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Title: Nonstoichiometry, structure, and properties of Ba 1−x TiO y thin films

Abstract

Sometimes worse is better – variations in the chemistry of BaTiO 3 can have unexpected effects on properties.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1473987
Grant/Contract Number:  
AC02-05-CH11231: Materials Project program KC23; SC-0012375
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Name: Journal of Materials Chemistry C Journal Volume: 6 Journal Issue: 40; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Dasgupta, Arvind, Saremi, Sahar, Ruijuan, Xu, Dedon, Liv R., Pandya, Shishir, Damodaran, Anoop R., and Martin, Lane W. Nonstoichiometry, structure, and properties of Ba 1−x TiO y thin films. United Kingdom: N. p., 2018. Web. doi:10.1039/C8TC02725K.
Dasgupta, Arvind, Saremi, Sahar, Ruijuan, Xu, Dedon, Liv R., Pandya, Shishir, Damodaran, Anoop R., & Martin, Lane W. Nonstoichiometry, structure, and properties of Ba 1−x TiO y thin films. United Kingdom. doi:10.1039/C8TC02725K.
Dasgupta, Arvind, Saremi, Sahar, Ruijuan, Xu, Dedon, Liv R., Pandya, Shishir, Damodaran, Anoop R., and Martin, Lane W. Thu . "Nonstoichiometry, structure, and properties of Ba 1−x TiO y thin films". United Kingdom. doi:10.1039/C8TC02725K.
@article{osti_1473987,
title = {Nonstoichiometry, structure, and properties of Ba 1−x TiO y thin films},
author = {Dasgupta, Arvind and Saremi, Sahar and Ruijuan, Xu and Dedon, Liv R. and Pandya, Shishir and Damodaran, Anoop R. and Martin, Lane W.},
abstractNote = {Sometimes worse is better – variations in the chemistry of BaTiO 3 can have unexpected effects on properties.},
doi = {10.1039/C8TC02725K},
journal = {Journal of Materials Chemistry C},
number = 40,
volume = 6,
place = {United Kingdom},
year = {2018},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/C8TC02725K

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Works referenced in this record:

Strong ferroelectric domain-wall pinning in BiFeO3 ceramics
journal, October 2010

  • Rojac, Tadej; Kosec, Marija; Budic, Bojan
  • Journal of Applied Physics, Vol. 108, Issue 7
  • DOI: 10.1063/1.3490249

Trap Density Determination by Space‐Charge‐Limited Currents
journal, May 1962

  • Bube, Richard H.
  • Journal of Applied Physics, Vol. 33, Issue 5
  • DOI: 10.1063/1.1728818

Enhanced Piezoelectric Property of Barium Titanate Single Crystals with Engineered Domain Configurations
journal, September 1999

  • Wada, Satoshi; Suzuki, Shingo; Noma, Tatsuo
  • Japanese Journal of Applied Physics, Vol. 38, Issue Part 1, No. 9B
  • DOI: 10.1143/JJAP.38.5505

Reorientation of (MnTi″−VO••)× defect dipoles in acceptor-modified BaTiO3 single crystals: An electron paramagnetic resonance study
journal, November 2008

  • Zhang, Lixue; Erdem, Emre; Ren, Xiaobing
  • Applied Physics Letters, Vol. 93, Issue 20
  • DOI: 10.1063/1.3006327

Role of charged defects on the electrical and electromechanical properties of rhombohedral Pb ( Zr , Ti ) O 3 with oxygen octahedra tilts
journal, January 2016


Identification of A - and B -Site Cation Vacancy Defects in Perovskite Oxide Thin Films
journal, November 2010


Defect-Dipole Formation in Copper-Doped PbTiO 3 Ferroelectrics
journal, March 2008


Ferroelectricity in Pb 1+δ ZrO 3 Thin Films
journal, July 2017


Colossal Permittivity in Ultrafine Grain Size BaTiO3–x and Ba0.95La0.05TiO3–x Materials
journal, February 2008

  • Guillemet-Fritsch, S.; Valdez-Nava, Z.; Tenailleau, C.
  • Advanced Materials, Vol. 20, Issue 3
  • DOI: 10.1002/adma.200700245

Electronic Transport and Ferroelectric Switching in Ion-Bombarded, Defect-Engineered BiFeO 3 Thin Films
journal, November 2017

  • Saremi, Sahar; Xu, Ruijuan; Dedon, Liv R.
  • Advanced Materials Interfaces, Vol. 5, Issue 3
  • DOI: 10.1002/admi.201700991

Transition of Compensating Defect Mode in Niobium-Doped Barium Titanate
journal, March 1994


Enhanced Electrical Resistivity and Properties via Ion Bombardment of Ferroelectric Thin Films
journal, October 2016


�ber die magnetische Nachwirkung
journal, May 1935


Modeling the electrical conductivity in BaTiO3 on the basis of first-principles calculations
journal, August 2008

  • Erhart, Paul; Albe, Karsten
  • Journal of Applied Physics, Vol. 104, Issue 4
  • DOI: 10.1063/1.2956327

Point defect complexes and their association energies in acceptor-doped oxides
journal, November 1982


Defect Chemistry of Donor-Doped BaTiO3
journal, April 1984


Electrical and charge storage characteristics of the tantalum oxide-silicon dioxide device
journal, November 1978

  • Angle, R. L.; Talley, H. E.
  • IEEE Transactions on Electron Devices, Vol. 25, Issue 11
  • DOI: 10.1109/T-ED.1978.19266

Electrical and structural characteristics of lanthanum-doped barium titanate ceramics
journal, December 1999

  • Morrison, Finlay D.; Sinclair, Derek C.; West, Anthony R.
  • Journal of Applied Physics, Vol. 86, Issue 11
  • DOI: 10.1063/1.371698

Improved stoichiometry and misfit control in perovskite thin film formation at a critical fluence by pulsed laser deposition
journal, December 2005

  • Ohnishi, T.; Lippmaa, M.; Yamamoto, T.
  • Applied Physics Letters, Vol. 87, Issue 24
  • DOI: 10.1063/1.2146069

Enhancement of Ferroelectricity in Strained BaTiO3 Thin Films
journal, November 2004


Quantitative study of band structure in BaTiO3 particles with vacant ionic sites
journal, October 2016

  • Oshime, Norihiro; Kano, Jun; Ikeda, Naoshi
  • Journal of Applied Physics, Vol. 120, Issue 15
  • DOI: 10.1063/1.4964803

Imprint Control of BaTiO 3 Thin Films via Chemically Induced Surface Polarization Pinning
journal, March 2016


Thermodynamics of mono- and di-vacancies in barium titanate
journal, October 2007

  • Erhart, Paul; Albe, Karsten
  • Journal of Applied Physics, Vol. 102, Issue 8
  • DOI: 10.1063/1.2801011

Base-Metal Electrode-Multilayer Ceramic Capacitors: Past, Present and Future Perspectives
journal, January 2003

  • Kishi, Hiroshi; Mizuno, Youichi; Chazono, Hirokazu
  • Japanese Journal of Applied Physics, Vol. 42, Issue Part 1, No. 1
  • DOI: 10.1143/JJAP.42.1

Investigation of Rare-Earth Doped Barium Titanate
journal, April 1961


Origin of colossal permittivity in BaTiO 3 via broadband dielectric spectroscopy
journal, January 2013

  • Han, Hyuksu; Voisin, Christophe; Guillemet-Fritsch, Sophie
  • Journal of Applied Physics, Vol. 113, Issue 2
  • DOI: 10.1063/1.4774099

Nonstoichiometry, Structure, and Properties of BiFeO 3 Films
journal, August 2016


Room-temperature ferroelectricity in strained SrTiO3
journal, August 2004

  • Haeni, J. H.; Irvin, P.; Chang, W.
  • Nature, Vol. 430, Issue 7001, p. 758-761
  • DOI: 10.1038/nature02773

The volume of formation of Schottky defects in ionic crystals
journal, February 1981


Internal bias in ferroelectric ceramics: Origin and time dependence
journal, November 1988


First-order reversal-curve diagrams and reversible magnetization
journal, September 2003


Deep‐level transient spectroscopy: A new method to characterize traps in semiconductors
journal, July 1974


Defects and charge transport in perovskite ferroelectrics
journal, October 1996


Defect ordering and defect–domain-wall interactions in PbTiO 3 : A first-principles study
journal, December 2013


Sintering of PZT Ceramics: I, Atmosphere Control
journal, April 1983


The energy and elastic dipole tensor of defects in ionic crystals calculated by the supercell method
journal, February 1985


Preisach modeling of ferroelectric pinched loops
journal, December 2000

  • Robert, G.; Damjanovic, D.; Setter, N.
  • Applied Physics Letters, Vol. 77, Issue 26
  • DOI: 10.1063/1.1332824

Defect Chemistry of Relaxor Ferroelectrics and the Implications for Dielectric Degradation
journal, December 1989


Nonstoichiometry in Undoped BaTiO3
journal, September 1981


The energy of formation of Schottky defects in ionic crystals
journal, October 1967


Improved leakage and ferroelectric properties of Mn and Ti codoped BiFeO3 thin films
journal, March 2009

  • Kawae, T.; Terauchi, Y.; Tsuda, H.
  • Applied Physics Letters, Vol. 94, Issue 11
  • DOI: 10.1063/1.3098408

A model for fatigue in ferroelectric perovskite thin films
journal, February 2000

  • Dawber, Matthew; Scott, J. F.
  • Applied Physics Letters, Vol. 76, Issue 8
  • DOI: 10.1063/1.125938

Computer modelling of barium titanate
journal, January 1983


Defect studies of doped and undoped barium titanate using computer simulation techniques
journal, January 1986


Electrical after-effects in Pb(Ti, Zr)O3 ceramics
journal, January 1977


Effect of Growth Induced (Non)Stoichiometry on the Structure, Dielectric Response, and Thermal Conductivity of SrTiO 3 Thin Films
journal, December 2011

  • Breckenfeld, E.; Wilson, R.; Karthik, J.
  • Chemistry of Materials, Vol. 24, Issue 2
  • DOI: 10.1021/cm203042q

Controlled cation stoichiometry in pulsed laser deposition-grown BaTiO 3 epitaxial thin films with laser fluence
journal, August 2011

  • Kan, Daisuke; Shimakawa, Yuichi
  • Applied Physics Letters, Vol. 99, Issue 8
  • DOI: 10.1063/1.3628461

First-order reversal curve diagrams: A new tool for characterizing the magnetic properties of natural samples
journal, December 2000

  • Roberts, Andrew P.; Pike, Christopher R.; Verosub, Kenneth L.
  • Journal of Geophysical Research: Solid Earth, Vol. 105, Issue B12
  • DOI: 10.1029/2000JB900326

Enhancement of Ferroelectric Curie Temperature in BaTiO 3 Films via Strain-Induced Defect Dipole Alignment
journal, August 2014

  • Damodaran, Anoop R.; Breckenfeld, Eric; Chen, Zuhuang
  • Advanced Materials, Vol. 26, Issue 36
  • DOI: 10.1002/adma.201400254

Preisach model for the simulation of ferroelectric capacitors
journal, March 2001

  • Bartic, Andrei T.; Wouters, Dirk J.; Maes, Herman E.
  • Journal of Applied Physics, Vol. 89, Issue 6
  • DOI: 10.1063/1.1335639

Epitaxial Ferroelectric Heterostructures Fabricated by Selective Area Epitaxy of SrRuO3 Using an MgO Mask
journal, February 2012

  • Karthik, J.; Damodaran, Anoop R.; Martin, Lane W.
  • Advanced Materials, Vol. 24, Issue 12
  • DOI: 10.1002/adma.201104697

Micron-Scaled Spectral-Resolved Cathodoluminescence of Grains in Bariumtitanate Ceramics
journal, September 1983


A study of the effects of process variables on the properties of PZT films produced by a single-layer sol-gel technique
journal, May 1995

  • Tu, Y. L.; Milne, S. J.
  • Journal of Materials Science, Vol. 30, Issue 10
  • DOI: 10.1007/BF00362126

Grain size effect on the dielectric nonlinearity of BaTiO3 ceramics
journal, May 2010

  • Fujii, Ichiro; Ugorek, Michael; Trolier-McKinstry, Susan
  • Journal of Applied Physics, Vol. 107, Issue 10
  • DOI: 10.1063/1.3428423