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Title: Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks

Sensitized upconversion is explored in three metal–organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(II) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm -2.
Authors:
 [1] ;  [1] ;  [1] ; ORCiD logo [2] ;  [2] ; ORCiD logo [1]
  1. Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States). Dept. of Chemistry and Macromolecules Innovation Inst.
  2. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division
Publication Date:
Grant/Contract Number:
AC02-06CH11357; SC0012446
Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 54; Journal Issue: 56; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Research Org:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE
OSTI Identifier:
1473675

Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, and Morris, Amanda J.. Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks. United States: N. p., Web. doi:10.1039/c8cc01893f.
Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, & Morris, Amanda J.. Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks. United States. doi:10.1039/c8cc01893f.
Rowe, Jennifer M., Zhu, Jie, Soderstrom, Erin M., Xu, Wenqian, Yakovenko, Andrey, and Morris, Amanda J.. 2018. "Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks". United States. doi:10.1039/c8cc01893f.
@article{osti_1473675,
title = {Sensitized photon upconversion in anthracene-based zirconium metal–organic frameworks},
author = {Rowe, Jennifer M. and Zhu, Jie and Soderstrom, Erin M. and Xu, Wenqian and Yakovenko, Andrey and Morris, Amanda J.},
abstractNote = {Sensitized upconversion is explored in three metal–organic frameworks (MOFs) constructed from the anthracene dicarboxylate (ADC) derivatives and zirconium nodes, 9,10-ADC (9,10-MOF), 2,6-ADC (2,6-MOF) and 1,4-ADC (1,4-MOF). Selective excitation of surface-bound Pd(II) mesoporphyrin IX (PdMP) gives rise to delayed fluorescence (τ = 370 ± 30 ns) from anthracene in the 9,10-MOF. The overall upconversion efficiency of the Pd@9,10-MOF is 0.46 ± 0.05% with a threshold intensity of 104 ± 26 mW cm-2.},
doi = {10.1039/c8cc01893f},
journal = {ChemComm},
number = 56,
volume = 54,
place = {United States},
year = {2018},
month = {6}
}

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