Role of sterics in phosphine-ligated gold clusters

Parrish, Katherine A.; King, Mary; Ligare, Marshall R.; Johnson, Grant E.; Hernández, Heriberto

doi:10.1039/C8CP04961K

Title: Role of sterics in phosphine-ligated gold clusters

Journal Article · 23 January 2019 · Physical Chemistry Chemical Physics. PCCP

DOI: https://doi.org/10.1039/C8CP04961K · OSTI ID:1474188

Parrish, Katherine A. ^[1]; King, Mary ^[2];

^[3];

^[1]

Department of Chemistry, Grinnell College, Grinnell, USA
Department of Chemistry, University of Texas at Austin, Austin, USA
Physical Sciences Division, Pacific Northwest National Laboratory, Richland, USA

This study examined the solution-phase exchange reactions of triphenylphosphine (PPh ₃ ) ligands on Au ₈ L ₇ ²⁺ (L = PPh ₃ ) gold clusters with three different tolyl ligands using electrospray ionization mass spectrometry to provide insight into how steric differences in the phosphines influence the extent of ligand exchange and the stability of the resulting mixed-phosphine clusters.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Office of Workforce Development for Teachers & Scientists (WDTS)

OSTI ID:: 1474188

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 4 Vol. 21; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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