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Title: SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis

Delamination of layered zeolite precursor B-SSZ-70 succeeds in an aqueous solution of Zn(NO 3 ) 2 and Bu 4 NF without need for sonication.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [1] ; ORCiD logo [2] ;  [3] ;  [3] ; ORCiD logo [1]
  1. Department of Chemical and Biomolecular Engineering, University of California at Berkeley, Berkeley, USA
  2. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, USA
  3. Chevron Energy Technology Company, Richmond, USA
Publication Date:
Grant/Contract Number:
FG02-05ER15696; AC02-05CH11231
Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 42; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1476958

Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, and Katz, Alexander. SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis. United Kingdom: N. p., Web. doi:10.1039/C8DT03044H.
Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, & Katz, Alexander. SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis. United Kingdom. doi:10.1039/C8DT03044H.
Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, and Katz, Alexander. 2018. "SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis". United Kingdom. doi:10.1039/C8DT03044H.
@article{osti_1476958,
title = {SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis},
author = {Okrut, Alexander and Aigner, Martina and Schöttle, Christian and Grosso-Giordano, Nicolás A. and Hwang, Son-Jong and Ouyang, Xiaoying and Zones, Stacey and Katz, Alexander},
abstractNote = {Delamination of layered zeolite precursor B-SSZ-70 succeeds in an aqueous solution of Zn(NO 3 ) 2 and Bu 4 NF without need for sonication.},
doi = {10.1039/C8DT03044H},
journal = {Dalton Transactions},
number = 42,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {10}
}

Works referenced in this record:

Delamination of Layered Zeolite Precursors under Mild Conditions: Synthesis of UCB-1 via Fluoride/Chloride Anion-Promoted Exfoliation
journal, March 2011
  • Ogino, Isao; Nigra, Michael M.; Hwang, Son-Jong
  • Journal of the American Chemical Society, Vol. 133, Issue 10, p. 3288-3291
  • DOI: 10.1021/ja111147z

Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor
journal, January 2008
  • Maheshwari, Sudeep; Jordan, Edgar; Kumar, Sandeep
  • Journal of the American Chemical Society, Vol. 130, Issue 4, p. 1507-1516
  • DOI: 10.1021/ja077711i