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Title: Does Marine Surface Tension Have Global Biogeography? Addition for the OCEANFILMS Package

Abstract

We apply principles of Gibbs phase plane chemistry across the entire ocean-atmosphere interface to investigate aerosol generation and geophysical transfer issues. Marine surface tension differences comprise a tangential pressure field controlling trace gas fluxes, primary organic inputs, and sea spray salt injections, in addition to heat and momentum fluxes. Mapping follows from the organic microlayer composition, now represented in ocean system models. Organic functional variations drive the microforcing, leading to (1) reduced turbulence and (by extension) laminar gas-energy diffusion; plus (2) altered bubble film mass emission into the boundary layer. Interfacial chemical behaviors are, therefore, closely reviewed as the background. We focus on phase transitions among two dimensional “solid, liquid, and gaseous” states serving as elasticity indicators. From the pool of dissolved organic carbon (DOC) only proteins and lipids appear to occupy significant atmospheric interfacial areas. The literature suggests albumin and stearic acid as the best proxies, and we distribute them through ecodynamic simulation. Consensus bulk distributions are obtained to control their adsorptive equilibria. We devise parameterizations for both the planar free energy and equation of state, relating excess coverage to the surface pressure and its modulus. Constant settings for the molecular surrogates are drawn from laboratory study and successfullymore » reproduce surfactant solid-to-gas occurrence in compression experiments. Since DOC functionality measurements are rare, we group them into super-ecological province tables to verify aqueous concentration estimates. Outputs are then fed into a coverage, tension, elasticity code. The resulting two dimensional pressure contours cross a critical range for the regulation of precursor piston velocity, bubble breakage, and primary aerosol sources plus ripple damping. Concepts extend the water-air adsorption theory currently embodied in our OCEANFILMS aerosol emissions package, and the two approaches could be inserted into Earth System Models together. Uncertainties in the logic include kinetic and thermochemical factors operating at multiple scales.« less

Authors:
ORCiD logo [1];  [2];  [3];  [4]; ORCiD logo [1]; ORCiD logo [1];  [5]; ORCiD logo [1];  [1];  [6]; ORCiD logo [1]; ORCiD logo [1];  [7];  [8];  [9];  [10]; ORCiD logo [11];  [12];  [11];  [13]
+ Show Author Affiliations
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
  3. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  5. Texas A & M Univ., College Station, TX (United States)
  6. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Building Technologies Research and Integration Center (BTRIC)
  7. Univ. of Arizona, Tucson, AZ (United States)
  8. International Arctic Research Center, Fairbanks, AK (United States)
  9. Univ. of New Hampshire, Durham, NH (United States)
  10. North Carolina State Univ., Raleigh, NC (United States)
  11. Univ. of California, San Diego, CA (United States). Scripps Inst. of Oceanography
  12. National Center for Atmospheric Research, Boulder, CO (United States)
  13. New Mexico Inst. of Mining and Technology, Socorro, NM (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Biological and Environmental Research (BER) (SC-23); USDOE Office of Science (SC). Biological and Environmental Research (BER) (SC-23)
OSTI Identifier:
1474516
Alternate Identifier(s):
OSTI ID: 1557763
Report Number(s):
LA-UR-19-20906
Journal ID: ISSN 2073-4433; ATMOCZ
Grant/Contract Number:  
AC05-00OR22725; 89233218CNA000001
Resource Type:
Accepted Manuscript
Journal Name:
Atmosphere (Basel)
Additional Journal Information:
Journal Name: Atmosphere (Basel); Journal Volume: 9; Journal Issue: 6; Journal ID: ISSN 2073-4433
Publisher:
MDPI
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; Earth Sciences; interfacial surface tension and pressure; gas precursors; primary aerosol; heat and momentum flux; biogeochemical mapping; organic macromolecules; surfactants; elasticity; proteins; lipids; compressio

Citation Formats

Elliott, Scott M., Burrows, Susannah, Cameron-Smith, Philip, Hoffman, Forrest, Hunke, Elizabeth Clare, Jeffery, Nicole, Liu, Yina, Maltrud, Mathew Einar, Menzo, Zachary Michael, Ogunro, Oluwaseun, Van Roekel, Luke, Wang, Shanlin, Brunke, Michael, Jin, Meibing, Letscher, Robert, Meskhidze, Nicholas, Russell, Lynn, Simpson, Isla, Stokes, Dale, and Wingenter, Oliver. Does Marine Surface Tension Have Global Biogeography? Addition for the OCEANFILMS Package. United States: N. p., 2018. Web. doi:10.3390/atmos9060216.
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Elliott, Scott M., Burrows, Susannah, Cameron-Smith, Philip, Hoffman, Forrest, Hunke, Elizabeth Clare, Jeffery, Nicole, Liu, Yina, Maltrud, Mathew Einar, Menzo, Zachary Michael, Ogunro, Oluwaseun, Van Roekel, Luke, Wang, Shanlin, Brunke, Michael, Jin, Meibing, Letscher, Robert, Meskhidze, Nicholas, Russell, Lynn, Simpson, Isla, Stokes, Dale, & Wingenter, Oliver. Does Marine Surface Tension Have Global Biogeography? Addition for the OCEANFILMS Package. United States. doi:10.3390/atmos9060216.
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Elliott, Scott M., Burrows, Susannah, Cameron-Smith, Philip, Hoffman, Forrest, Hunke, Elizabeth Clare, Jeffery, Nicole, Liu, Yina, Maltrud, Mathew Einar, Menzo, Zachary Michael, Ogunro, Oluwaseun, Van Roekel, Luke, Wang, Shanlin, Brunke, Michael, Jin, Meibing, Letscher, Robert, Meskhidze, Nicholas, Russell, Lynn, Simpson, Isla, Stokes, Dale, and Wingenter, Oliver. Mon . "Does Marine Surface Tension Have Global Biogeography? Addition for the OCEANFILMS Package". United States. doi:10.3390/atmos9060216. https://www.osti.gov/servlets/purl/1474516.
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@article{osti_1474516,
title = {Does Marine Surface Tension Have Global Biogeography? Addition for the OCEANFILMS Package},
author = {Elliott, Scott M. and Burrows, Susannah and Cameron-Smith, Philip and Hoffman, Forrest and Hunke, Elizabeth Clare and Jeffery, Nicole and Liu, Yina and Maltrud, Mathew Einar and Menzo, Zachary Michael and Ogunro, Oluwaseun and Van Roekel, Luke and Wang, Shanlin and Brunke, Michael and Jin, Meibing and Letscher, Robert and Meskhidze, Nicholas and Russell, Lynn and Simpson, Isla and Stokes, Dale and Wingenter, Oliver},
abstractNote = {We apply principles of Gibbs phase plane chemistry across the entire ocean-atmosphere interface to investigate aerosol generation and geophysical transfer issues. Marine surface tension differences comprise a tangential pressure field controlling trace gas fluxes, primary organic inputs, and sea spray salt injections, in addition to heat and momentum fluxes. Mapping follows from the organic microlayer composition, now represented in ocean system models. Organic functional variations drive the microforcing, leading to (1) reduced turbulence and (by extension) laminar gas-energy diffusion; plus (2) altered bubble film mass emission into the boundary layer. Interfacial chemical behaviors are, therefore, closely reviewed as the background. We focus on phase transitions among two dimensional “solid, liquid, and gaseous” states serving as elasticity indicators. From the pool of dissolved organic carbon (DOC) only proteins and lipids appear to occupy significant atmospheric interfacial areas. The literature suggests albumin and stearic acid as the best proxies, and we distribute them through ecodynamic simulation. Consensus bulk distributions are obtained to control their adsorptive equilibria. We devise parameterizations for both the planar free energy and equation of state, relating excess coverage to the surface pressure and its modulus. Constant settings for the molecular surrogates are drawn from laboratory study and successfully reproduce surfactant solid-to-gas occurrence in compression experiments. Since DOC functionality measurements are rare, we group them into super-ecological province tables to verify aqueous concentration estimates. Outputs are then fed into a coverage, tension, elasticity code. The resulting two dimensional pressure contours cross a critical range for the regulation of precursor piston velocity, bubble breakage, and primary aerosol sources plus ripple damping. Concepts extend the water-air adsorption theory currently embodied in our OCEANFILMS aerosol emissions package, and the two approaches could be inserted into Earth System Models together. Uncertainties in the logic include kinetic and thermochemical factors operating at multiple scales.},
doi = {10.3390/atmos9060216},
journal = {Atmosphere (Basel)},
number = 6,
volume = 9,
place = {United States},
year = {2018},
month = {6}
}
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DOI:  10.3390/atmos9060216
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Spontaneous assembly of marine dissolved organic matter into polymer gels
journal, February 1998

  • Chin, Wei-Chun; Orellana, Mónica V.; Verdugo, Pedro
  • Nature, Vol. 391, Issue 6667
  • DOI: 10.1038/35345

Observed physical and environmental causes of scatter in whitecap coverage values in a fetch-limited coastal zone
journal, January 2008

  • Callaghan, Adrian H.; Deane, Grant B.; Stokes, M. Dale
  • Journal of Geophysical Research, Vol. 113, Issue C5
  • DOI: 10.1029/2007JC004453

Global distribution and climate forcing of marine organic aerosol: 1. Model improvements and evaluation
journal, January 2011

Production and fate of transparent exopolymer particles in the ocean
journal, January 2011

  • Wurl, Oliver; Miller, Lisa; Vagle, Svein
  • Journal of Geophysical Research, Vol. 116
  • DOI: 10.1029/2011JC007342

The Statistical Mechanical Theory of Surface Tension
journal, March 1949

  • Kirkwood, John G.; Buff, Frank P.
  • The Journal of Chemical Physics, Vol. 17, Issue 3
  • DOI: 10.1063/1.1747248

The damping of ocean waves by surface films: A new look at an old problem
journal, January 1989

  • Alpers, Werner; Hühnerfuss, Heinrich
  • Journal of Geophysical Research, Vol. 94, Issue C5
  • DOI: 10.1029/JC094iC05p06251

From Anchovies to Sardines and Back: Multidecadal Change in the Pacific Ocean
journal, January 2003

The electrification of the atmosphere by particles from bubbles in the sea
journal, January 1963

The organic chemical composition of the ocean surface
journal, April 1967

Ecosystem behavior at Bermuda Station “S” and ocean weather station “India”: A general circulation model and observational analysis
journal, June 1993

  • Fasham, M. J. R.; Sarmiento, J. L.; Slater, R. D.
  • Global Biogeochemical Cycles, Vol. 7, Issue 2
  • DOI: 10.1029/92GB02784

In situ measurements of surface tension, wave damping, and wind properties modified by natural films
journal, January 1992

  • Wei, Yi; Wu, Jin
  • Journal of Geophysical Research, Vol. 97, Issue C4
  • DOI: 10.1029/91JC02820

Statistical Mechanics of Multilayer Sorption: 2. Systems Containing Multiple Solutes
journal, January 2012

  • Dutcher, Cari S.; Ge, Xinlei; Wexler, Anthony S.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 2
  • DOI: 10.1021/jp2084154

Lipids in aerosols from the tropical North Pacific: Temporal variability
journal, January 1982

  • Gagosian, Robert B.; Zafiriou, Oliver C.; Peltzer, Edward T.
  • Journal of Geophysical Research, Vol. 87, Issue C13
  • DOI: 10.1029/JC087iC13p11133

Oceanic Primary Production: Estimation by Remote Sensing at Local and Regional Scales
journal, September 1988

Film slicks on the sea surface and some mechanisms of their formation
journal, January 1992

  • Ermakov, S. A.; Salashin, S. G.; Panchenko, A. R.
  • Dynamics of Atmospheres and Oceans, Vol. 16, Issue 3-4
  • DOI: 10.1016/0377-0265(92)90010-Q

Molecular indicators of diagenetic status in marine organic matter
journal, December 1997

Stability of stearic acid monolayers on Artificial Sea Water
journal, August 2012

  • Brzozowska, A. M.; Duits, M. H. G.; Mugele, F.
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 407
  • DOI: 10.1016/j.colsurfa.2012.04.055

Adsorption of Hydrophobically Modified Starch at Oil/Water Interfaces during Emulsification
journal, October 2006

  • Nilsson, Lars; Bergenståhl, Björn
  • Langmuir, Vol. 22, Issue 21
  • DOI: 10.1021/la060870f

Surfactants and submicron sea spray generation
journal, January 2006

  • Sellegri, K.; O'Dowd, C. D.; Yoon, Y. J.
  • Journal of Geophysical Research, Vol. 111, Issue D22
  • DOI: 10.1029/2005JD006658
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