Dynamic behavior of CH3NH3PbI3 perovskite twin domains
Abstract
We report the recent discovery of twin domains in MAPbI3 perovskites has initiated contentious discussion on the ferroic nature of hybrid perovskites. Ferroelectric polarization is thought to facilitate the dissociation of photoinduced electron-hole pairs, helping to explain the extraordinary photovoltaic performance exhibited by this class of materials. Alternate to ferroelectricity, which has yet to be unambiguously established despite considerable efforts to do so, ferroelasticity was also proposed in these materials. Meanwhile, given the coupling of ionic states and ferroelectricity and the interconnected nature of defect chemistry and ferroelasticity, the electrochemical reactivity can no longer be ignored. In this work, using band excitation piezoresponse force microscopy, we reveal the variation in elasticity between adjacent domains, indicating the ferroelasticity and the difference in the crystallographic states of the twin domain. Moreover, using band excitation contact Kelvin probe force microscopy, we dynamically map the evolution of the twinning structure under electric bias. These results help decipher the effect of the twin domains on ionic mobility and ion diffusion pathways. Combining these results, we reveal the interaction of twin domains and ionic activity in this material. Furthermore, this work provides insights into the twinning structure in MAPbI3 and its potential effects on the hybridmore »
- Authors:
-
[1];
[2];
[2];
[2];
[2];
[2];
[2];
[2];
[2];
[2]
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS); Univ. of Tennessee, Knoxville, TN (United States). Department of Materials Science and Engineering
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
- Univ. of Tennessee, Knoxville, TN (United States). Department of Materials Science and Engineering
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1474602
- Alternate Identifier(s):
- OSTI ID: 1464317
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 113; Journal Issue: 7; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Liu, Yongtao, Collins, Liam F., Belianinov, Alex, Neumayer, Sabine M., Ievlev, Anton V., Ahmadi, Mahshid, Xiao, Kai, Retterer, Scott T., Jesse, Stephen, Kalinin, Sergei V., Hu, Bin, and Ovchinnikova, Olga S. Dynamic behavior of CH3NH3PbI3 perovskite twin domains. United States: N. p., 2018.
Web. doi:10.1063/1.5041256.
Liu, Yongtao, Collins, Liam F., Belianinov, Alex, Neumayer, Sabine M., Ievlev, Anton V., Ahmadi, Mahshid, Xiao, Kai, Retterer, Scott T., Jesse, Stephen, Kalinin, Sergei V., Hu, Bin, & Ovchinnikova, Olga S. Dynamic behavior of CH3NH3PbI3 perovskite twin domains. United States. https://doi.org/10.1063/1.5041256
Liu, Yongtao, Collins, Liam F., Belianinov, Alex, Neumayer, Sabine M., Ievlev, Anton V., Ahmadi, Mahshid, Xiao, Kai, Retterer, Scott T., Jesse, Stephen, Kalinin, Sergei V., Hu, Bin, and Ovchinnikova, Olga S. Mon .
"Dynamic behavior of CH3NH3PbI3 perovskite twin domains". United States. https://doi.org/10.1063/1.5041256. https://www.osti.gov/servlets/purl/1474602.
@article{osti_1474602,
title = {Dynamic behavior of CH3NH3PbI3 perovskite twin domains},
author = {Liu, Yongtao and Collins, Liam F. and Belianinov, Alex and Neumayer, Sabine M. and Ievlev, Anton V. and Ahmadi, Mahshid and Xiao, Kai and Retterer, Scott T. and Jesse, Stephen and Kalinin, Sergei V. and Hu, Bin and Ovchinnikova, Olga S.},
abstractNote = {We report the recent discovery of twin domains in MAPbI3 perovskites has initiated contentious discussion on the ferroic nature of hybrid perovskites. Ferroelectric polarization is thought to facilitate the dissociation of photoinduced electron-hole pairs, helping to explain the extraordinary photovoltaic performance exhibited by this class of materials. Alternate to ferroelectricity, which has yet to be unambiguously established despite considerable efforts to do so, ferroelasticity was also proposed in these materials. Meanwhile, given the coupling of ionic states and ferroelectricity and the interconnected nature of defect chemistry and ferroelasticity, the electrochemical reactivity can no longer be ignored. In this work, using band excitation piezoresponse force microscopy, we reveal the variation in elasticity between adjacent domains, indicating the ferroelasticity and the difference in the crystallographic states of the twin domain. Moreover, using band excitation contact Kelvin probe force microscopy, we dynamically map the evolution of the twinning structure under electric bias. These results help decipher the effect of the twin domains on ionic mobility and ion diffusion pathways. Combining these results, we reveal the interaction of twin domains and ionic activity in this material. Furthermore, this work provides insights into the twinning structure in MAPbI3 and its potential effects on the hybrid perovskite optoelectronics.},
doi = {10.1063/1.5041256},
journal = {Applied Physics Letters},
number = 7,
volume = 113,
place = {United States},
year = {2018},
month = {8}
}
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Works referenced in this record:
Ferroionic states in ferroelectric thin films
journal, May 2017
- Morozovska, Anna N.; Eliseev, Eugene A.; Morozovsky, Nicholas V.
- Physical Review B, Vol. 95, Issue 19
Self-formed grain boundary healing layer for highly efficient CH3NH3PbI3 perovskite solar cells
journal, June 2016
- Son, Dae-Yong; Lee, Jin-Wook; Choi, Yung Ji
- Nature Energy, Vol. 1, Issue 7
Differentiating Ferroelectric and Nonferroelectric Electromechanical Effects with Scanning Probe Microscopy
journal, May 2015
- Balke, Nina; Maksymovych, Petro; Jesse, Stephen
- ACS Nano, Vol. 9, Issue 6
On the importance of ferroelectric domains for the performance of perovskite solar cells
journal, June 2018
- Rossi, Daniele; Pecchia, Alessandro; Maur, Matthias Auf der
- Nano Energy, Vol. 48
The band excitation method in scanning probe microscopy for rapid mapping of energy dissipation on the nanoscale
journal, September 2007
- Jesse, Stephen; Kalinin, Sergei V.; Proksch, Roger
- Nanotechnology, Vol. 18, Issue 43
Exploring Anomalous Polarization Dynamics in Organometallic Halide Perovskites
journal, January 2018
- Ahmadi, Mahshid; Collins, Liam; Puretzky, Alexander
- Advanced Materials, Vol. 30, Issue 11
Mapping nanoscale elasticity and dissipation using dual frequency contact resonance AFM
journal, August 2011
- Gannepalli, A.; Yablon, D. G.; Tsou, A. H.
- Nanotechnology, Vol. 22, Issue 35
Unravelling the Effects of Grain Boundary and Chemical Doping on Electron–Hole Recombination in CH 3 NH 3 PbI 3 Perovskite by Time-Domain Atomistic Simulation
journal, March 2016
- Long, Run; Liu, Jin; Prezhdo, Oleg V.
- Journal of the American Chemical Society, Vol. 138, Issue 11
High-Gain and Low-Driving-Voltage Photodetectors Based on Organolead Triiodide Perovskites
journal, January 2015
- Dong, Rui; Fang, Yanjun; Chae, Jungseok
- Advanced Materials, Vol. 27, Issue 11
Sequential deposition as a route to high-performance perovskite-sensitized solar cells
journal, July 2013
- Burschka, Julian; Pellet, Norman; Moon, Soo-Jin
- Nature, Vol. 499, Issue 7458, p. 316-319
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009
- Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
- Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
Iodine Migration and its Effect on Hysteresis in Perovskite Solar Cells
journal, January 2016
- Li, Cheng; Tscheuschner, Steffen; Paulus, Fabian
- Advanced Materials, Vol. 28, Issue 12
Solution-processed hybrid perovskite photodetectors with high detectivity
journal, November 2014
- Dou, Letian; Yang, Yang (Micheal); You, Jingbi
- Nature Communications, Vol. 5, Issue 1
Dual-frequency resonance-tracking atomic force microscopy
journal, October 2007
- Rodriguez, Brian J.; Callahan, Clint; Kalinin, Sergei V.
- Nanotechnology, Vol. 18, Issue 47, Article No. 475504
Drive frequency dependent phase imaging in piezoresponse force microscopy
journal, August 2010
- Bo, Huifeng; Kan, Yi; Lu, Xiaomei
- Journal of Applied Physics, Vol. 108, Issue 4
Enhancing Ion Migration in Grain Boundaries of Hybrid Organic-Inorganic Perovskites by Chlorine
journal, May 2017
- Yang, Bin; Brown, Chance C.; Huang, Jingsong
- Advanced Functional Materials, Vol. 27, Issue 26
A deconvoluted PL approach to probe the charge carrier dynamics of the grain interior and grain boundary of a perovskite film for perovskite solar cell applications
journal, January 2017
- Mamun, Abdullah Al; Ava, Tanzila Tasnim; Jeong, Hyeon Jun
- Physical Chemistry Chemical Physics, Vol. 19, Issue 13
Colloidally prepared La-doped BaSnO 3 electrodes for efficient, photostable perovskite solar cells
journal, March 2017
- Shin, Seong Sik; Yeom, Eun Joo; Yang, Woon Seok
- Science, Vol. 356, Issue 6334
Ferroic domains regulate photocurrent in single-crystalline CH3NH3PbI3 films self-grown on FTO/TiO2 substrate
journal, June 2018
- Huang, Boyuan; Kong, Guoli; Esfahani, Ehsan Nasr
- npj Quantum Materials, Vol. 3, Issue 1
Orientation of Ferroelectric Domains and Disappearance upon Heating Methylammonium Lead Triiodide Perovskite from Tetragonal to Cubic Phase
journal, March 2018
- Vorpahl, Sarah M.; Giridharagopal, Rajiv; Eperon, Giles E.
- ACS Applied Energy Materials, Vol. 1, Issue 4
Ferroelastic Fingerprints in Methylammonium Lead Iodide Perovskite
journal, January 2016
- Hermes, Ilka M.; Bretschneider, Simon A.; Bergmann, Victor W.
- The Journal of Physical Chemistry C, Vol. 120, Issue 10
Ion Migration in Organometal Trihalide Perovskite and Its Impact on Photovoltaic Efficiency and Stability
journal, January 2016
- Yuan, Yongbo; Huang, Jinsong
- Accounts of Chemical Research, Vol. 49, Issue 2
Band Excitation in Scanning Probe Microscopy: Recognition and Functional Imaging
journal, April 2014
- Jesse, S.; Vasudevan, R. K.; Collins, L.
- Annual Review of Physical Chemistry, Vol. 65, Issue 1
Viscoelastic Property Mapping with Contact Resonance Force Microscopy
journal, December 2011
- Killgore, J. P.; Yablon, D. G.; Tsou, A. H.
- Langmuir, Vol. 27, Issue 23
Photoinduced enhancement of a triboelectric nanogenerator based on an organolead halide perovskite
journal, January 2016
- Su, Li; Zhao, Zhenxuan; Li, Huayang
- Journal of Materials Chemistry C, Vol. 4, Issue 43
Ferroelectric domains in methylammonium lead iodide perovskite thin-films
journal, January 2017
- Röhm, Holger; Leonhard, Tobias; Hoffmann, Michael J.
- Energy & Environmental Science, Vol. 10, Issue 4
Direct observation of intrinsic twin domains in tetragonal CH3NH3PbI3
journal, February 2017
- Rothmann, Mathias Uller; Li, Wei; Zhu, Ye
- Nature Communications, Vol. 8, Issue 1
Ferroelectric or non-ferroelectric: Why so many materials exhibit “ferroelectricity” on the nanoscale
journal, June 2017
- Vasudevan, Rama K.; Balke, Nina; Maksymovych, Peter
- Applied Physics Reviews, Vol. 4, Issue 2
CH 3 NH 3 PbI 3 perovskites: Ferroelasticity revealed
journal, April 2017
- Strelcov, Evgheni; Dong, Qingfeng; Li, Tao
- Science Advances, Vol. 3, Issue 4
Effect of surface ionic screening on the polarization reversal scenario in ferroelectric thin films: Crossover from ferroionic to antiferroionic states
journal, December 2017
- Morozovska, Anna N.; Eliseev, Eugene A.; Kurchak, Anatolii I.
- Physical Review B, Vol. 96, Issue 24
Contact-resonance atomic force microscopy for viscoelasticity
journal, January 2008
- Yuya, P. A.; Hurley, D. C.; Turner, J. A.
- Journal of Applied Physics, Vol. 104, Issue 7
Determination of the True Lateral Grain Size in Organic–Inorganic Halide Perovskite Thin Films
journal, April 2017
- MacDonald, Gordon A.; Heveran, Chelsea M.; Yang, Mengjin
- ACS Applied Materials & Interfaces, Vol. 9, Issue 39
Nanoscale mapping of ion diffusion in a lithium-ion battery cathode
journal, August 2010
- Balke, N.; Jesse, S.; Morozovska, A. N.
- Nature Nanotechnology, Vol. 5, Issue 10
CH3NH3PbI3 perovskites: Ferroelasticity revealed
text, January 2017
- Y., Shao,; J., Huang,; Y., Deng,
- The University of North Carolina at Chapel Hill University Libraries
Scanning Probe Microscopy
journal, January 2008
- Morita, Seizo
- Journal of the Vacuum Society of Japan, Vol. 51, Issue 12
Ferroelectric or non-ferroelectric: why so many materials exhibit ferroelectricity on the nanoscale
preprint, January 2017
- Vasudevan, Rama K.; Balke, Nina; Maksymovych, Peter
- arXiv
Effect of surface ionic screening on polarization reversal scenario in ferroelectric thin films: crossover from ferroionic to antiferroionic states
text, January 2017
- Morozovska, Anna N.; Eliseev, Eugene A.; Kurchak, Anatolii I.
- arXiv
Works referencing / citing this record:
Ferroelectric Properties of Perovskite Thin Films and Their Implications for Solar Energy Conversion
journal, February 2019
- Röhm, Holger; Leonhard, Tobias; Schulz, Alexander D.
- Advanced Materials, Vol. 31, Issue 26
Light‐Ferroic Interaction in Hybrid Organic–Inorganic Perovskites
journal, September 2019
- Liu, Yongtao; Ievlev, Anton V.; Collins, Liam
- Advanced Optical Materials, Vol. 7, Issue 23
Strain–Chemical Gradient and Polarization in Metal Halide Perovskites
journal, April 2020
- Liu, Yongtao; Ievlev, Anton V.; Collins, Liam
- Advanced Electronic Materials, Vol. 6, Issue 4
Zur Rolle der Iodid‐Methylammonium‐Interaktion in der Ferroelektrizität in CH 3 NH 3 PbI 3
journal, November 2019
- Breternitz, J.; Lehmann, F.; Barnett, S. A.
- Angewandte Chemie, Vol. 132, Issue 1
Role of the Iodide–Methylammonium Interaction in the Ferroelectricity of CH 3 NH 3 PbI 3
journal, November 2019
- Breternitz, J.; Lehmann, F.; Barnett, S. A.
- Angewandte Chemie International Edition, Vol. 59, Issue 1
Probing the Microstructure of Methylammonium Lead Iodide Perovskite Solar Cells
journal, March 2019
- Leonhard, Tobias; Schulz, Alexander D.; Röhm, Holger
- Energy Technology, Vol. 7, Issue 3
Ferroelastic domains drive charge separation and suppress electron–hole recombination in all-inorganic halide perovskites: time-domain ab initio analysis
journal, January 2020
- Shi, Ran; Zhang, Zhaosheng; Fang, Wei-hai
- Nanoscale Horizons, Vol. 5, Issue 4
Dielectric and ferroic properties of metal halide perovskites
journal, January 2019
- Wilson, Jacob N.; Frost, Jarvist M.; Wallace, Suzanne K.
- APL Materials, Vol. 7, Issue 1
Twin domains modulate light-matter interactions in metal halide perovskites
journal, January 2020
- Liu, Yongtao; Li, Mingxing; Wang, Miaosheng
- APL Materials, Vol. 8, Issue 1
Role of the iodide–methylammonium interaction in the ferroelectricity of CH3NH3PbI3
text, January 2019
- Breternitz, J.; Lehmann, F.; Barnett, S. A.
- Freie Universität Berlin
Ferroelectric Properties of Perovskite Thin Films and Their Implications for Solar Energy Conversion
text, January 2019
- Röhm, Holger; Leonhard, Tobias; Schulz, Alexander D.
- Karlsruhe