Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs
Abstract
A series of pentapyridyl-supported Ru(ii) complexes are synthesized and characterized using X-ray crystallography, UV-Vis,1H NMR and cyclic voltammetry. Moreover, these monometallic species are compared with previously reported bimetallic analogues with regards to their structure and ligand substitution behavior.
- Publication Date:
- Research Org.:
- Univ. of Wisconsin-Madison, Stoughton, WI (United States). Synchrotron Radiation Center (SRC)
- Sponsoring Org.:
- USDOE; National Science Foundation (NSF); National Institutes of Health (NIH)
- OSTI Identifier:
- 1476319
- Grant/Contract Number:
- SC0016442
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Volume: 46; Journal Issue: 28; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Park, Sungho V., and Berry, John F. Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs. United States: N. p., 2017.
Web. doi:10.1039/C7DT01847A.
Park, Sungho V., & Berry, John F. Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs. United States. doi:https://doi.org/10.1039/C7DT01847A
Park, Sungho V., and Berry, John F. Mon .
"Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs". United States. doi:https://doi.org/10.1039/C7DT01847A. https://www.osti.gov/servlets/purl/1476319.
@article{osti_1476319,
title = {Synthesis, characterization and solution behavior of a systematic series of pentapyridyl-supported Ru II complexes: comparison to bimetallic analogs},
author = {Park, Sungho V. and Berry, John F.},
abstractNote = {A series of pentapyridyl-supported Ru(ii) complexes are synthesized and characterized using X-ray crystallography, UV-Vis,1H NMR and cyclic voltammetry. Moreover, these monometallic species are compared with previously reported bimetallic analogues with regards to their structure and ligand substitution behavior.},
doi = {10.1039/C7DT01847A},
journal = {Dalton Transactions},
number = 28,
volume = 46,
place = {United States},
year = {2017},
month = {6}
}
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Figures / Tables:
Scheme 1: Representative depictions of a bimetallic Ru–Ru complex (left) and a monometallic Ru complex (right) bearing N-donor ligands and a terminal oxo, nitrido or nitrene moiety.
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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.