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Title: Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs

Abstract

A series of pentapyridyl-supported Ru(ii) complexes are synthesized and characterized using X-ray crystallography, UV-Vis, 1H NMR and cyclic voltammetry. Moreover, these monometallic species are compared with previously reported bimetallic analogues with regards to their structure and ligand substitution behavior.

Authors:
ORCiD logo [1]; ORCiD logo [1]
  1. Univ. of Wisconsin, Madison, WI (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Univ. of Wisconsin-Madison, Stoughton, WI (United States). Synchrotron Radiation Center (SRC)
Sponsoring Org.:
USDOE; National Science Foundation (NSF); National Institutes of Health (NIH)
OSTI Identifier:
1476319
Grant/Contract Number:  
SC0016442
Resource Type:
Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Volume: 46; Journal Issue: 28; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Park, Sungho V., and Berry, John F. Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs. United States: N. p., 2017. Web. doi:10.1039/C7DT01847A.
Park, Sungho V., & Berry, John F. Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs. United States. doi:10.1039/C7DT01847A.
Park, Sungho V., and Berry, John F. Mon . "Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs". United States. doi:10.1039/C7DT01847A. https://www.osti.gov/servlets/purl/1476319.
@article{osti_1476319,
title = {Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs},
author = {Park, Sungho V. and Berry, John F.},
abstractNote = {A series of pentapyridyl-supported Ru(ii) complexes are synthesized and characterized using X-ray crystallography, UV-Vis,1H NMR and cyclic voltammetry. Moreover, these monometallic species are compared with previously reported bimetallic analogues with regards to their structure and ligand substitution behavior.},
doi = {10.1039/C7DT01847A},
journal = {Dalton Transactions},
number = 28,
volume = 46,
place = {United States},
year = {2017},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 1 work
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Figures / Tables:

Scheme 1 Scheme 1: Representative depictions of a bimetallic Ru–Ru complex (left) and a monometallic Ru complex (right) bearing N-donor ligands and a terminal oxo, nitrido or nitrene moiety.

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