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Title: SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis

Abstract

Delamination of layered zeolite precursor B-SSZ-70 succeeds in an aqueous solution of Zn(NO 3 ) 2 and Bu 4 NF without need for sonication.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2];  [3];  [3]; ORCiD logo [1]
  1. Department of Chemical and Biomolecular Engineering, University of California at Berkeley, Berkeley, USA
  2. Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, USA
  3. Chevron Energy Technology Company, Richmond, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1476958
Grant/Contract Number:  
FG02-05ER15696; AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 47 Journal Issue: 42; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, and Katz, Alexander. SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis. United Kingdom: N. p., 2018. Web. doi:10.1039/C8DT03044H.
Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, & Katz, Alexander. SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis. United Kingdom. doi:10.1039/C8DT03044H.
Okrut, Alexander, Aigner, Martina, Schöttle, Christian, Grosso-Giordano, Nicolás A., Hwang, Son-Jong, Ouyang, Xiaoying, Zones, Stacey, and Katz, Alexander. Tue . "SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis". United Kingdom. doi:10.1039/C8DT03044H.
@article{osti_1476958,
title = {SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis},
author = {Okrut, Alexander and Aigner, Martina and Schöttle, Christian and Grosso-Giordano, Nicolás A. and Hwang, Son-Jong and Ouyang, Xiaoying and Zones, Stacey and Katz, Alexander},
abstractNote = {Delamination of layered zeolite precursor B-SSZ-70 succeeds in an aqueous solution of Zn(NO 3 ) 2 and Bu 4 NF without need for sonication.},
doi = {10.1039/C8DT03044H},
journal = {Dalton Transactions},
number = 42,
volume = 47,
place = {United Kingdom},
year = {2018},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8DT03044H

Citation Metrics:
Cited by: 2 works
Citation information provided by
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Works referenced in this record:

Delaminated zeolite precursors as selective acidic catalysts
journal, November 1998

  • Corma, A.; Fornes, V.; Pergher, S. B.
  • Nature, Vol. 396, Issue 6709, p. 353-356
  • DOI: 10.1038/24592

Influence of layer structure preservation on the catalytic properties of the pillared zeolite MCM-36
journal, June 2010

  • Maheshwari, Sudeep; Martínez, Cristina; Teresa Portilla, M.
  • Journal of Catalysis, Vol. 272, Issue 2
  • DOI: 10.1016/j.jcat.2010.04.011

Extra-Large-Pore Zeolites: Bridging the Gap between Micro and Mesoporous Structures
journal, April 2010

  • Jiang, Jiuxing; Yu, Jihong; Corma, Avelino
  • Angewandte Chemie International Edition, Vol. 49, Issue 18
  • DOI: 10.1002/anie.200904016

Well-Defined Silanols in the Structure of the Calcined High-Silica Zeolite SSZ-70: New Understanding of a Successful Catalytic Material
journal, November 2017

  • Smeets, Stef; Berkson, Zachariah J.; Xie, Dan
  • Journal of the American Chemical Society, Vol. 139, Issue 46
  • DOI: 10.1021/jacs.7b08810

Nonaqueous Fluoride/Chloride Anion-Promoted Delamination of Layered Zeolite Precursors: Synthesis and Characterization of UCB-2
journal, December 2011

  • Eilertsen, Einar A.; Ogino, Isao; Hwang, Son-Jong
  • Chemistry of Materials, Vol. 23, Issue 24
  • DOI: 10.1021/cm202364q

Delamination of Layered Zeolite Precursors under Mild Conditions: Synthesis of UCB-1 via Fluoride/Chloride Anion-Promoted Exfoliation
journal, March 2011

  • Ogino, Isao; Nigra, Michael M.; Hwang, Son-Jong
  • Journal of the American Chemical Society, Vol. 133, Issue 10, p. 3288-3291
  • DOI: 10.1021/ja111147z

Layer Structure Preservation during Swelling, Pillaring, and Exfoliation of a Zeolite Precursor
journal, January 2008

  • Maheshwari, Sudeep; Jordan, Edgar; Kumar, Sandeep
  • Journal of the American Chemical Society, Vol. 130, Issue 4, p. 1507-1516
  • DOI: 10.1021/ja077711i

Structure and Colloidal Stability of Nanosized Zeolite Beta Precursors
journal, January 2010

  • Hould, Nathan D.; Kumar, Sandeep; Tsapatsis, Michael
  • Langmuir, Vol. 26, Issue 2
  • DOI: 10.1021/la902445c

The Quest For Extra-Large Pore, Crystalline Molecular Sieves
journal, November 1997


Epoxidation of 1-octene under harsh tail-end conditions in a flow reactor II: impact of delaminated-zeolite catalyst surface area and structural integrity on catalytic performance
journal, January 2017

  • Aigner, Martina; Grosso-Giordano, Nicolás Andrés; Schöttle, Christian
  • Reaction Chemistry & Engineering, Vol. 2, Issue 6
  • DOI: 10.1039/C7RE00138J

Layered zeolitic materials: an approach to designing versatile functional solids
journal, January 2014

  • Díaz, Urbano; Corma, Avelino
  • Dalton Transactions, Vol. 43, Issue 27
  • DOI: 10.1039/c3dt53181c

Effect of Defect Site Preorganization on Fe(III) Grafting and Stability: A Comparative Study of Delaminated Zeolite vs Amorphous Silica Supports
journal, July 2017


Two-dimensional zeolites: dream or reality?
journal, January 2011

  • Roth, Wieslaw J.; Čejka, Jiří
  • Catalysis Science & Technology, Vol. 1, Issue 1
  • DOI: 10.1039/c0cy00027b

Cutting Materials in Half: A Graph Theory Approach for Generating Crystal Surfaces and Its Prediction of 2D Zeolites
journal, February 2018


From 3D to 2D zeolite catalytic materials
journal, January 2018

  • Přech, J.; Pizarro, P.; Serrano, D. P.
  • Chemical Society Reviews, Vol. 47, Issue 22
  • DOI: 10.1039/C8CS00370J

Two-Dimensional Zeolites: Current Status and Perspectives
journal, February 2014

  • Roth, Wieslaw J.; Nachtigall, Petr; Morris, Russell E.
  • Chemical Reviews, Vol. 114, Issue 9
  • DOI: 10.1021/cr400600f

Highly Active Layered Titanosilicate Catalyst with High Surface Density of Isolated Titanium on the Accessible Interlayer Surface
journal, May 2018

  • Tsunoji, Nao; Opanasenko, Maksym V.; Kubů, Martin
  • ChemCatChem, Vol. 10, Issue 12
  • DOI: 10.1002/cctc.201800413

Pioneering In Situ Recrystallization during Bead Milling: A Top-down Approach to Prepare Zeolite A Nanocrystals
journal, July 2016

  • Anand, Chokkalingam; Yamaguchi, Yudai; Liu, Zhendong
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep29210

Single-Step Delamination of a MWW Borosilicate Layered Zeolite Precursor under Mild Conditions without Surfactant and Sonication
journal, January 2014

  • Ouyang, Xiaoying; Hwang, Son-Jong; Runnebaum, Ron C.
  • Journal of the American Chemical Society, Vol. 136, Issue 4
  • DOI: 10.1021/ja410141u

One-pot synthesis of MWW zeolite nanosheets using a rationally designed organic structure-directing agent
journal, January 2015

  • Luo, Helen Y.; Michaelis, Vladimir K.; Hodges, Sydney
  • Chemical Science, Vol. 6, Issue 11
  • DOI: 10.1039/C5SC01912E

Role of Delamination in Zeolite-Catalyzed Aromatic Alkylation: UCB-3 versus 3-D Al-SSZ-70
journal, May 2014

  • Runnebaum, Ron C.; Ouyang, Xiaoying; Edsinga, Jeffrey A.
  • ACS Catalysis, Vol. 4, Issue 7
  • DOI: 10.1021/cs500285w

Heteroatom-Substituted Delaminated Zeolites as Solid Lewis Acid Catalysts
journal, March 2015

  • Ouyang, Xiaoying; Hwang, Son-Jong; Xie, Dan
  • ACS Catalysis, Vol. 5, Issue 5
  • DOI: 10.1021/cs5020546

Two-dimensional zeolites in catalysis: current status and perspectives
journal, January 2016

  • Opanasenko, Maksym V.; Roth, Wieslaw J.; Čejka, Jiří
  • Catalysis Science & Technology, Vol. 6, Issue 8
  • DOI: 10.1039/C5CY02079D

Novel surfactant-free route to delaminated all-silica and titanosilicate zeolites derived from a layered borosilicate MWW precursor
journal, January 2014

  • Ouyang, Xiaoying; Wanglee, Ying-Jen; Hwang, Son-Jong
  • Dalton Trans., Vol. 43, Issue 27
  • DOI: 10.1039/C4DT00383G

Heteroatom-Tolerant Delamination of Layered Zeolite Precursor Materials
journal, April 2013

  • Ogino, Isao; Eilertsen, Einar A.; Hwang, Son-Jong
  • Chemistry of Materials, Vol. 25, Issue 9
  • DOI: 10.1021/cm3032785

Outer-Sphere Control of Catalysis on Surfaces: A Comparative Study of Ti(IV) Single-Sites Grafted on Amorphous versus Crystalline Silicates for Alkene Epoxidation
journal, March 2018

  • Grosso-Giordano, Nicolás A.; Schroeder, Christian; Okrut, Alexander
  • Journal of the American Chemical Society, Vol. 140, Issue 15
  • DOI: 10.1021/jacs.7b11467

Epoxidation of 1-octene under harsh tail-end conditions in a flow reactor I: a comparative study of crystalline vs. amorphous catalysts
journal, January 2017

  • Aigner, Martina; Grosso-Giordano, Nicolás Andrés; Okrut, Alexander
  • Reaction Chemistry & Engineering, Vol. 2, Issue 6
  • DOI: 10.1039/C7RE00076F

Silicon-29 NMR study of the surface of silica gel by cross polarization and magic-angle spinning
journal, December 1980

  • Maciel, Gary E.; Sindorf, Dean W.
  • Journal of the American Chemical Society, Vol. 102, Issue 25
  • DOI: 10.1021/ja00545a056