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Title: Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery

Abstract

While solid state electrolytes hold promise for safer batteries, the lithium/solid-state electrolyte interface has presented challenges. In this paper, we report a fully self-forming solid state rechargeable battery based on the Li/I2 couple using LiI rich lithium iodide-(3-hydroxyproprionitrile)2 electrolyte. Effective charge-discharge cycling was demonstrated, showing promise for future generations of high energy density self-forming, self-healing batteries.

Authors:
 [1]; ORCiD logo [1];  [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [2]
  1. Stony Brook Univ., NY (United States). Dept. of Chemistry
  2. Stony Brook Univ., NY (United States). Dept. of Chemistry and Department of Materials Science and Chemical Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
  3. Stony Brook Univ., NY (United States). Dept. of Chemistry and Department of Materials Science and Chemical Engineering
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1473649
Report Number(s):
BNL-209047-2018-JAAM
Journal ID: ISSN 0013-4651
Grant/Contract Number:  
SC0012704; EE0007785
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 165; Journal Issue: 10; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; 36 MATERIALS SCIENCE; impedance; lithium battery; self-forming

Citation Formats

Abraham, Alyson, Huang, Jianping, Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery. United States: N. p., 2018. Web. doi:10.1149/2.0371810jes.
Abraham, Alyson, Huang, Jianping, Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery. United States. doi:https://doi.org/10.1149/2.0371810jes
Abraham, Alyson, Huang, Jianping, Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Wed . "Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery". United States. doi:https://doi.org/10.1149/2.0371810jes. https://www.osti.gov/servlets/purl/1473649.
@article{osti_1473649,
title = {Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery},
author = {Abraham, Alyson and Huang, Jianping and Smith, Paul F. and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},
abstractNote = {While solid state electrolytes hold promise for safer batteries, the lithium/solid-state electrolyte interface has presented challenges. In this paper, we report a fully self-forming solid state rechargeable battery based on the Li/I2 couple using LiI rich lithium iodide-(3-hydroxyproprionitrile)2 electrolyte. Effective charge-discharge cycling was demonstrated, showing promise for future generations of high energy density self-forming, self-healing batteries.},
doi = {10.1149/2.0371810jes},
journal = {Journal of the Electrochemical Society},
number = 10,
volume = 165,
place = {United States},
year = {2018},
month = {7}
}

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Free Publicly Available Full Text
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Cited by: 1 work
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