ alloy heterostructure with in-plane composition variations
journal, February 2015

Establishment of 2D Crystal Heterostructures by Sulfurization of Sequential Transition Metal Depositions: Preparation, Characterization, and Selective Growth
journal, October 2016

Mechanical Alloying and Milling
journal, May 1995

2D materials and van der Waals heterostructures
text, January 2016