Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides

Felder, Justin B.; Smith, Mark D.; Sefat, Athena; zur Loye, Hans-Conrad

doi:10.1016/j.solidstatesciences.2018.04.014

Title: Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides

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Abstract

The mild hydrothermal crystal growth technique has been leveraged to synthesize four new zero-dimensional transition metal fluorides. Their structures were determined by single crystal X-ray diffraction and confirmed by powder X-ray diffraction. The thermal, optical, and magnetic properties were investigated and the presence of thermal polymorphism and antiferromagnetism were observed. In addition, the potential application of these materials as precursors for advanced functional materials was explored.

Authors:

Felder, Justin B. ^[1]; Smith, Mark D. ^[1]; Sefat, Athena ^[2]; zur Loye, Hans-Conrad ^[1]

Univ. of South Carolina, Columbia, SC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: 2018-04-28

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1474520

Alternate Identifier(s):: OSTI ID: 1495493

Grant/Contract Number:: AC05-00OR22725; SC0008664

Resource Type:: Accepted Manuscript

Journal Name:: Solid State Sciences

Additional Journal Information:: Journal Volume: 81; Journal Issue: C; Journal ID: ISSN 1293-2558

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

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                    Felder, Justin B., Smith, Mark D., Sefat, Athena, and zur Loye, Hans-Conrad. Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides.  United States: N. p., 2018. 
        Web.  doi:10.1016/j.solidstatesciences.2018.04.014.

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                    Felder, Justin B., Smith, Mark D., Sefat, Athena, & zur Loye, Hans-Conrad. Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides.  United States.  doi:https://doi.org/10.1016/j.solidstatesciences.2018.04.014

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                    Felder, Justin B., Smith, Mark D., Sefat, Athena, and zur Loye, Hans-Conrad. Sat .  
        "Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides".  United States.  doi:https://doi.org/10.1016/j.solidstatesciences.2018.04.014.  https://www.osti.gov/servlets/purl/1474520.

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@article{osti_1474520,

  title        = {Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides},

  author       = {Felder, Justin B. and Smith, Mark D. and Sefat, Athena and zur Loye, Hans-Conrad},

  abstractNote = {The mild hydrothermal crystal growth technique has been leveraged to synthesize four new zero-dimensional transition metal fluorides. Their structures were determined by single crystal X-ray diffraction and confirmed by powder X-ray diffraction. The thermal, optical, and magnetic properties were investigated and the presence of thermal polymorphism and antiferromagnetism were observed. In addition, the potential application of these materials as precursors for advanced functional materials was explored.},

  doi          = {10.1016/j.solidstatesciences.2018.04.014},

  journal      = {Solid State Sciences},

  number       = C,

  volume       = 81,

  place        = {United States},

  year         = {2018},

  month        = {4}

}

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DOI: https://doi.org/10.1016/j.solidstatesciences.2018.04.014

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