Intermediate temperature fuel cells via an ion-pair coordinated polymer electrolyte

Lee, Kwan-Soo; Maurya, Sandip; Kim, Yu Seung; Kreller, Cortney R.; Wilson, Mahlon S.; Larsen, Dennis; Elangovan, S. Elango; Mukundan, Rangachary

doi:10.1039/C7EE03595K

Title: Intermediate temperature fuel cells via an ion-pair coordinated polymer electrolyte

Journal Article · 01 March 2018 · Energy & Environmental Science

DOI: https://doi.org/10.1039/C7EE03595K · OSTI ID:1473810

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^[1]; Larsen, Dennis ^[2]; Elangovan, S. Elango ^[2];

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Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Ceramatec, Inc., Salt Lake City, UT (United States)

Fuel cells are attractive devices that convert chemical energy into electricity through the direct electrochemical reaction of hydrogen and oxygen. Intermediate temperature fuel cells operated at 200–300°C can simplify water and thermal managements, enable the use of non-precious or low-loading precious metal catalysts and provide insensitivity toward fuel and air impurities such as carbon monoxide. However, the performance of current intermediate temperature fuel cells is poor due to a lack of highly-conductive membrane electrolytes and optimal electrodes designed for these fuel cells. We demonstrate high-performing intermediate temperature fuel cells that use SnP₂O₇–polymer composite membranes and a quaternary ammonium-biphosphate ion-pair coordinated polymer electrolyte in the electrodes. The peak power density of the fuel cell under H₂ and O₂ reached 870 mW cm^-2 at 240°C with minimal performance loss under exposure to 25% carbon monoxide.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E); USDOE National Nuclear Security Administration (NNSA)

Contributing Organization:: Univ. of Tennessee, Knoxville, TN (United States)

Grant/Contract Number:: AC52-06NA25396; AR0000314

OSTI ID:: 1473810

Report Number(s):: LA-UR--17-31199

Journal Information:: Energy & Environmental Science, Journal Name: Energy & Environmental Science Journal Issue: 4 Vol. 11; ISSN EESNBY; ISSN 1754-5692

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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