Atomic layer deposition and first principles modeling of glassy Li 3 BO 3 –Li 2 CO 3 electrolytes for solid-state Li metal batteries

Kazyak, Eric; Chen, Kuan-Hung; Davis, Andrew L.; Yu, Seungho; Sanchez, Adrian J.; Lasso, Jose; Bielinski, Ashley R.; Thompson, Travis; Sakamoto, Jeff; Siegel, Donald J.; Dasgupta, Neil P.

doi:10.1039/C8TA08761J

Title: Atomic layer deposition and first principles modeling of glassy Li ₃ BO ₃ –Li ₂ CO ₃ electrolytes for solid-state Li metal batteries

Journal Article · 16 October 2018 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/C8TA08761J · OSTI ID:1475466

^[1];

^[2]; Davis, Andrew L. ^[1];

^[1]; Sanchez, Adrian J. ^[1]; Lasso, Jose ^[1]; Bielinski, Ashley R. ^[1]; Thompson, Travis ^[1];

^[3];

^[1]

Department of Mechanical Engineering, University of Michigan, Ann Arbor, USA
Department of Materials Science and Engineering, University of Michigan, Ann Arbor, USA
Department of Mechanical Engineering, University of Michigan, Ann Arbor, USA, Department of Materials Science and Engineering

Glassy Li ₃ BO ₃ –Li ₂ CO ₃ ALD films are deposited and shown to have excellent stability against Li metal and high ionic conductivity.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AR0000653

OSTI ID:: 1475466

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 40 Vol. 6; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (75)

Atomic Layer Deposition for Lithium-Based Batteries Ma, Lu; Nuwayhid, Ramsay B.; Wu, Tianpin Advanced Materials Interfaces, Vol. 3, Issue 21 https://doi.org/10.1002/admi.201600564	journal	September 2016
All-Solid-State Lithium-Ion Microbatteries: A Review of Various Three-Dimensional Concepts Oudenhoven, Jos F. M.; Baggetto, Loïc.; Notten, Peter H. L. Advanced Energy Materials, Vol. 1, Issue 1 https://doi.org/10.1002/aenm.201000002	journal	November 2010
Unexpected Improved Performance of ALD Coated LiCoO ₂ /Graphite Li-Ion Batteries Jung, Yoon Seok; Lu, Peng; Cavanagh, Andrew S. Advanced Energy Materials, Vol. 3, Issue 2 https://doi.org/10.1002/aenm.201200370	journal	September 2012
Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes Porz, Lukas; Swamy, Tushar; Sheldon, Brian W. Advanced Energy Materials, Vol. 7, Issue 20 https://doi.org/10.1002/aenm.201701003	journal	July 2017
Atomic Layer Deposition of Li _x Al _y S Solid-State Electrolytes for Stabilizing Lithium-Metal Anodes Cao, Yanqiang; Meng, Xiangbo; Elam, Jeffrey W. ChemElectroChem, Vol. 3, Issue 6 https://doi.org/10.1002/celc.201600139	journal	April 2016
Electrical properties of lithiated boron oxide fast-ion conducting glasses Horopanitis, E. E.; Perentzis, G.; Pavlidou, E. Ionics, Vol. 9, Issue 1-2 https://doi.org/10.1007/BF02376543	journal	January 2003
New Li solid electrolytes Shannon, R. D.; Taylor, B. E.; English, A. D. Electrochimica Acta, Vol. 22, Issue 7 https://doi.org/10.1016/0013-4686(77)80035-2	journal	July 1977
XPS investigation of lithium borate glass and the Li/LiBO2 interface Hensley, D. A.; Garofalini, S. H. Applied Surface Science, Vol. 81, Issue 3 https://doi.org/10.1016/0169-4332(94)90290-9	journal	November 1994
A high-throughput infrastructure for density functional theory calculations Jain, Anubhav; Hautier, Geoffroy; Moore, Charles J. Computational Materials Science, Vol. 50, Issue 8 https://doi.org/10.1016/j.commatsci.2011.02.023	journal	June 2011
Python Materials Genomics (pymatgen): A robust, open-source python library for materials analysis Ong, Shyue Ping; Richards, William Davidson; Jain, Anubhav Computational Materials Science, Vol. 68 https://doi.org/10.1016/j.commatsci.2012.10.028	journal	February 2013
Atomic Layer Deposited ZnO: B As Transparent Conductive Oxide for Increased Short Circuit Current Density in Silicon Heterojunction Solar Cells Gatz, Henriette A.; Koushik, Dibyashree; Rath, Jatin K. Energy Procedia, Vol. 92 https://doi.org/10.1016/j.egypro.2016.07.028	journal	August 2016
LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries Ohta, Narumi; Takada, Kazunori; Sakaguchi, Isao Electrochemistry Communications, Vol. 9, Issue 7 https://doi.org/10.1016/j.elecom.2007.02.008	journal	July 2007
Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte Cheng, Eric Jianfeng; Sharafi, Asma; Sakamoto, Jeff Electrochimica Acta, Vol. 223 https://doi.org/10.1016/j.electacta.2016.12.018	journal	January 2017
Influence of Li2O-B2O3 glass on ionic migration and interfacial properties of La2/3−xLi3xTiO3 solid electrolyte Zhang, Hui; Hao, Shimeng; Lin, Junpin Journal of Alloys and Compounds, Vol. 704 https://doi.org/10.1016/j.jallcom.2017.02.059	journal	May 2017
Correlation between structural and electrical properties of heavily lithiated boron oxide solid electrolytes Horopanitis, E. E.; Perentzis, G.; Beck, A. Journal of Non-Crystalline Solids, Vol. 354, Issue 2-9 https://doi.org/10.1016/j.jnoncrysol.2007.07.046	journal	January 2008
Chemical stability enhancement of lithium conducting solid electrolyte plates using sputtered LiPON thin films West, W. C.; Whitacre, J. F.; Lim, J. R. Journal of Power Sources, Vol. 126, Issue 1-2, p. 134-138 https://doi.org/10.1016/j.jpowsour.2003.08.030	journal	February 2004
Ultra-thin LiPON films – Fundamental properties and application in solid state thin film model batteries Nowak, Susann; Berkemeier, Frank; Schmitz, Guido Journal of Power Sources, Vol. 275 https://doi.org/10.1016/j.jpowsour.2014.10.202	journal	February 2015
All-solid-state lithium-ion and lithium metal batteries – paving the way to large-scale production Schnell, Joscha; Günther, Till; Knoche, Thomas Journal of Power Sources, Vol. 382 https://doi.org/10.1016/j.jpowsour.2018.02.062	journal	April 2018
Solid-state thin-film rechargeable batteries Dudney, N.J. Materials Science and Engineering: B, Vol. 116, Issue 3, p. 245-249 https://doi.org/10.1016/j.mseb.2004.05.045	journal	February 2005
All-solid-state lithium-ion battery using Li2.2C0.8B0.2O3 electrolyte Okumura, Toyoki; Takeuchi, Tomonari; Kobayashi, Hironori Solid State Ionics, Vol. 288 https://doi.org/10.1016/j.ssi.2016.01.045	journal	May 2016
Atomic layer deposition of B2O3 thin films at room temperature Putkonen, Matti; Niinistö, Lauri Thin Solid Films, Vol. 514, Issue 1-2 https://doi.org/10.1016/j.tsf.2006.03.001	journal	August 2006
Atomic Layer Deposition of the Solid Electrolyte LiPON Kozen, Alexander C.; Pearse, Alexander J.; Lin, Chuan-Fu Chemistry of Materials, Vol. 27, Issue 15 https://doi.org/10.1021/acs.chemmater.5b01654	journal	July 2015
Atomic Layer Deposition of Lithium Phosphorus Oxynitride Nisula, Mikko; Shindo, Yohei; Koga, Hideyuki Chemistry of Materials, Vol. 27, Issue 20 https://doi.org/10.1021/acs.chemmater.5b02199	journal	October 2015
Bulk-Type All Solid-State Batteries with 5 V Class LiNi _0.5 Mn _1.5 O ₄ Cathode and Li ₁₀ GeP ₂ S ₁₂ Solid Electrolyte Oh, Gwangseok; Hirayama, Masaaki; Kwon, Ohmin Chemistry of Materials, Vol. 28, Issue 8 https://doi.org/10.1021/acs.chemmater.5b04940	journal	April 2016
Recent Advances in Atomic Layer Deposition Dasgupta, Neil P.; Lee, Han-Bo-Ram; Bent, Stacey F. Chemistry of Materials, Vol. 28, Issue 7 https://doi.org/10.1021/acs.chemmater.6b00673	journal	March 2016
Electrochemical Nature of the Cathode Interface for a Solid-State Lithium-Ion Battery: Interface between LiCoO ₂ and Garnet-Li ₇ La ₃ Zr ₂ O ₁₂ Park, Kyusung; Yu, Byeong-Chul; Jung, Ji-Won Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03870	journal	October 2016
Nanoscale Solid State Batteries Enabled by Thermal Atomic Layer Deposition of a Lithium Polyphosphazene Solid State Electrolyte Pearse, Alexander J.; Schmitt, Thomas E.; Fuller, Elliot J. Chemistry of Materials, Vol. 29, Issue 8 https://doi.org/10.1021/acs.chemmater.7b00805	journal	April 2017
Atomic Layer Deposition of the Solid Electrolyte Garnet Li ₇ La ₃ Zr ₂ O ₁₂ Kazyak, Eric; Chen, Kuan-Hung; Wood, Kevin N. Chemistry of Materials, Vol. 29, Issue 8 https://doi.org/10.1021/acs.chemmater.7b00944	journal	April 2017
Stabilization of Lithium Metal Anodes by Hybrid Artificial Solid Electrolyte Interphase Kozen, Alexander C.; Lin, Chuan-Fu; Zhao, Oliver Chemistry of Materials, Vol. 29, Issue 15 https://doi.org/10.1021/acs.chemmater.7b01496	journal	July 2017
Grain Boundary Contributions to Li-Ion Transport in the Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO) Yu, Seungho; Siegel, Donald J. Chemistry of Materials, Vol. 29, Issue 22 https://doi.org/10.1021/acs.chemmater.7b02805	journal	November 2017
Surface Chemistry Mechanism of Ultra-Low Interfacial Resistance in the Solid-State Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ Sharafi, Asma; Kazyak, Eric; Davis, Andrew L. Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b03002	journal	September 2017
Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations Zhu, Yizhou; He, Xingfeng; Mo, Yifei ACS Applied Materials & Interfaces, Vol. 7, Issue 42 https://doi.org/10.1021/acsami.5b07517	journal	October 2015
Li ₇ La ₃ Zr ₂ O ₁₂ Interface Modification for Li Dendrite Prevention Tsai, Chih-Long; Roddatis, Vladimir; Chandran, C. Vinod ACS Applied Materials & Interfaces, Vol. 8, Issue 16 https://doi.org/10.1021/acsami.6b00831	journal	April 2016
Atomic Layer Deposited Lithium Silicates as Solid-State Electrolytes for All-Solid-State Batteries Wang, Biqiong; Liu, Jian; Norouzi Banis, Mohammad ACS Applied Materials & Interfaces, Vol. 9, Issue 37 https://doi.org/10.1021/acsami.7b07113	journal	March 2017
Atomic Layer Deposition of Lithium Niobium Oxides as Potential Solid-State Electrolytes for Lithium-Ion Batteries Wang, Biqiong; Zhao, Yang; Banis, Mohammad Norouzi ACS Applied Materials & Interfaces, Vol. 10, Issue 2 https://doi.org/10.1021/acsami.7b13467	journal	January 2018
Electrochemical Window of the Li-Ion Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ Thompson, Travis; Yu, Seungho; Williams, Logan ACS Energy Letters, Vol. 2, Issue 2 https://doi.org/10.1021/acsenergylett.6b00593	journal	January 2017
Lithium Metal Anodes: Toward an Improved Understanding of Coupled Morphological, Electrochemical, and Mechanical Behavior Wood, Kevin N.; Noked, Malachi; Dasgupta, Neil P. ACS Energy Letters, Vol. 2, Issue 3 https://doi.org/10.1021/acsenergylett.6b00650	journal	February 2017
Solid Electrolyte Lithium Phosphous Oxynitride as a Protective Nanocladding Layer for 3D High-Capacity Conversion Electrodes Lin, Chuan-Fu; Noked, Malachi; Kozen, Alexander C. ACS Nano, Vol. 10, Issue 2 https://doi.org/10.1021/acsnano.5b07757	journal	January 2016
Atomic Layer Deposition of Stable LiAlF ₄ Lithium Ion Conductive Interfacial Layer for Stable Cathode Cycling Xie, Jin; Sendek, Austin D.; Cubuk, Ekin D. ACS Nano, Vol. 11, Issue 7 https://doi.org/10.1021/acsnano.7b02561	journal	July 2017
Three-Dimensional Solid-State Lithium-Ion Batteries Fabricated by Conformal Vapor-Phase Chemistry Pearse, Alexander; Schmitt, Thomas; Sahadeo, Emily ACS Nano, Vol. 12, Issue 5 https://doi.org/10.1021/acsnano.7b08751	journal	April 2018
Atomic Layer Deposition of Li ₂ O–Al ₂ O ₃ Thin Films Aaltonen, Titta; Nilsen, Ola; Magrasó, Anna Chemistry of Materials, Vol. 23, Issue 21 https://doi.org/10.1021/cm200899k	journal	November 2011
Ultrathin Lithium-Ion Conducting Coatings for Increased Interfacial Stability in High Voltage Lithium-Ion Batteries Park, Joong Sun; Meng, Xiangbo; Elam, Jeffrey W. Chemistry of Materials, Vol. 26, Issue 10 https://doi.org/10.1021/cm500512n	journal	May 2014
Li−Fe−P−O ₂ Phase Diagram from First Principles Calculations Ong, Shyue Ping; Wang, Lei; Kang, Byoungwoo Chemistry of Materials, Vol. 20, Issue 5 https://doi.org/10.1021/cm702327g	journal	February 2008
Atomic Layer Deposition: An Overview George, Steven M. Chemical Reviews, Vol. 110, Issue 1, p. 111-131 https://doi.org/10.1021/cr900056b	journal	January 2010
Atomic-Scale Influence of Grain Boundaries on Li-Ion Conduction in Solid Electrolytes for All-Solid-State Batteries Dawson, James A.; Canepa, Pieremanuele; Famprikis, Theodosios Journal of the American Chemical Society, Vol. 140, Issue 1 https://doi.org/10.1021/jacs.7b10593	journal	December 2017
Mechanistic Study of Lithium Aluminum Oxide Atomic Layer Deposition Comstock, David J.; Elam, Jeffrey W. The Journal of Physical Chemistry C, Vol. 117, Issue 4 https://doi.org/10.1021/jp308828p	journal	January 2013
Atomic Layer Deposition of Lithium Tantalate Solid-State Electrolytes Liu, Jian; Banis, Mohammad N.; Li, Xifei The Journal of Physical Chemistry C, Vol. 117, Issue 39 https://doi.org/10.1021/jp4063302	journal	September 2013
Atomic Layer Deposition and in Situ Characterization of Ultraclean Lithium Oxide and Lithium Hydroxide Kozen, Alexander C.; Pearse, Alexander J.; Lin, Chuan-Fu The Journal of Physical Chemistry C, Vol. 118, Issue 48 https://doi.org/10.1021/jp509298r	journal	November 2014
Ultrathin Coatings on Nano-LiCoO₂ for Li-Ion Vehicular Applications Scott, Isaac D.; Jung, Yoon Seok; Cavanagh, Andrew S. Nano Letters, Vol. 11, Issue 2, p. 414-418 https://doi.org/10.1021/nl1030198	journal	February 2011
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Lithium battery chemistries enabled by solid-state electrolytes Manthiram, Arumugam; Yu, Xingwen; Wang, Shaofei Nature Reviews Materials, Vol. 2, Issue 4 https://doi.org/10.1038/natrevmats.2016.103	journal	February 2017
Negating interfacial impedance in garnet-based solid-state Li metal batteries Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin) Nature Materials, Vol. 16, Issue 5 https://doi.org/10.1038/nmat4821	journal	December 2016
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
Synthesis of ion conducting Li _x Al _y Si _z O thin films by atomic layer deposition Perng, Ya-Chuan; Cho, Jea; Sun, Steven Y. J. Mater. Chem. A, Vol. 2, Issue 25 https://doi.org/10.1039/C3TA14928E	journal	January 2014
Atomic layer deposition of B-doped ZnO using triisopropyl borate as the boron precursor and comparison with Al-doped ZnO Garcia-Alonso, Diana; Potts, Stephen E.; van Helvoirt, Cristian A. A. Journal of Materials Chemistry C, Vol. 3, Issue 13 https://doi.org/10.1039/C4TC02707H	journal	January 2015
Electrical characterization of amorphous LiAlO ₂ thin films deposited by atomic layer deposition Hu, Yang; Ruud, Amund; Miikkulainen, Ville RSC Advances, Vol. 6, Issue 65 https://doi.org/10.1039/C6RA03137D	journal	January 2016
Impact of air exposure and surface chemistry on Li–Li ₇ La ₃ Zr ₂ O ₁₂ interfacial resistance Sharafi, Asma; Yu, Seungho; Naguib, Michael Journal of Materials Chemistry A, Vol. 5, Issue 26 https://doi.org/10.1039/C7TA03162A	journal	January 2017
New horizons for inorganic solid state ion conductors Zhang, Zhizhen; Shao, Yuanjun; Lotsch, Bettina Energy & Environmental Science, Vol. 11, Issue 8 https://doi.org/10.1039/C8EE01053F	journal	January 2018
Solid electrolyte coated high voltage layered–layered lithium-rich composite cathode: Li1.2Mn0.525Ni0.175Co0.1O2 Martha, Surendra K.; Nanda, Jagjit; Kim, Yoongu Journal of Materials Chemistry A, Vol. 1, Issue 18 https://doi.org/10.1039/c3ta10586e	journal	January 2013
Atomic layer deposition of B2O3/SiO2 thin films and their application in an efficient diffusion doping process Kim, Woo-Hee; Oh, Il-Kwon; Kim, Min-Kyu Journal of Materials Chemistry C, Vol. 2, Issue 29 https://doi.org/10.1039/c4tc00648h	journal	January 2014
Commentary: The Materials Project: A materials genome approach to accelerating materials innovation Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy APL Materials, Vol. 1, Issue 1 https://doi.org/10.1063/1.4812323	journal	July 2013
Atomic layer deposition of lithium phosphates as solid-state electrolytes for all-solid-state microbatteries Wang, Biqiong; Liu, Jian; Sun, Qian Nanotechnology, Vol. 25, Issue 50 https://doi.org/10.1088/0957-4484/25/50/504007	journal	November 2014
Elegant design of electrode and electrode/electrolyte interface in lithium-ion batteries by atomic layer deposition Liu, Jian; Sun, Xueliang Nanotechnology, Vol. 26, Issue 2 https://doi.org/10.1088/0957-4484/26/2/024001	journal	December 2014
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Molecular dynamics investigation of lithium borate glasses: Local structure and ion dynamics Varsamis, Cristos-Platon E.; Vegiri, Alice; Kamitsos, Efstratios I. Physical Review B, Vol. 65, Issue 10 https://doi.org/10.1103/PhysRevB.65.104203	journal	February 2002
Thickness-dependent dc conductivity of lithium borate glasses Berkemeier, Frank; Abouzari, Mohammad Reza Shoar; Schmitz, Guido Physical Review B, Vol. 76, Issue 2 https://doi.org/10.1103/PhysRevB.76.024205	journal	July 2007
Atmospheric pressure spatial atomic layer deposition web coating with in situ monitoring of film thickness Yersak, Alexander S.; Lee, Yung C.; Spencer, Joseph A. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 32, Issue 1 https://doi.org/10.1116/1.4850176	journal	January 2014
P-type Doping of Silicon Suitable for Structures with High Aspect Ratios by Using a Dopant Source of Boron Oxide Grown by Atomic Layer Deposition Kalkofen, B.; Mothukuru, V. M.; Lisker, M. ECS Transactions, Vol. 45, Issue 6 https://doi.org/10.1149/1.3700939	journal	April 2012
Thermal Atomic Layer Deposition of Lithium Phosphorus Oxynitride as a Thin-Film Solid Electrolyte Shibata, Satoshi Journal of The Electrochemical Society, Vol. 163, Issue 13 https://doi.org/10.1149/2.0371613jes	journal	January 2016
Properties of lithium phosphorus oxynitride (Lipon) for 3D solid-state lithium batteries Xu, Fan; Dudney, Nancy J.; Veith, Gabriel M. Journal of Materials Research, Vol. 25, Issue 8 https://doi.org/10.1557/JMR.2010.0193	journal	August 2010
ALD for clean energy conversion, utilization, and storage Elam, Jeffrey W.; Dasgupta, Neil P.; Prinz, Fritz B. MRS Bulletin, Vol. 36, Issue 11, p. 899-906 https://doi.org/10.1557/mrs.2011.265	journal	November 2011
Mechanochemical synthesis and crystallization of Li₃BO₃–Li₂CO₃ glass electrolytes Nagao, Kenji; Hayashi, Akitoshi; Tatsumisago, Masahiro Journal of the Ceramic Society of Japan, Vol. 124, Issue 9 https://doi.org/10.2109/jcersj2.16114	journal	January 2016
Bulk-Type All-Solid-State Lithium Secondary Battery with Li2S-P2S5 Thin-Film Separator Sakuda, Atsushi; Hayashi, Akitoshi; Ohtomo, Takamasa Electrochemistry, Vol. 80, Issue 10 https://doi.org/10.5796/electrochemistry.80.839	journal	January 2012

Similar Records

Recent progress and future prospects of atomic layer deposition to prepare/modify solid-state electrolytes and interfaces between electrodes for next-generation lithium batteries

Journal Article · 2021 · Nanoscale Advances · OSTI ID:2471427

Han, Lu; Hsieh, Chien-Te; Chandra Mallick, Bikash; +2 more

Nanoscale Solid State Batteries Enabled by Thermal Atomic Layer Deposition of a Lithium Polyphosphazene Solid State Electrolyte

Journal Article · 2017 · Chemistry of Materials · OSTI ID:1360797

Pearse, Alexander J.; Schmitt, Thomas E.; Fuller, Elliot J.; +7 more

Structure, thermal stability and properties of Li{sub 3}Sc(BO{sub 3}){sub 2}

Journal Article · 2011 · Journal of Solid State Chemistry · OSTI ID:21496544

Tao, X M; Su, L M; Zheng, F; +2 more

Title: Atomic layer deposition and first principles modeling of glassy Li 3 BO 3 –Li 2 CO 3 electrolytes for solid-state Li metal batteries

Citation Formats

References (75)

Similar Records

Related Subjects

Title: Atomic layer deposition and first principles modeling of glassy Li ₃ BO ₃ –Li ₂ CO ₃ electrolytes for solid-state Li metal batteries