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Title: Role of disorder in limiting the true multi-electron redox in ε-LiVOPO 4

Ball-milling-induced disorder and defects impede multi-electron redox in ε-LiVOPO 4 and trigger side reactions.
Authors:
ORCiD logo [1] ; ORCiD logo [1] ;  [1] ; ORCiD logo [2] ;  [1] ;  [1] ;  [1] ;  [2] ; ORCiD logo [3] ; ORCiD logo [2] ;  [1] ; ORCiD logo [1] ; ORCiD logo [4] ; ORCiD logo [1] ; ORCiD logo [1]
  1. NorthEast Center for Chemical Energy Storage (NECCES) at Binghamton University in Binghamton, USA
  2. X-ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, USA
  3. Diamond Light Source Ltd., UK
  4. Department of Chemistry, Stony Brook University, New York 11974, USA
Publication Date:
Grant/Contract Number:
SC0012583
Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry A Journal Volume: 6 Journal Issue: 42; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United Kingdom
Language:
English
OSTI Identifier:
1475465

Rana, Jatinkumar, Shi, Yong, Zuba, Mateusz J., Wiaderek, Kamila M., Feng, Jun, Zhou, Hui, Ding, Jia, Wu, Tianpin, Cibin, Giannantonio, Balasubramanian, Mahalingam, Omenya, Fredrick, Chernova, Natasha A., Chapman, Karena W., Whittingham, M. Stanley, and Piper, Louis F. J.. Role of disorder in limiting the true multi-electron redox in ε-LiVOPO 4. United Kingdom: N. p., Web. doi:10.1039/C8TA06469E.
Rana, Jatinkumar, Shi, Yong, Zuba, Mateusz J., Wiaderek, Kamila M., Feng, Jun, Zhou, Hui, Ding, Jia, Wu, Tianpin, Cibin, Giannantonio, Balasubramanian, Mahalingam, Omenya, Fredrick, Chernova, Natasha A., Chapman, Karena W., Whittingham, M. Stanley, & Piper, Louis F. J.. Role of disorder in limiting the true multi-electron redox in ε-LiVOPO 4. United Kingdom. doi:10.1039/C8TA06469E.
Rana, Jatinkumar, Shi, Yong, Zuba, Mateusz J., Wiaderek, Kamila M., Feng, Jun, Zhou, Hui, Ding, Jia, Wu, Tianpin, Cibin, Giannantonio, Balasubramanian, Mahalingam, Omenya, Fredrick, Chernova, Natasha A., Chapman, Karena W., Whittingham, M. Stanley, and Piper, Louis F. J.. 2018. "Role of disorder in limiting the true multi-electron redox in ε-LiVOPO 4". United Kingdom. doi:10.1039/C8TA06469E.
@article{osti_1475465,
title = {Role of disorder in limiting the true multi-electron redox in ε-LiVOPO 4},
author = {Rana, Jatinkumar and Shi, Yong and Zuba, Mateusz J. and Wiaderek, Kamila M. and Feng, Jun and Zhou, Hui and Ding, Jia and Wu, Tianpin and Cibin, Giannantonio and Balasubramanian, Mahalingam and Omenya, Fredrick and Chernova, Natasha A. and Chapman, Karena W. and Whittingham, M. Stanley and Piper, Louis F. J.},
abstractNote = {Ball-milling-induced disorder and defects impede multi-electron redox in ε-LiVOPO 4 and trigger side reactions.},
doi = {10.1039/C8TA06469E},
journal = {Journal of Materials Chemistry A},
number = 42,
volume = 6,
place = {United Kingdom},
year = {2018},
month = {10}
}

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Electrochemical Behavior of Nanostructured ?-VOPO4 over Two Redox Plateaus
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Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
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