Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides

Felder, Justin B.; Smith, Mark D.; Sefat, Athena; zur Loye, Hans-Conrad

doi:10.1016/j.solidstatesciences.2018.04.014

Title: Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides

Full Record
Other Related Research

Abstract

The mild hydrothermal crystal growth technique has been leveraged to synthesize four new zero-dimensional transition metal fluorides. Their structures were determined by single crystal X-ray diffraction and confirmed by powder X-ray diffraction. The thermal, optical, and magnetic properties were investigated and the presence of thermal polymorphism and antiferromagnetism were observed. In addition, the potential application of these materials as precursors for advanced functional materials was explored.

Authors:

Felder, Justin B. ^[1]; Smith, Mark D. ^[1]; Sefat, Athena ^[2]; zur Loye, Hans-Conrad ^[1]

Univ. of South Carolina, Columbia, SC (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: 2018-04-28

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1474520

Alternate Identifier(s):: OSTI ID: 1495493

Grant/Contract Number:: AC05-00OR22725; SC0008664

Resource Type:: Accepted Manuscript

Journal Name:: Solid State Sciences

Additional Journal Information:: Journal Volume: 81; Journal Issue: C; Journal ID: ISSN 1293-2558

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Felder, Justin B., Smith, Mark D., Sefat, Athena, and zur Loye, Hans-Conrad. Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides.  United States: N. p., 2018. 
Web.  doi:10.1016/j.solidstatesciences.2018.04.014.

Copy to clipboard


                    Felder, Justin B., Smith, Mark D., Sefat, Athena, & zur Loye, Hans-Conrad. Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides.  United States.  https://doi.org/10.1016/j.solidstatesciences.2018.04.014

Copy to clipboard


                    Felder, Justin B., Smith, Mark D., Sefat, Athena, and zur Loye, Hans-Conrad. Sat .  
"Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides".  United States.  https://doi.org/10.1016/j.solidstatesciences.2018.04.014.  https://www.osti.gov/servlets/purl/1474520.

Copy to clipboard


                    
@article{osti_1474520,

  title        = {Magnetic and thermal behavior of a family of compositionally related zero-dimensional fluorides},

  author       = {Felder, Justin B. and Smith, Mark D. and Sefat, Athena and zur Loye, Hans-Conrad},

  abstractNote = {The mild hydrothermal crystal growth technique has been leveraged to synthesize four new zero-dimensional transition metal fluorides. Their structures were determined by single crystal X-ray diffraction and confirmed by powder X-ray diffraction. The thermal, optical, and magnetic properties were investigated and the presence of thermal polymorphism and antiferromagnetism were observed. In addition, the potential application of these materials as precursors for advanced functional materials was explored.},

  doi          = {10.1016/j.solidstatesciences.2018.04.014},

  journal      = {Solid State Sciences},

  number       = C,

  volume       = 81,

  place        = {United States},

  year         = {2018},

  month        = {4}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1016/j.solidstatesciences.2018.04.014

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

Retention of a Paramagnetic Ground State at Low Temperatures in a Family of Structurally Related U ^IV Phosphates

Journal Article Felder, Justin B. ; Calder, Stuart ; zur Loye, Hans-Conrad - Inorganic Chemistry

A new uranium fluoride phosphate, UFPO4, was synthesized via a mild hydrothermal route and characterized optically, thermally, and magnetically. Two thermal transformation products, U₂O(PO₄)₂ and U^IVU^VIO₂(PO₄)₂, were discovered to be structurally related, and were subsequently synthesized for bulk property measurements. All three materials failed to follow Curie–Weiss behavior at low temperatures, attributed to the nearly ubiquitous singlet ground state of U(IV), transitioning into a Curie–Weiss paramagnetic regime at high temperatures. Neutron diffraction experiments were performed on UFPO₄ and U^IVU^VIO₂(PO₄)₂ in order to characterize this unusual magnetic behavior.
Cited by 4
https://doi.org/10.1021/acs.inorgchem.8b01284

Full Text Available
Hydrothermal synthesis, crystal structure, thermal behavior and spectroscopic and magnetic properties of two new organically templated fluoro-vanadyl-hydrogenarsenates: (R){sub 0.5}[(VO)(HAsO{sub 4})F] (R: Ethylenediammonium and piperazinium)

Journal Article Berrocal, Teresa ; Mesa, Jose L. ; Pizarro, Jose L ; ... - Journal of Solid State Chemistry

Two new fluoro-vanadyl-hydrogenarsenate compounds templated by ethylenediamine and piperazine with formula, (C{sub 2}N{sub 2}H{sub 10}){sub 0.5}[(VO)(HAsO{sub 4})F] (1) and (C{sub 4}N{sub 2}H{sub 12}){sub 0.5}[(VO)(HAsO{sub 4})F] (2), respectively, have been synthesized by using mild hydrothermal conditions under autogenous pressure. The crystal structures have been solved from single-crystal X-ray diffraction data. The phases crystallize in the P2{sub 1}/c monoclinic space group with the unit-cell parameters a=7.8634(4) A, b=7.7658(4) A, c=10.4195(6) A, {beta}=101.524(5){sup o} for compound (1) and a=6.301(1) A, b=10.244(1) A, c=10.248(1) A and {beta}=95.225(1){sup o} for compound (2). These phases exhibit a layered inorganic framework. In both cases, the structure ismore »« less
https://doi.org/10.1016/j.jssc.2008.01.037
Two new two-dimensional organically templated phosphite compounds: (C{sub 6}H{sub 16}N{sub 2}){sub 0.5}[M(HPO{sub 3})F], M=Fe(II) and Co(II): Solvothermal synthesis, crystal structures, thermal, spectroscopic, and magnetic properties

Journal Article Fernandez-Armas, Sergio ; Mesa, Jose L ; Pizarro, Jose L ; ... - Journal of Solid State Chemistry

The organically templated (C{sub 6}H{sub 16}N{sub 2}){sub 0.5}[M(HPO{sub 3})F] [M(II)=Fe (1) and Co (2)] compounds have been synthesized by using mild hydrothermal conditions under autogeneous pressure. The crystal structures have been determined from X-ray single-crystal diffraction data. The compounds are isostructural and crystallize in the C2/c monoclinic space group. The unit-cell parameters are a=5.607(1), b=21.276(4), c=11.652(1)A, {beta}=93.74(1) deg. for the iron phase and a=5.5822(7), b=21.325(3), c=11.4910(1)A, {beta}=93.464(9){sup o} for the cobalt compound with Z=4. The crystal structure of these compounds consists of [M(HPO{sub 3})F]{sup -} anionic sheets. The layers are constructed from chains which contain [M{sub 2}O{sub 6}F{sub 3}] dimericmore »« less
https://doi.org/10.1016/j.jssc.2005.09.032
Synthesis and characterization of new fluoride-containing manganese vanadates A{sub 2}Mn{sub 2}V{sub 2}O{sub 7}F{sub 2} (A=Rb, Cs) and Mn{sub 2}VO{sub 4}F

Journal Article Sanjeewa, Liurukara D. ; McGuire, Michael A. ; Smith Pellizzeri, Tiffany M. ; ... - Journal of Solid State Chemistry

Large single crystals of A{sub 2}Mn{sub 2}V{sub 2}O{sub 7}F{sub 2} (A=Rb, Cs) and Mn{sub 2}VO{sub 4}F were grown using a high-temperature (~600 °C) hydrothermal technique. Single crystal X-ray diffraction and powder X-ray diffraction were utilized to characterize the structures, which both possess MnO{sub 4}F{sub 2} building blocks. The A{sub 2}Mn{sub 2}V{sub 2}O{sub 7}F{sub 2} series crystallizes as a new structure type in space group Pbcn (No. 60), Z=4 (Rb{sub 2}Mn{sub 2}V{sub 2}O{sub 7}F{sub 2}: a=7.4389(17) Å, b=11.574(3) Å, c=10.914(2) Å; Cs{sub 2}Mn{sub 2}V{sub 2}O{sub 7}F{sub 2}: a=7.5615(15) Å, b=11.745(2) Å, c=11.127(2) Å). The structure is composed of zigzag chains ofmore »« less
https://doi.org/10.1016/J.JSSC.2016.05.008
A Mechanistic Understanding of Nonclassical Crystal Growth in Hydrothermally Synthesized Sodium Yttrium Fluoride Nanowires

Journal Article Bard, Alexander B. ; Zhou, Xuezhe ; Xia, Xiaojing ; ... - Chemistry of Materials

Sodium yttrium fluoride (NaYF4) is an important upconverting material with many potential uses in chemistry, materials science, and biology, which can be synthesized hydrothermally in both cubic (a) and hexagonal (ß) crystallographic polymorphs. Understanding the mechanisms underlying the phase conversion between the cubic and hexagonal polymorphs is of great interest to help inform future efforts to synthesize atomically-precise quantum materials with well-defined sizes and morphologies. In this work, we use a combination of analytical transmission electron microscopy (TEM), scanning transmission electron microscopy (STEM), powder X-ray diffraction (XRD), in situ liquid cell TEM, atom probe tomography (APT), and extended x-ray absorptionmore »« less
https://doi.org/10.1021/acs.chemmater.9b04076

Full Text Available

Similar Records