Title: Entangled chain polymer liquids under continuous shear deformation: consequences of a microscopically anharmonic confining tube

Abstract

Here, we generalize our non-classical theory for the shear rheology of entangled flexible polymer liquids to address the consequences of a deformation-modified anharmonic tube confinement field. Numerical results for stress–strain curves, orientational relaxation time, primitive path (PP) step orientational order parameter, dynamic tube diameter and transverse entropic barrier under nonequilibrium conditions are presented as a function of dimensionless shear rate, strain and degree of entanglement. Deformation-induced changes of the tube field have essentially no effect on rheology under fast deformations conditions corresponding to Rouse Weissenberg numbers Wi_R > 1 because of the dominance of PP chain stretch. However, the scaling behavior of the effective orientational relaxation time and rheological response at low deformation rates Wi_R < 1 are significantly modified, with the stress overshoot coordinates predicted to become shear rate and degree of entanglement dependent. Stress-assisted transverse activated barrier hopping as a new channel of orientational relaxation is found to be potentially important when Wi_R < 1. The dynamic tube diameter and transverse entropic barrier that confines chains in a tube are rich functions of strain, shear rate and degree of entanglement. Deformation can increase or decrease the tube diameter, and non-monotonic changes with strain are possible due to competingmore » consequences of PP orientation, chain stretch and stress. The transverse barrier is relatively high for all strains below the stress overshoot, for weaker entanglement, and for Wi_R > 1, corresponding to a dynamically stable tube. But for high enough degrees of entanglement and Wi_R < 1, although the barrier still exists it can become very low.« less

Authors:

Xie, Shi-Jie  ^[1];

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Schweizer, Kenneth S. ^[2]

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+ Show Author Affiliations

1. Univ. of Illinois, Urbana, IL (United States). Dept. of Materials Science
2. Univ. of Illinois, Urbana, IL (United States). Frederick Seitz Materials Research Lab., Dept. of Materials Science, Dept. of Chemistry and Dept. of Chemical and Biomolecular Engineering

Publication Date:

2018-08-08

Research Org.:

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:

USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

OSTI Identifier:

1476390

Alternate Identifier(s):

OSTI ID: 1464837

Grant/Contract Number:  

AC05-00OR22725

Resource Type:

Accepted Manuscript

Journal Name:

Soft Matter

Additional Journal Information:

Journal Volume: 14; Journal Issue: 34; Journal ID: ISSN 1744-683X

Publisher:

Royal Society of Chemistry

Country of Publication:

United States

Language:

English

Subject:

36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY