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Title: Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks

Abstract

Sensitized upconversion is explored in three metal–organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(II) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm-2.

Authors:
 [1];  [1];  [1]; ORCiD logo [2];  [2]; ORCiD logo [1]
+ Show Author Affiliations
  1. Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States). Dept. of Chemistry and Macromolecules Innovation Inst.
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1473675
Alternate Identifier(s):
OSTI ID: 1457465
Grant/Contract Number:  
AC02-06CH11357; SC0012446
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 56; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, and Morris, Amanda J. Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks. United States: N. p., 2018. Web. doi:10.1039/c8cc01893f.
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Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, & Morris, Amanda J. Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks. United States. https://doi.org/10.1039/c8cc01893f
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Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, and Morris, Amanda J. Tue . "Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks". United States. https://doi.org/10.1039/c8cc01893f. https://www.osti.gov/servlets/purl/1473675.
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@article{osti_1473675,
title = {Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks},
author = {Rowe, Jennifer M. and Zhu, Jie and Soderstrom, Erin M. and Xu, Wenqian and Yakovenko, Andrey and Morris, Amanda J.},
abstractNote = {Sensitized upconversion is explored in three metal–organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(II) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm-2.},
doi = {10.1039/c8cc01893f},
journal = {ChemComm},
number = 56,
volume = 54,
place = {United States},
year = {2018},
month = {6}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1039/c8cc01893f
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Cited by: 14 works
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Figures / Tables:

Fig. 1 Fig. 1: Molecular structures of (a)9,10-ADCA, (b)2,6-ADCA, (c) 1,4- ADCA and (d) PdMP.
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    Works referencing / citing this record:

    Engineering Porous Emitting Framework Nanoparticles with Integrated Sensitizers for Low‐Power Photon Upconversion by Triplet Fusion
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    • DOI: 10.1088/1361-648x/ab38da
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