Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework

doi:10.1016/j.poly.2018.05.021

Title: Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework

Abstract

Here, the adsorption and removal of Sb(OH)₆^- from water using the water stable Zr₆-based MOF, NU-1000, is explored. The adsorption capacity and uptake time of Sb(OH)₆- in NU-1000 is measured at varying concentrations to determine an overall maximum adsorption capacity of 260 mg of Sb(OH)₆^- per g of MOF, corresponding to 2.5 Sb(OH)₆^- per node of NU-1000 and exhibiting the highest adsorption capacity of any material reported to date for Sb(V) removal. Differential pair distribution function (dPDF) analysis of total X-ray scattering data reveals that Sb(OH)₆^- interacts in an η₂μ₂ fashion with the Zr₆-node of NU-1000, and that as the amount of Sb(OH)₆^- adsorbed increases, the interaction between the analyte and the node becomes stronger. Post-adsorption characterization shows that NU-1000 remains stable throughout the adsorption process.

Authors:

Rangwani, Sean ^[1]; Howarth, Ashlee J. ^[2]; DeStefano, Matthew R. ^[1]; Malliakas, Christos D. ^[1]; Platero-Prats, Ana E. ^[3]; Chapman, Karena W. ^[3]; Farha, Omar K. ^[4]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; Concordia Univ., Montreal, QC (Canada). Dept. of Chemistry and Biochemistry
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS) and X-ray Science Division
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry; King Abdulaziz Univ., Jeddah (Saudi Arabia). Dept. of Chemistry and Faculty of Science

Publication Date:: 2018-05-26

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; Electric Power Research Inst. (EPRI), Palo Alto, CA (United States)

OSTI Identifier:: 1474406

Alternate Identifier(s):: OSTI ID: 1562992

Grant/Contract Number:: AC02-06CH11357; AC02- 06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Polyhedron

Additional Journal Information:: Journal Volume: 151; Journal Issue: C; Journal ID: ISSN 0277-5387

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Metal–organic framework; Adsorbent; Antimony; Wastewater; Nuclear

Citation Formats


                    Rangwani, Sean, Howarth, Ashlee J., DeStefano, Matthew R., Malliakas, Christos D., Platero-Prats, Ana E., Chapman, Karena W., and Farha, Omar K. Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework.  United States: N. p., 2018. 
        Web.  doi:10.1016/j.poly.2018.05.021.

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                    Rangwani, Sean, Howarth, Ashlee J., DeStefano, Matthew R., Malliakas, Christos D., Platero-Prats, Ana E., Chapman, Karena W., & Farha, Omar K. Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework.  United States.  doi:10.1016/j.poly.2018.05.021.

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                    Rangwani, Sean, Howarth, Ashlee J., DeStefano, Matthew R., Malliakas, Christos D., Platero-Prats, Ana E., Chapman, Karena W., and Farha, Omar K. Sat .  
        "Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework".  United States.  doi:10.1016/j.poly.2018.05.021.  https://www.osti.gov/servlets/purl/1474406.

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@article{osti_1474406,

  title        = {Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework},

  author       = {Rangwani, Sean and Howarth, Ashlee J. and DeStefano, Matthew R. and Malliakas, Christos D. and Platero-Prats, Ana E. and Chapman, Karena W. and Farha, Omar K.},

  abstractNote = {Here, the adsorption and removal of Sb(OH)6- from water using the water stable Zr6-based MOF, NU-1000, is explored. The adsorption capacity and uptake time of Sb(OH)6- in NU-1000 is measured at varying concentrations to determine an overall maximum adsorption capacity of 260 mg of Sb(OH)6- per g of MOF, corresponding to 2.5 Sb(OH)6- per node of NU-1000 and exhibiting the highest adsorption capacity of any material reported to date for Sb(V) removal. Differential pair distribution function (dPDF) analysis of total X-ray scattering data reveals that Sb(OH)6- interacts in an η2μ2 fashion with the Zr6-node of NU-1000, and that as the amount of Sb(OH)6- adsorbed increases, the interaction between the analyte and the node becomes stronger. Post-adsorption characterization shows that NU-1000 remains stable throughout the adsorption process.},

  doi          = {10.1016/j.poly.2018.05.021},

  journal      = {Polyhedron},

  number       = C,

  volume       = 151,

  place        = {United States},

  year         = {2018},

  month        = {5}

}

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Journal Article:

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DOI: 10.1016/j.poly.2018.05.021

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Cited by: 4 works

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Figures / Tables:

Figure 1: Structure of (a) NU-1000; (b) the eight-connected Zr₆ metal node of NU-1000; and (c) the tetratopic pyrene-based linker, 1,3,6,8-tetrakis(p-benzoate)pyrene, of NU-1000.

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Works referencing / citing this record:

Efficient extraction of inorganic selenium from water by a Zr metal–organic framework: investigation of volumetric uptake capacity and binding motifs
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RSC Advances, Vol. 9, Issue 59
DOI: 10.1039/c9ra06879a

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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

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Title: Adsorptive removal of Sb(V) from water using a mesoporous Zr-based metal–organic framework

Abstract

Citation Formats

Figures / Tables:

Efficient extraction of inorganic selenium from water by a Zr metal–organic framework: investigation of volumetric uptake capacity and binding motifs journal, January 2018

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Recent Progress in the Removal of Heavy Metal Ions from Water Using Metal‐Organic Frameworks journal, January 2020

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journal, January 2018

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