Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Layer-by-Layer Synthesis of Thick Mesoporous TiO 2 Films with Vertically Oriented Accessible Nanopores and Their Application for Lithium-Ion Battery Negative Electrodes

Abstract

TiO2 films of varying thicknesses (up to ≈1.0 µm) with vertically oriented, accessible 7–9 nm nanopores are synthesized using an evaporation-induced self-assembly layer-by-layer technique. The hypothesis behind the approach is that epitaxial alignment of hydrophobic blocks of surfactant templates induces a consistent, accessible mesophase orientation across a multilayer film, ultimately leading to continuous, vertically aligned pore channels. Characterization using grazing incidence X-ray scattering, scanning electron microscopy, and impedance spectroscopy indicates that the pores are oriented vertically even in relatively thick films (up to 1 µm). These films contain a combination of amorphous and nanocrystalline anatase titania of value for electrochemical energy storage. When applied as negative electrodes in lithium-ion batteries, a capacity of 254 mAh g-1 is obtained after 200 cycles for a single-layer TiO2 film prepared on modified substrate, higher than on unmodified substrate or nonporous TiO2 film, due to the high accessibility of the vertically oriented channels in the films. Thicker films on modified substrate have increased absolute capacity because of higher mass loading but a reduced specific capacity because of transport limitations. These results suggest that the multilayer epitaxial approach is a viable way to prepare high capacity TiO2 films with vertically oriented continuous nanopores.

Authors:
 [1];  [1];  [1];  [1];  [1];  [2];  [1];  [1]; ORCiD logo [1]
+ Show Author Affiliations
  1. Univ. of Kentucky, Lexington, KY (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC); National Science Foundation (NSF)
OSTI Identifier:
1473600
Alternate Identifier(s):
OSTI ID: 1461907
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Volume: 28; Journal Issue: 37; Journal ID: ISSN 1616-301X
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Nagpure, Suraj, Zhang, Qinglin, Khan, M. Arif, Islam, Syed Z., Xu, Jiagang, Strzalka, Joseph, Cheng, Yang-Tse, Knutson, Barbara L., and Rankin, Stephen E. Layer-by-Layer Synthesis of Thick Mesoporous TiO 2 Films with Vertically Oriented Accessible Nanopores and Their Application for Lithium-Ion Battery Negative Electrodes. United States: N. p., 2018. Web. doi:10.1002/adfm.201801849.
Copy to clipboard
Nagpure, Suraj, Zhang, Qinglin, Khan, M. Arif, Islam, Syed Z., Xu, Jiagang, Strzalka, Joseph, Cheng, Yang-Tse, Knutson, Barbara L., & Rankin, Stephen E. Layer-by-Layer Synthesis of Thick Mesoporous TiO 2 Films with Vertically Oriented Accessible Nanopores and Their Application for Lithium-Ion Battery Negative Electrodes. United States. https://doi.org/10.1002/adfm.201801849
Copy to clipboard
Nagpure, Suraj, Zhang, Qinglin, Khan, M. Arif, Islam, Syed Z., Xu, Jiagang, Strzalka, Joseph, Cheng, Yang-Tse, Knutson, Barbara L., and Rankin, Stephen E. Fri . "Layer-by-Layer Synthesis of Thick Mesoporous TiO 2 Films with Vertically Oriented Accessible Nanopores and Their Application for Lithium-Ion Battery Negative Electrodes". United States. https://doi.org/10.1002/adfm.201801849. https://www.osti.gov/servlets/purl/1473600.
Copy to clipboard
@article{osti_1473600,
title = {Layer-by-Layer Synthesis of Thick Mesoporous TiO 2 Films with Vertically Oriented Accessible Nanopores and Their Application for Lithium-Ion Battery Negative Electrodes},
author = {Nagpure, Suraj and Zhang, Qinglin and Khan, M. Arif and Islam, Syed Z. and Xu, Jiagang and Strzalka, Joseph and Cheng, Yang-Tse and Knutson, Barbara L. and Rankin, Stephen E.},
abstractNote = {TiO2 films of varying thicknesses (up to ≈1.0 µm) with vertically oriented, accessible 7–9 nm nanopores are synthesized using an evaporation-induced self-assembly layer-by-layer technique. The hypothesis behind the approach is that epitaxial alignment of hydrophobic blocks of surfactant templates induces a consistent, accessible mesophase orientation across a multilayer film, ultimately leading to continuous, vertically aligned pore channels. Characterization using grazing incidence X-ray scattering, scanning electron microscopy, and impedance spectroscopy indicates that the pores are oriented vertically even in relatively thick films (up to 1 µm). These films contain a combination of amorphous and nanocrystalline anatase titania of value for electrochemical energy storage. When applied as negative electrodes in lithium-ion batteries, a capacity of 254 mAh g-1 is obtained after 200 cycles for a single-layer TiO2 film prepared on modified substrate, higher than on unmodified substrate or nonporous TiO2 film, due to the high accessibility of the vertically oriented channels in the films. Thicker films on modified substrate have increased absolute capacity because of higher mass loading but a reduced specific capacity because of transport limitations. These results suggest that the multilayer epitaxial approach is a viable way to prepare high capacity TiO2 films with vertically oriented continuous nanopores.},
doi = {10.1002/adfm.201801849},
journal = {Advanced Functional Materials},
number = 37,
volume = 28,
place = {United States},
year = {2018},
month = {7}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adfm.201801849
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Mesoporous Titania Nanotubes: Their Preparation and Application as Electrode Materials for Rechargeable Lithium Batteries
journal, October 2007

  • Wang, K.; Wei, M.; Morris, M. A.
  • Advanced Materials, Vol. 19, Issue 19, p. 3016-3020
  • DOI: 10.1002/adma.200602189

Advanced titania nanostructures and composites for lithium ion battery
journal, September 2011

Electrochemical and Photoelectrochemical Investigation of Single-Crystal Anatase
journal, January 1996

  • Kavan, L.; Grätzel, M.; Gilbert, S. E.
  • Journal of the American Chemical Society, Vol. 118, Issue 28
  • DOI: 10.1021/ja954172l

Pore orientation effects on the kinetics of mesostructure loss in surfactant templated titania thin films
journal, January 2016

  • Das, Saikat; Nagpure, Suraj; Garlapalli, Ravinder K.
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 4
  • DOI: 10.1039/C5CP05178A

Multiple Li Positions inside Oxygen Octahedra in Lithiated TiO 2 Anatase
journal, January 2003

  • Wagemaker, Marnix; Kearley, Gordon J.; van Well, Ad A.
  • Journal of the American Chemical Society, Vol. 125, Issue 3
  • DOI: 10.1021/ja028165q

Lithium Storage in Nanostructured TiO 2 Made by Hydrothermal Growth
journal, February 2004

  • Kavan, Ladislav; Kalbáč, Martin; Zukalová, Markéta
  • Chemistry of Materials, Vol. 16, Issue 3
  • DOI: 10.1021/cm035046g

Ti-based compounds as anode materials for Li-ion batteries
journal, January 2012

  • Zhu, Guan-Nan; Wang, Yong-Gang; Xia, Yong-Yao
  • Energy & Environmental Science, Vol. 5, Issue 5
  • DOI: 10.1039/c2ee03410g

Rocking Chair Lithium Battery Based on Nanocrystalline TiO[sub 2] (Anatase)
journal, January 1995

  • Huang, S. Y.
  • Journal of The Electrochemical Society, Vol. 142, Issue 9
  • DOI: 10.1149/1.2048726

Facile Synthesis of Nanocrystalline TiO 2 Mesoporous Microspheres for Lithium-Ion Batteries
journal, December 2010

  • Wang, Jie; Zhou, Yingke; Hu, Yuanyuan
  • The Journal of Physical Chemistry C, Vol. 115, Issue 5
  • DOI: 10.1021/jp1087509

Facile hydrothermal synthesis of porous TiO 2 nanowire electrodes with high-rate capability for Li ion batteries
journal, June 2010

Mass Transport and Electrode Accessibility Through Periodic Self-Assembled Nanoporous Silica Thin Films
journal, May 2007

  • Wei, Ta-Chen; Hillhouse, Hugh W.
  • Langmuir, Vol. 23, Issue 10
  • DOI: 10.1021/la062699d

Adsorption and Recovery of Polyphenolic Flavonoids Using TiO 2 -Functionalized Mesoporous Silica Nanoparticles
journal, March 2017

  • Khan, M. Arif; Wallace, William T.; Islam, Syed Z.
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 37
  • DOI: 10.1021/acsami.7b09510

Tuning the Mesopore Size of Titania Thin Films Using a Polymeric Swelling Agent
journal, May 2011

  • Wu, Qing Liu; Rankin, Stephen E.
  • The Journal of Physical Chemistry C, Vol. 115, Issue 24
  • DOI: 10.1021/jp2021193

Porous TiO 2 /C Nanocomposite Shells As a High-Performance Anode Material for Lithium-Ion Batteries
journal, July 2013

  • Wang, Wenshou; Sa, Qina; Chen, Jihua
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 14
  • DOI: 10.1021/am402350n

Lithium intercalation in TiO2 modifications
journal, January 1997

  • Nuspl, Gerhard; Yoshizawa, Kazunari; Yamabe, Tokio
  • Journal of Materials Chemistry, Vol. 7, Issue 12
  • DOI: 10.1039/a703935b

Titanium-Based Anode Materials for Safe Lithium-Ion Batteries
journal, July 2012

  • Chen, Zonghai; Belharouak, Ilias; Sun, Y. -K.
  • Advanced Functional Materials, Vol. 23, Issue 8
  • DOI: 10.1002/adfm.201200698

Sandwich-Like, Graphene-Based Titania Nanosheets with High Surface Area for Fast Lithium Storage
journal, July 2011

  • Yang, Shubin; Feng, Xinliang; Müllen, Klaus
  • Advanced Materials, Vol. 23, Issue 31
  • DOI: 10.1002/adma.201101599

Aligned TiO 2 Nanotube Arrays As Durable Lithium-Ion Battery Negative Electrodes
journal, August 2012

  • Wu, Qing Liu; Li, Juchuan; Deshpande, Rutooj D.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 35
  • DOI: 10.1021/jp3072266

Reorganization Induced by Silver Salt Reduction Inside a Mesostructured Block Copolymer Silica Film
journal, December 2011

  • Chassagneux, Fernand; Simon, Jean-Paul; Bois, Laurence
  • The Journal of Physical Chemistry C, Vol. 115, Issue 51
  • DOI: 10.1021/jp207207x

Hydrogen incorporation by plasma treatment gives mesoporous black TiO2 thin films with visible photoelectrochemical water oxidation activity
journal, May 2018

The dedicated high-resolution grazing-incidence X-ray scattering beamline 8-ID-E at the Advanced Photon Source
journal, June 2012

  • Jiang, Zhang; Li, Xuefa; Strzalka, Joseph
  • Journal of Synchrotron Radiation, Vol. 19, Issue 4
  • DOI: 10.1107/S0909049512022017

Synthesis of mesoporous titania thin films with vertical pore channels and thick and crystalline walls
journal, November 2011

Rate Characteristics of Anatase TiO[sub 2] Nanotubes and Nanorods for Lithium Battery Anode Materials at Room Temperature
journal, January 2007

  • Kim, Jinyoung; Cho, Jaephil
  • Journal of The Electrochemical Society, Vol. 154, Issue 6
  • DOI: 10.1149/1.2724756

Preparation and electrochemical characterization of TiO2 nanowires as an electrode material for lithium-ion batteries
journal, November 2008

Multilayer Films from Templated TiO 2 and Structural Changes during their Thermal Treatment
journal, May 2008

  • Procházka, Jan; Kavan, Ladislav; Shklover, Valery
  • Chemistry of Materials, Vol. 20, Issue 9
  • DOI: 10.1021/cm071452e

Incorporating poly(3-hexyl thiophene) into orthogonally aligned cylindrical nanopores of titania for optoelectronics
journal, March 2017

Improved lithium storage properties of electrospun TiO2 with tunable morphology: from porous anatase to necklace rutile
journal, January 2013

  • Yang, Yang; Wang, Haiying; Zhou, Qiwen
  • Nanoscale, Vol. 5, Issue 21
  • DOI: 10.1039/c3nr02819d

Alternative Li-Ion Battery Electrode Based on Self-Organized Titania Nanotubes
journal, January 2009

  • Ortiz, Gregorio F.; Hanzu, Ilie; Djenizian, Thierry
  • Chemistry of Materials, Vol. 21, Issue 1
  • DOI: 10.1021/cm801670u

Soft-Templated Self-Assembly of Mesoporous Anatase TiO 2 /Carbon Composite Nanospheres for High-Performance Lithium Ion Batteries
journal, July 2016

  • Wu, Ruofei; Shen, Shuiyun; Xia, Guofeng
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 31
  • DOI: 10.1021/acsami.6b03733

Correlating Titania Nanostructured Morphologies with Performance as Anode Materials for Lithium-Ion Batteries
journal, October 2016

Electrochemical evaluation of rutile TiO2 nanoparticles as negative electrode for Li-ion batteries
journal, December 2009

Nanocrystalline anatase TiO2: a new anode material for rechargeable sodium ion batteries
journal, January 2013

  • Xu, Yang; Memarzadeh Lotfabad, Elmira; Wang, Huanlei
  • Chemical Communications, Vol. 49, Issue 79
  • DOI: 10.1039/c3cc45254a

Mesoporous Titania Thin Film with Highly Ordered and Fully Accessible Vertical Pores and Crystalline Walls
journal, May 2008

  • Koh, Chol-Won; Lee, U-Hwang; Song, June-Kyu
  • Chemistry – An Asian Journal, Vol. 3, Issue 5
  • DOI: 10.1002/asia.200700331

Visible-Light Photocatalysis in Titania-Based Mesoporous Thin Films
journal, April 2008

  • Soni, Saurabh S.; Henderson, Mark J.; Bardeau, Jean-François
  • Advanced Materials, Vol. 20, Issue 8
  • DOI: 10.1002/adma.200701066

A review on the key issues for lithium-ion battery management in electric vehicles
journal, March 2013

High Lithium Electroactivity of Nanometer-Sized Rutile TiO2
journal, June 2006

  • Hu, Y.-S.; Kienle, L.; Guo, Y.-G.
  • Advanced Materials, Vol. 18, Issue 11, p. 1421-1426
  • DOI: 10.1002/adma.200502723

Phase behavior of ordered mesoporous silica film prepared by Brij-76 block copolymer
journal, April 2008

A review on electrolyte additives for lithium-ion batteries
journal, November 2006

Generalized Coating Route to Silica and Titania Films with Orthogonally Tilted Cylindrical Nanopore Arrays
journal, November 2006

  • Koganti, Venkat R.; Dunphy, Darren; Gowrishankar, Vignesh
  • Nano Letters, Vol. 6, Issue 11
  • DOI: 10.1021/nl061992v

In Situ GISAXS Investigation of Low-Temperature Aging in Oriented Surfactant-Mesostructured Titania Thin Films
journal, September 2015

  • Nagpure, Suraj; Das, Saikat; Garlapalli, Ravinder K.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 40
  • DOI: 10.1021/acs.jpcc.5b06945

Control of TiO 2 Grain Size and Positioning in Three-Dimensionally Ordered Macroporous TiO 2 /C Composite Anodes for Lithium Ion Batteries
journal, December 2013

  • Petkovich, Nicholas D.; Rudisill, Stephen G.; Wilson, Benjamin E.
  • Inorganic Chemistry, Vol. 53, Issue 2
  • DOI: 10.1021/ic402648f

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

Ordered mesoporous TiO2–C nanocomposite as an anode material for long-term performance lithium-ion batteries
journal, January 2013

  • Zeng, Lingxing; Zheng, Cheng; Xia, Lunchao
  • Journal of Materials Chemistry A, Vol. 1, Issue 13
  • DOI: 10.1039/c3ta10275k

Eco-friendly synthesis of rutile TiO2 nanostructures with controlled morphology for efficient lithium-ion batteries
journal, November 2016

Nanocrystalline TiO[sub 2] (Anatase) Electrodes: Surface Morphology, Adsorption, and Electrochemical Properties
journal, January 1996

  • Kavan, L.
  • Journal of The Electrochemical Society, Vol. 143, Issue 2
  • DOI: 10.1149/1.1836455

Highly Organized Mesoporous TiO2 Films with Controlled Crystallinity: A Li-Insertion Study
journal, January 2007

  • Fattakhova-Rohlfing, D.; Wark, M.; Brezesinski, T.
  • Advanced Functional Materials, Vol. 17, Issue 1, p. 123-132
  • DOI: 10.1002/adfm.200600425

Designing nanostructured Si anodes for high energy lithium ion batteries
journal, October 2012

Surfactant-Templated TiO 2 (Anatase):  Characteristic Features of Lithium Insertion Electrochemistry in Organized Nanostructures
journal, December 2000

  • Kavan, Ladislav; Rathouský, Jiří; Grätzel, Michael
  • The Journal of Physical Chemistry B, Vol. 104, Issue 50
  • DOI: 10.1021/jp003609v

Amorphous titanium oxide electrode for high-rate discharge and charge
journal, February 2004

Mesoporous electrode material from alumina-stabilized anatase TiO2 for lithium ion batteries
journal, July 2004

  • Attia, Adel; Zukalov�, Mark�ta; Rathousk�, Ji?�
  • Journal of Solid State Electrochemistry, Vol. 9, Issue 3
  • DOI: 10.1007/s10008-004-0564-3

Lithium batteries: Status, prospects and future
journal, May 2010

Vertically oriented hexagonal mesoporous films formed through nanometre-scale epitaxy
journal, September 2008

  • Richman, Erik K.; Brezesinski, Torsten; Tolbert, Sarah H.
  • Nature Materials, Vol. 7, Issue 9
  • DOI: 10.1038/nmat2257

Hydrothermal Stability of Ordered Surfactant-Templated Titania
journal, August 2013

  • Assaker, K.; Carteret, C.; Durand, P.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 32
  • DOI: 10.1021/jp405517w

TiO 2 as an active or supplemental material for lithium batteries
journal, January 2016

  • Song, Taeseup; Paik, Ungyu
  • Journal of Materials Chemistry A, Vol. 4, Issue 1
  • DOI: 10.1039/C5TA06888F

A Perspective on Mesoporous TiO 2 Materials
journal, July 2013

  • Li, Wei; Wu, Zhangxiong; Wang, Jinxiu
  • Chemistry of Materials, Vol. 26, Issue 1
  • DOI: 10.1021/cm4014859

Hybrid Organic−Inorganic Mesostructured Membranes: Interfaces and Organization at Different Length Scales
journal, June 2010

  • Alonso, Bruno; Fayon, Franck; Massiot, Dominique
  • The Journal of Physical Chemistry C, Vol. 114, Issue 27
  • DOI: 10.1021/jp101652a

Morphological and Chemical Tuning of High-Energy-Density Metal Oxides for Lithium Ion Battery Electrode Applications
journal, May 2017

Ionic Liquid-Assisted Synthesis of TiO 2 -Carbon Hybrid Nanostructures for Lithium-Ion Batteries
journal, January 2016

  • Cheng, Yanhua; Chen, Zheng; Wu, Haobin
  • Advanced Functional Materials, Vol. 26, Issue 9
  • DOI: 10.1002/adfm.201504134

Preparation and Novel Lithium Intercalation Properties of Titanium Oxide Nanotubes
journal, January 2005

  • Li, Junrong; Tang, Zilong; Zhang, Zhongtai
  • Electrochemical and Solid-State Letters, Vol. 8, Issue 6
  • DOI: 10.1149/1.1904465

Lithium-Ion Intercalation into TiO 2 -B Nanowires
journal, March 2005

  • Armstrong, A. R.; Armstrong, G.; Canales, J.
  • Advanced Materials, Vol. 17, Issue 7
  • DOI: 10.1002/adma.200400795

Lithium insertion in different TiO2 modifications
journal, September 1988

Scherrer grain-size analysis adapted to grazing-incidence scattering with area detectors
journal, October 2009

Controlled Formation of Highly Organized Mesoporous Titania Thin Films:  From Mesostructured Hybrids to Mesoporous Nanoanatase TiO 2
journal, August 2003

  • Crepaldi, Eduardo L.; Soler-Illia, Galo J. de A. A.; Grosso, David
  • Journal of the American Chemical Society, Vol. 125, Issue 32
  • DOI: 10.1021/ja030070g

Three-Dimensional Coherent Titania–Mesoporous Carbon Nanocomposite and Its Lithium-Ion Storage Properties
journal, June 2012

  • Shen, Laifa; Uchaker, Evan; Yuan, Changzhou
  • ACS Applied Materials & Interfaces, Vol. 4, Issue 6
  • DOI: 10.1021/am300357b

Preparation of Hollow Anatase TiO 2 Nanospheres via Ostwald Ripening
journal, March 2004

  • Yang, Hua Gui; Zeng, Hua Chun
  • The Journal of Physical Chemistry B, Vol. 108, Issue 11
  • DOI: 10.1021/jp0377782

The role of nanotechnology in the development of battery materials for electric vehicles
journal, December 2016

Green energy storage materials: Nanostructured TiO2 and Sn-based anodes for lithium-ion batteries
journal, January 2009

  • Deng, Da; Kim, Min Gyu; Lee, Jim Yang
  • Energy & Environmental Science, Vol. 2, Issue 8, p. 818-837
  • DOI: 10.1039/b823474d

Li + Ion Insertion in TiO 2 (Anatase). 2. Voltammetry on Nanoporous Films
journal, September 1997

  • Lindström, Henrik; Södergren, Sven; Solbrand, Anita
  • The Journal of Physical Chemistry B, Vol. 101, Issue 39
  • DOI: 10.1021/jp970490q

Lithium Intercalation in Nanoporous Anatase TiO 2 Studied with XPS
journal, April 1997

  • Södergren, Sven; Siegbahn, Hans; Rensmo, Håkan
  • The Journal of Physical Chemistry B, Vol. 101, Issue 16
  • DOI: 10.1021/jp9639399

Spatial Extent of Lithium Intercalation in Anatase TiO 2
journal, August 1999

  • van de Krol, Roel; Goossens, Albert; Schoonman, Joop
  • The Journal of Physical Chemistry B, Vol. 103, Issue 34
  • DOI: 10.1021/jp9909964

In Situ X-Ray Diffraction of Lithium Intercalation in Nanostructured and Thin Film Anatase TiO[sub 2]
journal, January 1999

  • van de Krol, Roel
  • Journal of The Electrochemical Society, Vol. 146, Issue 9
  • DOI: 10.1149/1.1392447

Orientation Dependence of Charge-Transfer Processes on TiO[sub 2] (Anatase) Single Crystals
journal, January 2000

  • Hengerer, Roland; Kavan, Ladislav; Krtil, Petr
  • Journal of The Electrochemical Society, Vol. 147, Issue 4
  • DOI: 10.1149/1.1393379

In-Situ GISAXS Investigation of Pore Orientation Effects on the Thermal Transformation Mechanism in Mesoporous Titania Thin Films
journal, December 2013

  • Das, Saikat; Wu, Qingliu; Garlapalli, Ravinder K.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 2
  • DOI: 10.1021/jp406165v

A Mesoporous γ-Alumina Film with Vertical Mesoporosity: The Unusual Conversion from a Im${\bar 3}$m Mesostructure to Vertically Oriented γ-Alumina Nanowires
journal, June 2011

  • Oveisi, Hamid; Jiang, Xiangfen; Imura, Masataka
  • Angewandte Chemie International Edition, Vol. 50, Issue 32
  • DOI: 10.1002/anie.201008192

High Lithium Electroactivity of Nanometer-Sized Rutile TiO2.
journal, August 2006

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    A Novel Strategy for the Selection of Polysulfide Adsorbents Toward High‐Performance Lithium‐Sulfur Batteries
    journal, May 2019

    Introducing nanodiamond into TiO 2 -based anode for improving the performance of lithium-ion batteries
    journal, January 2019

    • Gao, Xuan; Sun, Xiaochen; Jiang, Zhigang
    • New Journal of Chemistry, Vol. 43, Issue 9
    • DOI: 10.1039/c8nj06226a

    TiO 2 -B nanowires via topological conversion with enhanced lithium-ion intercalation properties
    journal, January 2019

    • Zhang, Weifeng; Zhang, Ying; Yu, Ling
    • Journal of Materials Chemistry A, Vol. 7, Issue 8
    • DOI: 10.1039/c8ta10709b

    Carbon-based materials for lithium-ion capacitors
    journal, January 2019

    • Wang, Xiaojun; Liu, Lili; Niu, Zhiqiang
    • Materials Chemistry Frontiers, Vol. 3, Issue 7
    • DOI: 10.1039/c9qm00062c

    Investigation of Cu doped flake-NiO as an anode material for lithium ion batteries
    journal, January 2019

    Study of the effect of irradiation with Fe 7+ ions on the structural properties of thin TiO 2 foils
    journal, January 2019

    • Dukenbayev, K.; Kozlovskiy, A.; Kenzhina, I.
    • Materials Research Express, Vol. 6, Issue 4
    • DOI: 10.1088/2053-1591/aafcbc
      Sort by:
      [ × clear filter / sort ]

      Similar Records in DOE PAGES and OSTI.GOV collections: