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Title: Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature

Abstract

We have performed high pressure-temperature Brillouin scattering measurements on single crystal hydrogen sulfide using externally heated diamond anvil cell techniques. The pressure dependences of the acoustic velocities, isothermal elastic constants, and moduli of single crystal hydrogen sulfide have been determined along four isotherms. Both elastic constants and moduli increase monotonously with pressure along each isotherm, while they show a decreased tendency with temperature elevated under the same pressure points. The experimental equation of state of single crystal hydrogen sulfide is obtained by fitting with a third-order Birch-Murnaghan and Tait equation. It is proposed that the effect of hydrogen bonds contributes to the unique tendency of elastic anisotropy in single crystal hydrogen sulfide. Through our work, we have extended the melting curve and phase diagram of hydrogen sulfide up to 12 GPa and 580 K.

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
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  1. Jilin Univ., Changchun (China). State Key Lab. of Superhard Materials
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1476093
Alternate Identifier(s):
OSTI ID: 1473737
Grant/Contract Number:  
AC02-06CH11357; FG02-94ER14466
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 124; Journal Issue: 12; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; Equations of state; Diamond anvil cells; Crystal structure; Elasticity; Acoustical properties; Light scattering; Brillouin spectroscopy; Phase transitions

Citation Formats

Zhou, Di, Huang, Xiaoli, Li, Xin, Yu, Hongyu, Li, Fangfei, Huang, Yanping, Lu, Mengya, Liang, Yongfu, Liu, Mingkun, Wu, Gang, Zhou, Qiang, Liu, Bingbing, and Cui, Tian. Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature. United States: N. p., 2018. Web. doi:10.1063/1.5040399.
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Zhou, Di, Huang, Xiaoli, Li, Xin, Yu, Hongyu, Li, Fangfei, Huang, Yanping, Lu, Mengya, Liang, Yongfu, Liu, Mingkun, Wu, Gang, Zhou, Qiang, Liu, Bingbing, & Cui, Tian. Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature. United States. https://doi.org/10.1063/1.5040399
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Zhou, Di, Huang, Xiaoli, Li, Xin, Yu, Hongyu, Li, Fangfei, Huang, Yanping, Lu, Mengya, Liang, Yongfu, Liu, Mingkun, Wu, Gang, Zhou, Qiang, Liu, Bingbing, and Cui, Tian. Fri . "Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature". United States. https://doi.org/10.1063/1.5040399. https://www.osti.gov/servlets/purl/1476093.
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@article{osti_1476093,
title = {Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature},
author = {Zhou, Di and Huang, Xiaoli and Li, Xin and Yu, Hongyu and Li, Fangfei and Huang, Yanping and Lu, Mengya and Liang, Yongfu and Liu, Mingkun and Wu, Gang and Zhou, Qiang and Liu, Bingbing and Cui, Tian},
abstractNote = {We have performed high pressure-temperature Brillouin scattering measurements on single crystal hydrogen sulfide using externally heated diamond anvil cell techniques. The pressure dependences of the acoustic velocities, isothermal elastic constants, and moduli of single crystal hydrogen sulfide have been determined along four isotherms. Both elastic constants and moduli increase monotonously with pressure along each isotherm, while they show a decreased tendency with temperature elevated under the same pressure points. The experimental equation of state of single crystal hydrogen sulfide is obtained by fitting with a third-order Birch-Murnaghan and Tait equation. It is proposed that the effect of hydrogen bonds contributes to the unique tendency of elastic anisotropy in single crystal hydrogen sulfide. Through our work, we have extended the melting curve and phase diagram of hydrogen sulfide up to 12 GPa and 580 K.},
doi = {10.1063/1.5040399},
journal = {Journal of Applied Physics},
number = 12,
volume = 124,
place = {United States},
year = {Fri Sep 28 00:00:00 EDT 2018},
month = {Fri Sep 28 00:00:00 EDT 2018}
}
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https://doi.org/10.1063/1.5040399
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Works referenced in this record:

Metal hydride materials for solid hydrogen storage: A review☆
journal, June 2007

Van Hove singularities and spectral smearing in high-temperature superconducting H 3 S
journal, March 2016

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Structure and Phase Transition in Solid Hydrogen and Deuterium Sulphides
journal, November 1969

  • SÁNdor, E.; Ogunade, S. O.
  • Nature, Vol. 224, Issue 5222
  • DOI: 10.1038/224905b0

Pressure-Induced Hydrogen Bonding Structure of D2S Phase I′
journal, July 2000

Brillouin scattering at high pressure: an overview
journal, January 2003

  • Polian, Alain
  • Journal of Raman Spectroscopy, Vol. 34, Issue 7-8
  • DOI: 10.1002/jrs.1031

Facilities for high-pressure research with the diamond anvil cell at GSECARS
journal, August 2005

  • Shen, Guoyin; Prakapenka, Vitali B.; Eng, Peter J.
  • Journal of Synchrotron Radiation, Vol. 12, Issue 5
  • DOI: 10.1107/S0909049505022442

Extended and accurate determination of the melting curves of argon, helium, ice ( H 2 O ) , and hydrogen ( H 2 )
journal, March 2000

  • Datchi, Frédéric; Loubeyre, Paul; LeToullec, René
  • Physical Review B, Vol. 61, Issue 10
  • DOI: 10.1103/PhysRevB.61.6535

The solid phases of deuterium sulphide by powder neutron diffraction
journal, January 1990

  • Cockcroft, Jeremy K.; Fitch, Andrew N.
  • Zeitschrift für Kristallographie - Crystalline Materials, Vol. 193, Issue 1-4
  • DOI: 10.1524/zkri.1990.193.14.1

Projector augmented-wave method
journal, December 1994

Quantum hydrogen-bond symmetrization in the superconducting hydrogen sulfide system
journal, March 2016

  • Errea, Ion; Calandra, Matteo; Pickard, Chris J.
  • Nature, Vol. 532, Issue 7597
  • DOI: 10.1038/nature17175

Pressure‐induced phase transition in solid hydrogen sulfide at 11 GPa
journal, August 1991

  • Shimizu, H.; Nakamichi, Y.; Sasaki, S.
  • The Journal of Chemical Physics, Vol. 95, Issue 3, p. 2036-2040
  • DOI: 10.1063/1.461002

Equations of state of ice VI and ice VII at high pressure and high temperature
journal, September 2014

  • Bezacier, Lucile; Journaux, Baptiste; Perrillat, Jean-Philippe
  • The Journal of Chemical Physics, Vol. 141, Issue 10
  • DOI: 10.1063/1.4894421

Synthesis and stability of hydrogen selenide compounds at high pressure
journal, November 2017

  • Pace, Edward J.; Binns, Jack; Peña Alvarez, Miriam
  • The Journal of Chemical Physics, Vol. 147, Issue 18
  • DOI: 10.1063/1.5004242

Development of low-temperature and high-pressure Brillouin scattering spectroscopy and its application to the solid I form of hydrogen sulphide
journal, October 2002

Pressure-temperature phase diagram of solid hydrogen sulfide determined by Raman spectroscopy
journal, April 1995

  • Shimizu, H.; Yamaguchi, H.; Sasaki, S.
  • Physical Review B, Vol. 51, Issue 14, p. 9391-9394
  • DOI: 10.1103/PhysRevB.51.9391

Brillouin scattering and x-ray diffraction of solid argon to 65 GPa and 700 K: Shear strength of argon at H P /H T
journal, September 2013

  • Marquardt, H.; Speziale, S.; Gleason, A.
  • Journal of Applied Physics, Vol. 114, Issue 9
  • DOI: 10.1063/1.4820578

Special points for Brillouin-zone integrations
journal, June 1976

  • Monkhorst, Hendrik J.; Pack, James D.
  • Physical Review B, Vol. 13, Issue 12, p. 5188-5192
  • DOI: 10.1103/PhysRevB.13.5188

Ab initio molecular dynamics for open-shell transition metals
journal, November 1993

Hydrogen bond symmetrization and superconducting phase of HBr and HCl under high pressure: An ab initio study
journal, August 2010

  • Duan, Defang; Tian, Fubo; He, Zhi
  • The Journal of Chemical Physics, Vol. 133, Issue 7
  • DOI: 10.1063/1.3471446

The metallization and superconductivity of dense hydrogen sulfide
journal, May 2014

  • Li, Yinwei; Hao, Jian; Liu, Hanyu
  • The Journal of Chemical Physics, Vol. 140, Issue 17
  • DOI: 10.1063/1.4874158

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Metric-tensor flexible-cell algorithm for isothermal–isobaric molecular dynamics simulations
journal, January 2001

  • Hernández, E.
  • The Journal of Chemical Physics, Vol. 115, Issue 22
  • DOI: 10.1063/1.1416867

Static Structure and Dynamical Correlations in High Pressure H 2 S
journal, September 1999

Molecular dissociation and two low-temperature high-pressure phases of H 2 S
journal, June 2004

Pressure-induced decomposition of solid hydrogen sulfide
journal, May 2015

Hydrogen sulfide at high pressure: Change in stoichiometry
journal, May 2016

Hydrogen storage in molecular compounds
journal, January 2004

  • Mao, W. L.; Mao, H. -k.
  • Proceedings of the National Academy of Sciences, Vol. 101, Issue 3
  • DOI: 10.1073/pnas.0307449100

New method of high-pressure Brillouin studies for elastic properties of molecular single-crystals grown in a diamond-anvil cell
conference, January 1994

  • Shimizu, Hiroyasu; Sasaki, Shigeo
  • High-pressure science and technology—1993, AIP Conference Proceedings
  • DOI: 10.1063/1.46180

High-pressure elastic properties of the VI and VII phase of ice in dense H 2 O and D 2 O
journal, March 1996

Superconductive sodalite-like clathrate calcium hydride at high pressures
journal, April 2012

  • Wang, H.; Tse, J. S.; Tanaka, K.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 17
  • DOI: 10.1073/pnas.1118168109

General, Closed-Form Expressions for Acoustic Waves in Cubic Crystals
journal, April 1979

Structures of H2S Phases I′ and IV under high pressure
journal, February 1998

  • Fujihisa, H.; Yamawaki, H.; Sakashita, M.
  • Physical Review B, Vol. 57, Issue 5, p. 2651-2654
  • DOI: 10.1103/PhysRevB.57.2651

Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system
journal, August 2015

  • Drozdov, A. P.; Eremets, M. I.; Troyan, I. A.
  • Nature, Vol. 525, Issue 7567
  • DOI: 10.1038/nature14964

Pressure-induced metallization of dense (H2S)2H2 with high-Tc superconductivity
journal, November 2014

  • Duan, Defang; Liu, Yunxian; Tian, Fubo
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06968

Order-disorder phase transition and dissociation of hydrogen sulfide under high pressure: Ab initio molecular dynamics study
journal, April 2010

  • Wang, Liancheng; Tian, Fubo; Feng, Wanxiang
  • The Journal of Chemical Physics, Vol. 132, Issue 16
  • DOI: 10.1063/1.3392673

First-Principles Simulations of Lithium Melting: Stability of the bcc Phase Close to Melting
journal, May 2010

Superconductivity at  100 K in dense SiH4(H2)2 predicted by first principles
journal, August 2010

  • Li, Y.; Gao, G.; Xie, Y.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 36
  • DOI: 10.1073/pnas.1007354107

Hydrogen Clathrate Structures in Rare Earth Hydrides at High Pressures: Possible Route to Room-Temperature Superconductivity
journal, September 2017

Deuteron and sulfur-33 NMR line-shape studies of the molecular motion in the liquid and solid phases of hydrogen sulfide and the solid II phase of hydrogen selenide
journal, October 1989

  • Collins, M. J.; Ratcliffe, C. I.; Ripmeester, J. A.
  • The Journal of Physical Chemistry, Vol. 93, Issue 21
  • DOI: 10.1021/j100358a046

Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021

Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020

Hydrogen sulfide at high pressure: Change in stoichiometry
text, January 2016

  • Goncharov, Alexander; Lobanov, Sergey S.; Kruglov, Ivan
  • Deutsches Elektronen-Synchrotron, DESY, Hamburg
  • DOI: 10.3204/pubdb-2019-01795

Hydrogen storage in molecular compounds
journal, August 2005

  • Mao, W.; Mao, H.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 61, Issue a1
  • DOI: 10.1107/s010876730509731x

The solid phases of deuterium sulphide by powder neutron diffraction
journal, January 1990

  • Cockcroft, Jeremy K.; Fitch, Andrew N.
  • Zeitschrift für Kristallographie, Vol. 193, Issue 1-2, p. 1-19
  • DOI: 10.1524/zkri.1990.193.1-2.1

Pressure-induced decomposition of solid hydrogen sulfide
text, January 2015

Hydrogen sulfide at high pressure: change in stoichiometry
text, January 2016

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    Works referencing / citing this record:

    Disorder–order structural transition of single crystal hydrogen chloride under high pressure–temperature
    journal, January 2019

    • Lu, Mengya; Zhou, Di; Li, Fangfei
    • Physical Chemistry Chemical Physics, Vol. 21, Issue 32
    • DOI: 10.1039/c9cp02839k
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