Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework

Rangwani, Sean; Howarth, Ashlee J.; DeStefano, Matthew R.; Malliakas, Christos D.; Platero-Prats, Ana E.; Chapman, Karena W.; Farha, Omar K.

doi:10.1016/j.poly.2018.05.021

Title: Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework

Journal Article · 26 May 2018 · Polyhedron

DOI: https://doi.org/10.1016/j.poly.2018.05.021 · OSTI ID:1474406

Rangwani, Sean ^[1]; Howarth, Ashlee J. ^[2]; DeStefano, Matthew R. ^[1]; Malliakas, Christos D. ^[1]; Platero-Prats, Ana E. ^[3]; Chapman, Karena W. ^[3]; Farha, Omar K. ^[4]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; Concordia Univ., Montreal, QC (Canada). Dept. of Chemistry and Biochemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS) and X-ray Science Division
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry and Faculty of Science

Here, the adsorption and removal of Sb(OH)₆^- from water using the water stable Zr₆-based MOF, NU-1000, is explored. The adsorption capacity and uptake time of Sb(OH)₆- in NU-1000 is measured at varying concentrations to determine an overall maximum adsorption capacity of 260 mg of Sb(OH)₆^- per g of MOF, corresponding to 2.5 Sb(OH)₆^- per node of NU-1000 and exhibiting the highest adsorption capacity of any material reported to date for Sb(V) removal. Differential pair distribution function (dPDF) analysis of total X-ray scattering data reveals that Sb(OH)₆^- interacts in an η₂μ₂ fashion with the Zr₆-node of NU-1000, and that as the amount of Sb(OH)₆^- adsorbed increases, the interaction between the analyte and the node becomes stronger. Post-adsorption characterization shows that NU-1000 remains stable throughout the adsorption process.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; Electric Power Research Inst. (EPRI), Palo Alto, CA (United States)

Grant/Contract Number:: AC02-06CH11357; AC02- 06CH11357

OSTI ID:: 1474406

Alternate ID(s):: OSTI ID: 1562992

Journal Information:: Polyhedron, Vol. 151, Issue C; ISSN 0277-5387

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 36 works

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