Square-planar Co( iii ) in {O 4 } coordination: large ZFS and reactivity with ROS

Steele, Jennifer L.; Tahsini, Laleh; Sun, Chen; Elinburg, Jessica K.; Kotyk, Christopher M.; McNeely, James; Stoian, Sebastian A.; Dragulescu-Andrasi, Alina; Ozarowski, Andrew; Ozerov, M.; Krzystek, J.; Telser, Joshua; Bacon, Jeffrey W.; Golen, James A.; Rheingold, Arnold L.; Doerrer, Linda H.

doi:10.1039/C8CC04464C

Title: Square-planar Co( iii ) in {O ₄ } coordination: large ZFS and reactivity with ROS

Journal Article · 22 October 2018 · ChemComm

DOI: https://doi.org/10.1039/C8CC04464C · OSTI ID:1476670

^[1]; Tahsini, Laleh ^[1]; Sun, Chen ^[1]; Elinburg, Jessica K. ^[1];

^[1]; McNeely, James ^[1];

^[2]; Dragulescu-Andrasi, Alina ^[3]; Ozarowski, Andrew ^[4]; Ozerov, M. ^[4];

^[4];

^[5];

^[1]; Golen, James A. ^[6]; Rheingold, Arnold L. ^[6];

^[1]

Chemistry Department, Boston University, Boston, USA
Department of Chemistry, University of Idaho, Moscow, USA
Department of Chemistry and Biochemistry, Florida State University, Tallahassee, USA
National High Magnetic Field Laboratory, Florida State University, Tallahassee, USA
f Department of Biological, Chemical and Physical Sciences, Roosevelt University, Chicago, USA
Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, USA

Oxidation of distorted square-planar perfluoropinacolate Co compound [Co ^II (pin ^F ) ₂ ] ²⁻ , 1 , to [Co ^III (pin ^F ) ₂ ] ¹⁻ , 2 , is reported.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI ID:: 1476670

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 85 Vol. 54; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (26)

High-Spin Square-Planar CoII and FeII Complexes and Reasons for Their Electronic Structure Cantalupo, Stefanie A.; Fiedler, Stephanie R.; Shores, Matthew P. Angewandte Chemie International Edition, Vol. 51, Issue 4 https://doi.org/10.1002/anie.201106091	journal	December 2011
Molecular and Electronic Structure of Four- and Five-Coordinate Cobalt Complexes Containing Two o -Phenylenediamine- or Two o -Aminophenol-Type Ligands at Various Oxidation Levels: An Experimental, Density Functional, and Correlated ab initio Study Bill, Eckhard; Bothe, Eberhard; Chaudhuri, Phalguni Chemistry - A European Journal, Vol. 11, Issue 1 https://doi.org/10.1002/chem.200400850	journal	November 2004
Ultrawide Band Multifrequency High-Field EMR Technique: A Methodology for Increasing Spectroscopic Information Hassan, A. K.; Pardi, L. A.; Krzystek, J. Journal of Magnetic Resonance, Vol. 142, Issue 2 https://doi.org/10.1006/jmre.1999.1952	journal	February 2000
Targeting of High-Valent Iron-TAML Activators at Hydrocarbons and Beyond Collins, Terrence J.; Ryabov, Alexander D. Chemical Reviews, Vol. 117, Issue 13 https://doi.org/10.1021/acs.chemrev.7b00034	journal	March 2017
Ligand-Promoted Palladium-Catalyzed Aerobic Oxidation Reactions Wang, Dian; Weinstein, Adam B.; White, Paul B. Chemical Reviews, Vol. 118, Issue 5 https://doi.org/10.1021/acs.chemrev.7b00334	journal	October 2017
Square-Planar Cobalt(III) Pincer Complex Lagaditis, Paraskevi O.; Schluschaß, Bastian; Demeshko, Serhiy Inorganic Chemistry, Vol. 55, Issue 9 https://doi.org/10.1021/acs.inorgchem.6b00369	journal	April 2016
Green, Catalytic Oxidations of Alcohols Sheldon, Roger A.; Arends, Isabel W. C. E.; ten Brink, Gerd-Jan Accounts of Chemical Research, Vol. 35, Issue 9 https://doi.org/10.1021/ar010075n	journal	September 2002
Designing Catalysts for Functionalization of Unactivated C–H Bonds Based on the CH Activation Reaction Hashiguchi, Brian G.; Bischof, Steven M.; Konnick, Michael M. Accounts of Chemical Research, Vol. 45, Issue 6 https://doi.org/10.1021/ar200250r	journal	January 2012
Controlling Site Selectivity in Palladium-Catalyzed C–H Bond Functionalization Neufeldt, Sharon R.; Sanford, Melanie S. Accounts of Chemical Research, Vol. 45, Issue 6 https://doi.org/10.1021/ar300014f	journal	January 2012
Making Oxygen with Ruthenium Complexes Concepcion, Javier J.; Jurss, Jonah W.; Brennaman, M. Kyle Accounts of Chemical Research, Vol. 42, Issue 12 https://doi.org/10.1021/ar9001526	journal	December 2009
Cobalt-Oxide-Based Materials as Water Oxidation Catalyst: Recent Progress and Challenges Deng, Xiaohui; Tüysüz, Harun ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs500713d	journal	September 2014
Diamagnetic Corrections and Pascal's Constants Bain, Gordon A.; Berry, John F. Journal of Chemical Education, Vol. 85, Issue 4 https://doi.org/10.1021/ed085p532	journal	April 2008
Synthesis, Structures, and Properties of a Series of Four-, Five-, and Six-Coordinate Cobalt(III) Triazacorrole Complexes: The First Examples of Transition Metal Corrolazines Ramdhanie, Bobby; Zakharov, Lev N.; Rheingold, Arnold L. Inorganic Chemistry, Vol. 41, Issue 16 https://doi.org/10.1021/ic020297x	journal	August 2002
Electronic Ground State and the d−d Transitions in Bis(biuretato)cobaltate(III) Ions Harnung, Sven E.; Larsen, Erik Inorganic Chemistry, Vol. 46, Issue 13 https://doi.org/10.1021/ic061519k	journal	June 2007
Structural and Electronic Properties of Old and New A ₂ [M(pin ^F ) ₂ ] Complexes Tahsini, Laleh; Specht, Sarah E.; Lum, June S. Inorganic Chemistry, Vol. 52, Issue 24 https://doi.org/10.1021/ic401837y	journal	November 2013
Spin-triplet cobalt complexes of biuret and related ligands Birker, P. J. M. W. L.; Bour, J. J.; Steggerda, J. J. Inorganic Chemistry, Vol. 12, Issue 6 https://doi.org/10.1021/ic50124a008	journal	June 1973
Homoleptic Organocobalt(III) Compounds with Intermediate Spin García-Monforte, M. Angeles; Ara, Irene; Martín, Antonio Inorganic Chemistry, Vol. 53, Issue 23 https://doi.org/10.1021/ic501719y	journal	October 2014
Square Planar Bis{3,6-bis(trimethylsilyl)benzene-1,2-dithiolato}metal Complexes of Cr ^II , Co ^III , and Rh ^II : An Experimental and Density Functional Theoretical Study Benedito, Flávio Luiz; Petrenko, Taras; Bill, Eckhard Inorganic Chemistry, Vol. 48, Issue 23 https://doi.org/10.1021/ic9008976	journal	December 2009
Tuning of Electronic Properties and Reactivity in Four-Coordinate Cobalt(III) Complexes by the Tetraazamacrocyclic Tropocoronand Ligand Doerrer, Linda H.; Bautista, Maria T.; Lippard, Stephen J. Inorganic Chemistry, Vol. 36, Issue 17 https://doi.org/10.1021/ic9703235	journal	August 1997
The Toluenedithiolate and Maleonitriledithiolate Square-Matrix Systems Williams, Raymond; Billig, E.; Waters, James H. Journal of the American Chemical Society, Vol. 88, Issue 1 https://doi.org/10.1021/ja00953a009	journal	January 1966
The Electronic Structure of the Isoelectronic, Square-Planar Complexes [Fe ^II (L) ₂ ] ² ^- and [Co ^III (L ^Bu ) ₂ ] ^- (L ² ^- and (L ^Bu ) ² ^- = Benzene-1,2-dithiolates): An Experimental and Density Functional Theoretical Study Ray, Kallol; Begum, Ameerunisha; Weyhermüller, Thomas Journal of the American Chemical Society, Vol. 127, Issue 12 https://doi.org/10.1021/ja042803i	journal	March 2005
Polyoxometalate water oxidation catalysts and the production of green fuel Lv, Hongjin; Geletii, Yurii V.; Zhao, Chongchao Chemical Society Reviews, Vol. 41, Issue 22, p. 7572-7589 https://doi.org/10.1039/c2cs35292c	journal	January 2012
Catalysts made of earth-abundant elements (Co, Ni, Fe) for water splitting: Recent progress and future challenges Du, Pingwu; Eisenberg, Richard Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee03250c	journal	January 2012
Reversible formation of a high-spin cobalt(II) complex of the neutral dioxygen ligand Willis, Christopher J. Journal of the Chemical Society, Chemical Communications, Issue 4 https://doi.org/10.1039/c39740000117	journal	January 1974
400. The determination of the paramagnetic susceptibility of substances in solution by nuclear magnetic resonance Evans, D. F. Journal of the Chemical Society (Resumed) https://doi.org/10.1039/jr9590002003	journal	January 1959
Cyclotron resonance of single-valley Dirac fermions in nearly gapless HgTe quantum wells Ludwig, J.; Vasilyev, Yu. B.; Mikhailov, N. N. Physical Review B, Vol. 89, Issue 24 https://doi.org/10.1103/PhysRevB.89.241406	journal	June 2014

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Title: Square-planar Co( iii ) in {O 4 } coordination: large ZFS and reactivity with ROS

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Title: Square-planar Co( iii ) in {O ₄ } coordination: large ZFS and reactivity with ROS