Room-Temperature Phototransistor with Negative Photoresponsivity of 108 A W-1 Using Fullerene-Sensitized Aligned Carbon Nanotubes

Bergemann, Kevin; Léonard, François

doi:10.1002/smll.201802806

Title: Room-Temperature Phototransistor with Negative Photoresponsivity of 10⁸ A W^-1 Using Fullerene-Sensitized Aligned Carbon Nanotubes

Journal Article · 23 September 2018 · Small

DOI: https://doi.org/10.1002/smll.201802806 · OSTI ID:1474080

Bergemann, Kevin ^[1];

^[1]

Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Detection of low intensity light down to a few photons requires photodetectors with high gain. In this paper, a new photodetector is reported based on C₆₀-sensitized aligned carbon nanotube (CNT) transistors with an extremely high responsivity of 10⁸ A W^-1 (gain > 10⁸) in the ultraviolet and visible range, and 720 A W^-1 (gain = 940) in the infrared range. In contrast to most sensitized phototransistors that operate on the photogating effect, the new photodetector operates on the modulation of the electrons scattering in the CNTs, leading to negative photoconductivity. Comparison with similar photodetectors using random CNT networks shows the benefit of using aligned CNTs. Finally, at room temperature, the aligned CNT photodetectors are demonstrated to detect a few tens of photons per CNT.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); Defense Advanced Research Projects Agency (DARPA) (United States)

Grant/Contract Number:: NA0003525

OSTI ID:: 1474080

Report Number(s):: SAND--2018-10184J; 667943

Journal Information:: Small, Journal Name: Small Journal Issue: 42 Vol. 14; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (49)

Influence of defects on nanotube transistor performance Neophytou, Neophytos; Kienle, Diego; Polizzi, Eric Applied Physics Letters, Vol. 88, Issue 24 https://doi.org/10.1063/1.2211932	journal	June 2006
Dose-Controlled, Floating Evaporative Self-assembly and Alignment of Semiconducting Carbon Nanotubes from Organic Solvents Joo, Yongho; Brady, Gerald J.; Arnold, Michael S. Langmuir, Vol. 30, Issue 12 https://doi.org/10.1021/la500162x	journal	March 2014
Uncooled Carbon Nanotube Photodetectors He, Xiaowei; Leonard, Francois; Kono, Junichiro arXiv https://doi.org/10.48550/arxiv.1505.02702	text	January 2015
Hybrid 2D-0D MoS ₂ -PbS Quantum Dot Photodetectors Kufer, Dominik; Nikitskiy, Ivan; Lasanta, Tania Advanced Materials, Vol. 27, Issue 1 https://doi.org/10.1002/adma.201402471	journal	November 2014
Significant Enhancement of Infrared Photodetector Sensitivity Using a Semiconducting Single-Walled Carbon Nanotube/C ₆₀ Phototransistor Park, Steve; Kim, Soo Jin; Nam, Ji Hyun Advanced Materials, Vol. 27, Issue 4 https://doi.org/10.1002/adma.201404544	journal	December 2014
Fundamental limits to single-photon detection determined by quantum coherence and backaction Young, Steve M.; Sarovar, Mohan; Léonard, François Physical Review A, Vol. 97, Issue 3 https://doi.org/10.1103/PhysRevA.97.033836	journal	March 2018
Carbon Nanotube Terahertz Detector He, Xiaowei; Fujimura, Naoki; Lloyd, J. Meagan Nano Letters, Vol. 14, Issue 7 https://doi.org/10.1021/nl5012678	journal	June 2014
Hysteresis Caused by Water Molecules in Carbon Nanotube Field-Effect Transistors Kim, Woong; Javey, Ali; Vermesh, Ophir Nano Letters, Vol. 3, Issue 2, p. 193-198 https://doi.org/10.1021/nl0259232	journal	February 2003
Photoinduced oxygen release and persistent photoconductivity in ZnO nanowires Bao, Jiming; Shalish, Ilan; Su, Zhihua Nanoscale Research Letters, Vol. 6, Issue 1 https://doi.org/10.1186/1556-276X-6-404	journal	January 2011
1∕f noise in single-walled carbon nanotube devices Snow, E. S.; Novak, J. P.; Lay, M. D. Applied Physics Letters, Vol. 85, Issue 18 https://doi.org/10.1063/1.1812838	journal	November 2004
Label-free single-molecule detection of DNA-hybridization kinetics with a carbon nanotube field-effect transistor Sorgenfrei, Sebastian; Chiu, Chien-yang; Gonzalez, Ruben L. Nature Nanotechnology, Vol. 6, Issue 2 https://doi.org/10.1038/nnano.2010.275	journal	January 2011
Wide-spectral/dynamic-range skin-compatible phototransistors enabled by floated heterojunction structures with surface functionalized SWCNTs and amorphous oxide semiconductors Hwang, Insik; Kim, Jaehyun; Lee, Minkyung Nanoscale, Vol. 9, Issue 43 https://doi.org/10.1039/C7NR05729F	journal	January 2017
External Quantum Efficiency Above 100% in a Singlet-Exciton-Fission-Based Organic Photovoltaic Cell Congreve, D. N.; Lee, J.; Thompson, N. J. Science, Vol. 340, Issue 6130 https://doi.org/10.1126/science.1232994	journal	April 2013
Singlets lead to photogeneration in C 60 -based organic heterojunctions Bergemann, Kevin J.; Liu, Xiao; Panda, Anurag Physical Review B, Vol. 92, Issue 3 https://doi.org/10.1103/PhysRevB.92.035408	journal	July 2015
Probing the Diameter Limit of Single Walled Carbon Nanotubes in SWCNT: Fullerene Solar Cells Pfohl, Moritz; Glaser, Konstantin; Graf, Arko Advanced Energy Materials, Vol. 6, Issue 21 https://doi.org/10.1002/aenm.201600890	journal	August 2016
Adsorption and desorption of oxygen probed from ZnO nanowire films by photocurrent measurements Li, Q. H.; Gao, T.; Wang, Y. G. Applied Physics Letters, Vol. 86, Issue 12 https://doi.org/10.1063/1.1883711	journal	March 2005
Single-ion adsorption and switching in carbon nanotubes Bushmaker, Adam W.; Oklejas, Vanessa; Walker, Don Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10475	journal	January 2016
Properties of short channel ballistic carbon nanotube transistors with ohmic contacts Léonard, François; Stewart, Derek A. Nanotechnology, Vol. 17, Issue 18 https://doi.org/10.1088/0957-4484/17/18/029	journal	August 2006
Crosstalk between nanotube devices: contact and channel effects Léonard, François Nanotechnology, Vol. 17, Issue 9 https://doi.org/10.1088/0957-4484/17/9/051	journal	April 2006
Broad Spectral Response Using Carbon Nanotube/Organic Semiconductor/C ₆₀ Photodetectors Arnold, Michael S.; Zimmerman, Jeramy D.; Renshaw, Christopher K. Nano Letters, Vol. 9, Issue 9 https://doi.org/10.1021/nl901637u	journal	September 2009
Optically Modulated Conduction in Chromophore-Functionalized Single-Wall Carbon Nanotubes Simmons, J. M.; In, I.; Campbell, V. E. Physical Review Letters, Vol. 98, Issue 8 https://doi.org/10.1103/PhysRevLett.98.086802	journal	February 2007
Quasi-ballistic carbon nanotube array transistors with current density exceeding Si and GaAs Brady, Gerald J.; Way, Austin J.; Safron, Nathaniel S. Science Advances, Vol. 2, Issue 9 https://doi.org/10.1126/sciadv.1601240	journal	September 2016
Electronically interacting single wall carbon nanotube–porphyrin nanohybrids Rahman, G. M. Aminur; Guldi, Dirk M.; Campidelli, Stéphane J. Mater. Chem., Vol. 16, Issue 1 https://doi.org/10.1039/b515394h	journal	January 2006
Fundamental Limits to Single-Photon Detection Determined by Quantum Coherence and Backaction Young, Steve M.; Sarovar, Mohan; Léonard, François arXiv https://doi.org/10.48550/arxiv.1710.09512	text	January 2017
Color Detection Using Chromophore-Nanotube Hybrid Devices Zhou, Xinjian; Zifer, Thomas; Wong, Bryan M. Nano Letters, Vol. 9, Issue 3 https://doi.org/10.1021/nl8032922	journal	March 2009
Uncooled Carbon Nanotube Photodetectors He, Xiaowei; Léonard, François; Kono, Junichiro Advanced Optical Materials, Vol. 3, Issue 8 https://doi.org/10.1002/adom.201500237	journal	July 2015
Toward Large Arrays of Multiplex Functionalized Carbon Nanotube Sensors for Highly Sensitive and Selective Molecular Detection Qi, Pengfei; Vermesh, Ophir; Grecu, Mihai Nano Letters, Vol. 3, Issue 3 https://doi.org/10.1021/nl034010k	journal	March 2003
High-Sensitivity Bolometers from Self-Oriented Single-Walled Carbon Nanotube Composites Vera-Reveles, Gustavo; Simmons, Trevor J.; Bravo-Sánchez, Mariela ACS Applied Materials & Interfaces, Vol. 3, Issue 8 https://doi.org/10.1021/am2007036	journal	June 2011
High performance transistors via aligned polyfluorene-sorted carbon nanotubes Brady, Gerald J.; Joo, Yongho; Singha Roy, Susmit Applied Physics Letters, Vol. 104, Issue 8, Article No. 083107 https://doi.org/10.1063/1.4866577	journal	February 2014
Functionalization of Single-Wall Carbon Nanotubes with Chromophores of Opposite Internal Dipole Orientation Zhao, Yuanchun; Huang, Changshui; Kim, Myungwoong ACS Applied Materials & Interfaces, Vol. 5, Issue 19 https://doi.org/10.1021/am4024753	journal	September 2013
Random-Telegraph-Signal Noise and Device Variability in Ballistic Nanotube Transistors Wang, Neng-Ping; Heinze, S.; Tersoff, J. Nano Letters, Vol. 7, Issue 4 https://doi.org/10.1021/nl062742h	journal	April 2007
Contact resistance between carbon nanotubes Buldum, Alper; Lu, Jian Ping Physical Review B, Vol. 63, Issue 16 https://doi.org/10.1103/PhysRevB.63.161403	journal	April 2001
Effects of oxygen on the electron transport properties of carbon nanotubes: Ultraviolet desorption and thermally induced processes Shim, Moonsub; Back, Ju Hee; Ozel, Taner Physical Review B, Vol. 71, Issue 20 https://doi.org/10.1103/PhysRevB.71.205411	journal	May 2005
Functionalization of Single-Wall Carbon Nanotubes with Chromophores of Opposite Internal Dipole Orientation Zhao, Yuanchun; Huang, Changshui; Kim, Myungwoong arXiv https://doi.org/10.48550/arxiv.1312.6301	text	January 2013
Dissociating Excitons Photogenerated in Semiconducting Carbon Nanotubes at Polymeric Photovoltaic Heterojunction Interfaces Bindl, Dominick J.; Safron, Nathaniel S.; Arnold, Michael S. ACS Nano, Vol. 4, Issue 10 https://doi.org/10.1021/nn1012397	journal	October 2010
Charge-injection-induced dynamic screening and origin of hysteresis in field-modulated transport in single-wall carbon nanotubes Vijayaraghavan, Aravind; Kar, Swastik; Soldano, Caterina Applied Physics Letters, Vol. 89, Issue 16 https://doi.org/10.1063/1.2362586	journal	October 2006
The Role of the Oxygen/Water Redox Couple in Suppressing Electron Conduction in Field-Effect Transistors Aguirre, Carla M.; Levesque, Pierre L.; Paillet, Matthieu Advanced Materials, Vol. 21, Issue 30 https://doi.org/10.1002/adma.200900550	journal	August 2009
Achieving High Mid-IR Bolometric Responsivity for Anisotropic Composite Materials from Carbon Nanotubes and Polymers Glamazda, Alexander Y.; Karachevtsev, Victor. A.; Euler, William B. Advanced Functional Materials, Vol. 22, Issue 10 https://doi.org/10.1002/adfm.201102597	journal	February 2012
Noise in carbon nanotube field effect transistor Liu, Fei; Wang, Kang L.; Zhang, Daihua Applied Physics Letters, Vol. 89, Issue 6 https://doi.org/10.1063/1.2335777	journal	August 2006
Electronically interacting single wall carbon nanotube–porphyrin nanohybrids Rahman, G. M. Aminur; Guldi, Dirk M.; Campidelli, Stéphane J. Mater. Chem., Vol. 16, Issue 1 https://doi.org/10.1039/B515394H	journal	January 2006
1/f noise in carbon nanotubes Collins, Philip G.; Fuhrer, M. S.; Zettl, A. Applied Physics Letters, Vol. 76, Issue 7 https://doi.org/10.1063/1.125621	journal	February 2000
Contact resistance between carbon nanotubes Ping, Lu, Jian; Alper, Buldum, The University of North Carolina at Chapel Hill University Libraries https://doi.org/10.17615/fhpw-sy58	text	January 2001
Photoinduced conductivity changes in carbon nanotube transistors Shim, Moonsub; Siddons, Giles P. Applied Physics Letters, Vol. 83, Issue 17 https://doi.org/10.1063/1.1622450	journal	October 2003
Efficiently Harvesting Excitons from Electronic Type-Controlled Semiconducting Carbon Nanotube Films Bindl, Dominick J.; Wu, Meng-Yin; Prehn, Frederick C. Nano Letters, Vol. 11, Issue 2 https://doi.org/10.1021/nl1031343	journal	February 2011
Single walled carbon nanotube/Si heterojunctions for high responsivity photodetectors Salvato, M.; Scagliotti, M.; De Crescenzi, M. Nanotechnology, Vol. 28, Issue 43 https://doi.org/10.1088/1361-6528/aa8797	journal	September 2017
Photothermovoltaic effect in carbon nanotubes: En route toward junctionless infrared photocells and light sensors Omari, M.; Kouklin, N. A. Applied Physics Letters, Vol. 98, Issue 24 https://doi.org/10.1063/1.3597410	journal	June 2011
Bioinspired Detection of Light Using a Porphyrin-Sensitized Single-Wall Nanotube Field Effect Transistor Hecht, David S.; Ramirez, Robert J. A.; Briman, Mikhail Nano Letters, Vol. 6, Issue 9 https://doi.org/10.1021/nl061231s	journal	September 2006
Directing and Sensing Changes in Molecular Conformation on Individual Carbon Nanotube Field Effect Transistors Guo, Xuefeng; Huang, Limin; O'Brien, Stephen Journal of the American Chemical Society, Vol. 127, Issue 43 https://doi.org/10.1021/ja054335y	journal	November 2005
Polyfluorene-Sorted, Carbon Nanotube Array Field-Effect Transistors with Increased Current Density and High On/Off Ratio Brady, Gerald J.; Joo, Yongho; Wu, Meng-Yin ACS Nano, Vol. 8, Issue 11, p. 11614-11621 https://doi.org/10.1021/nn5048734	journal	November 2014

Cited By (4)

Recent Progress in Organic Phototransistors: Semiconductor Materials, Device Structures and Optoelectronic Applications Huang, Xianhui; Ji, Deyang; Fuchs, Harald ChemPhotoChem, Vol. 4, Issue 1 https://doi.org/10.1002/cptc.201900287	journal	August 2019
Direct measurement of the surface energy of single-walled carbon nanotubes through atomic force microscopy Li, Hu; Liu, Jiangwei; Papadakis, Raffaello Journal of Applied Physics, Vol. 126, Issue 6 https://doi.org/10.1063/1.5108935	journal	August 2019
Recent Progress in Organic Phototransistors: Semiconductor Materials, Device Structures and Optoelectronic Applications Huang, Xianhui; Ji, Deyang; Fuchs, Harald ChemPhotoChem, Vol. 4, Issue 1 https://doi.org/10.1002/cptc.201900198	journal	August 2019
Visible- and solar-blind photodetectors using AlGaN high electron mobility transistors with a nanodot-based floating gate Armstrong, Andrew M.; Klein, Brianna A.; Allerman, Andrew A. Photonics Research, Vol. 7, Issue 6 https://doi.org/10.1364/prj.7.000b24	journal	January 2019

Similar Records

Ultrathin and Ultrasensitive Direct X‐ray Detector Based on Heterojunction Phototransistors

Journal Article · 2021 · Advanced Materials · OSTI ID:1805099

Gao, Yuanhong; Ge, Yongshuai; Wang, Xinwei; +13 more

Evidence of minority carrier injection efficiency >90% in an epitaxial graphene/SiC Schottky emitter bipolar junction phototransistor for ultraviolet detection

Journal Article · 2016 · Applied Physics Letters · OSTI ID:22489375

Chava, Venkata S. N.,; Omar, Sabih U.; Brown, Gabriel; +4 more

One-directional thermal transport in densely aligned single-wall carbon nanotube films

Journal Article · 2019 · Applied Physics Letters · OSTI ID:1800377

Yamaguchi, Shingi; Tsunekawa, Issei; Komatsu, Natsumi; +5 more

Related Subjects

47 OTHER INSTRUMENTATION
carbon nanotube
fullerene
gain
photodetector

Title: Room-Temperature Phototransistor with Negative Photoresponsivity of 108 A W-1 Using Fullerene-Sensitized Aligned Carbon Nanotubes

Citation Formats

References (49)

Cited By (4)

Similar Records

Related Subjects

Title: Room-Temperature Phototransistor with Negative Photoresponsivity of 10⁸ A W^-1 Using Fullerene-Sensitized Aligned Carbon Nanotubes