Extraction of rare earth elements using magnetite@MOF composites

Elsaidi, Sameh K.; Sinnwell, Michael A.; Devaraj, Arun; Droubay, Tim C.; Nie, Zimin; Murugesan, Vijayakumar; McGrail, B. Peter; Thallapally, Praveen K.

doi:10.1039/C8TA04750B

Title: Extraction of rare earth elements using magnetite@MOF composites

Abstract

Magnetic core–shell microspheres were developed to extract rare earth elements (REEs) from aqueous and brine solutions with up to 99.99% removal efficiency. The shell, composed of a thermally and chemically stable functionalized metal–organic framework (MOF), is grown over a synthesized Fe ₃ O ₄ magnetic core (magnetite@MOF).

Authors:

Elsaidi, Sameh K. ^[1];

^[1]; Devaraj, Arun ^[1]; Droubay, Tim C. ^[1]; Nie, Zimin ^[2];

^[2]; McGrail, B. Peter ^[2];

^[1]

Physical and Computational Science Directorate, Pacific Northwest National Laboratory Richland, Washington 99352, USA
Energy and Environment Technology Directorate, Pacific Northwest National Laboratory Richland, Washington 99352, USA

Publication Date:: Mon Jan 01 00:00:00 EST 2018

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Geothermal Technologies Office

OSTI Identifier:: 1472195

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. A

Additional Journal Information:: Journal Name: Journal of Materials Chemistry. A Journal Volume: 6 Journal Issue: 38; Journal ID: ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Elsaidi, Sameh K., Sinnwell, Michael A., Devaraj, Arun, Droubay, Tim C., Nie, Zimin, Murugesan, Vijayakumar, McGrail, B. Peter, and Thallapally, Praveen K. Extraction of rare earth elements using magnetite@MOF composites.  United Kingdom: N. p., 2018. 
Web.  doi:10.1039/C8TA04750B.

Copy to clipboard


                    Elsaidi, Sameh K., Sinnwell, Michael A., Devaraj, Arun, Droubay, Tim C., Nie, Zimin, Murugesan, Vijayakumar, McGrail, B. Peter, & Thallapally, Praveen K. Extraction of rare earth elements using magnetite@MOF composites.  United Kingdom.  https://doi.org/10.1039/C8TA04750B

Copy to clipboard


                    Elsaidi, Sameh K., Sinnwell, Michael A., Devaraj, Arun, Droubay, Tim C., Nie, Zimin, Murugesan, Vijayakumar, McGrail, B. Peter, and Thallapally, Praveen K. Mon .  
"Extraction of rare earth elements using magnetite@MOF composites".  United Kingdom.  https://doi.org/10.1039/C8TA04750B.

Copy to clipboard


                    
@article{osti_1472195,

  title        = {Extraction of rare earth elements using magnetite@MOF composites},

  author       = {Elsaidi, Sameh K. and Sinnwell, Michael A. and Devaraj, Arun and Droubay, Tim C. and Nie, Zimin and Murugesan, Vijayakumar and McGrail, B. Peter and Thallapally, Praveen K.},

  abstractNote = {Magnetic core–shell microspheres were developed to extract rare earth elements (REEs) from aqueous and brine solutions with up to 99.99% removal efficiency. The shell, composed of a thermally and chemically stable functionalized metal–organic framework (MOF), is grown over a synthesized Fe 3 O 4 magnetic core (magnetite@MOF).},

  doi          = {10.1039/C8TA04750B},

  journal      = {Journal of Materials Chemistry. A},

  number       = 38,

  volume       = 6,

  place        = {United Kingdom},

  year         = {Mon Jan 01 00:00:00 EST 2018},

  month        = {Mon Jan 01 00:00:00 EST 2018}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
https://doi.org/10.1039/C8TA04750B

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 26 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

O-carboxymethyl chitosan entrapped by silica: preparation and adsorption behaviour toward neodymium (III) ions: Adsorption of neodymium with SiO
journal, May 2012

Wang, Fuchun; Zhao, Junmei; Zhou, Huacong
Journal of Chemical Technology & Biotechnology, Vol. 88, Issue 2
DOI: 10.1002/jctb.3850

Reduced Magnetism in Core–Shell Magnetite@MOF Composites
journal, October 2017

Elsaidi, Sameh K.; Sinnwell, Michael A.; Banerjee, Debasis
Nano Letters, Vol. 17, Issue 11
DOI: 10.1021/acs.nanolett.7b03451

Heating and separation using nanomagnet-functionalized metal–organic frameworks
journal, January 2011

Lohe, Martin R.; Gedrich, Kristina; Freudenberg, Thomas
Chemical Communications, Vol. 47, Issue 11
DOI: 10.1039/c0cc05278g

POROUS MATERIALS:Prospects for Giant Pores
journal, February 1999

Férey, G.
Science, Vol. 283, Issue 5405
DOI: 10.1126/science.283.5405.1125

Eu(III) adsorption using di(2-thylhexly) phosphoric acid-immobilized magnetic GMZ bentonite
journal, February 2012

Chen, Yonggui; Zhu, Baohui; Wu, Dongbei
Chemical Engineering Journal, Vol. 181-182
DOI: 10.1016/j.cej.2011.11.100

Synthesis and chelating properties of some poly(amidoxime-hydroxamic acid) resins toward some trivalent lanthanide metal ions
journal, January 2005

Alakhras, Fadi A.; Dari, Kamal Abu; Mubarak, Mohammad S.
Journal of Applied Polymer Science, Vol. 97, Issue 2
DOI: 10.1002/app.21825

Graft copolymer-lanthanide complexes obtained by radiation grafting on polyethylene film
journal, November 2002

Choi, Seong-Ho; Lee, Kwang-Pill; Sohn, Sang-Ho
Journal of Applied Polymer Science, Vol. 87, Issue 2
DOI: 10.1002/app.11445

Adsorption of lanthanum (III) from aqueous solution using 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester-grafted magnetic silica nanocomposites
journal, September 2013

Wu, Dongbei; Sun, Yanhong; Wang, Qigang
Journal of Hazardous Materials, Vol. 260
DOI: 10.1016/j.jhazmat.2013.05.042

Applications of magnetic metal–organic framework composites
journal, January 2013

Ricco, Raffaele; Malfatti, Luca; Takahashi, Masahide
Journal of Materials Chemistry A, Vol. 1, Issue 42
DOI: 10.1039/c3ta13140h

Ion Imprinted Polymer Solid Phase Extraction (IIP‐SPE) for Preconcentrative Separation of Erbium(III) From Adjacent Lanthanides and Yttrium
journal, February 2006

Ramakrishnan, Kala; Prasada Rao, Talasila
Separation Science and Technology, Vol. 41, Issue 2
DOI: 10.1080/01496390500446327

Adsorption of heavy rare earth(III) with extraction resin containing bis(2,4,4-trimethylpentyl) monothiophosphinic acid
journal, July 2004

Jia, Q.; Wang, Z. H.; Li, D. Q.
Journal of Alloys and Compounds, Vol. 374, Issue 1-2
DOI: 10.1016/j.jallcom.2003.11.056

Minerals go critical
journal, August 2011

Eggert, Roderick G.
Nature Chemistry, Vol. 3, Issue 9
DOI: 10.1038/nchem.1116

GEOTHERMAL ENERGY FROM THE EARTH:Its Potential Impact as an Environmentally Sustainable Resource
journal, November 1997

Mock, John E.; Tester, Jefferson W.; Wright, P. Michael
Annual Review of Energy and the Environment, Vol. 22, Issue 1
DOI: 10.1146/annurev.energy.22.1.305

Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups
journal, June 2011

Akiyama, George; Matsuda, Ryotaro; Sato, Hiroshi
Advanced Materials, Vol. 23, Issue 29
DOI: 10.1002/adma.201101356

Ethylenediamine grafting on a zeolite-like metal organic framework (ZMOF) for CO2 capture
journal, September 2013

Chen, Chao; Kim, Jun; Park, Dong-Wha
Materials Letters, Vol. 106
DOI: 10.1016/j.matlet.2013.05.078

A critical review on solvent extraction of rare earths from aqueous solutions
journal, February 2014

Xie, Feng; Zhang, Ting An; Dreisinger, David
Minerals Engineering, Vol. 56
DOI: 10.1016/j.mineng.2013.10.021

Adsorption behavior of rare earth elements on silica gel modified with diglycol amic acid
journal, February 2015

Ogata, Takeshi; Narita, Hirokazu; Tanaka, Mikiya
Hydrometallurgy, Vol. 152
DOI: 10.1016/j.hydromet.2015.01.005

Monodisperse Magnetic Single-Crystal Ferrite Microspheres
journal, April 2005

Deng, Hong; Li, Xiaolin; Peng, Qing
Angewandte Chemie International Edition, Vol. 44, Issue 18
DOI: 10.1002/anie.200462551

Reticular synthesis and the design of new materials
journal, June 2003

Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W.
Nature, Vol. 423, Issue 6941, p. 705-714
DOI: 10.1038/nature01650

Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013

Carboni, Michaël; Abney, Carter W.; Liu, Shubin
Chemical Science, Vol. 4, Issue 6, p. 2396-2402
DOI: 10.1039/c3sc50230a

Cysteine-Functionalized Chitosan Magnetic Nano-Based Particles for the Recovery of Light and Heavy Rare Earth Metals: Uptake Kinetics and Sorption Isotherms
journal, February 2015

Galhoum, Ahmed; Mafhouz, Mohammad; Abdel-Rehem, Sayed
Nanomaterials, Vol. 5, Issue 1
DOI: 10.3390/nano5010154

Recovery of rare earth metals through biosorption: An overview
journal, October 2013

Das, Nilanjana; Das, Devlina
Journal of Rare Earths, Vol. 31, Issue 10
DOI: 10.1016/S1002-0721(13)60009-5

Selective incarceration of caesium ions by Venus flytrap action of a flexible framework sulfide
journal, January 2010

Ding, Nan; Kanatzidis, Mercouri G.
Nature Chemistry, Vol. 2, Issue 3
DOI: 10.1038/nchem.519

Selective Uptake of Rare Earths from Aqueous Solutions by EDTA-Functionalized Magnetic and Nonmagnetic Nanoparticles
journal, March 2014

Dupont, David; Brullot, Ward; Bloemen, Maarten
ACS Applied Materials & Interfaces, Vol. 6, Issue 7
DOI: 10.1021/am406027y

Magnetic Cores with Porous Coatings: Growth of Metal-Organic Frameworks on Particles Using Liquid Phase Epitaxy
journal, September 2012

Silvestre, Martin E.; Franzreb, Matthias; Weidler, Peter G.
Advanced Functional Materials, Vol. 23, Issue 9
DOI: 10.1002/adfm.201202078

Sorption of europium(III) and copper(II) by a mesostructured silica doped with acyl-hydroxypyrazole derivatives
journal, September 2006

Bou-Maroun, Elias; Goetz-Grandmont, Geneviève J.; Boos, Anne
Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 287, Issue 1-3
DOI: 10.1016/j.colsurfa.2006.05.047

Synthesis of Fe3O4@ZIF-8 magnetic core–shell microspheres and their potential application in a capillary microreactor
journal, July 2013

Zhang, Tong; Zhang, Xiongfu; Yan, Xinjuan
Chemical Engineering Journal, Vol. 228
DOI: 10.1016/j.cej.2013.05.020

On the Extraction of Rare Earth Elements from Geothermal Brines
journal, August 2017

Smith, York; Kumar, Pankaj; McLennan, John
Resources, Vol. 6, Issue 3
DOI: 10.3390/resources6030039

X-ray-absorption spectroscopy at the Fe $L_{2, 3}$ threshold in iron oxides
journal, August 1995

Crocombette, J. P.; Pollak, M.; Jollet, F.
Physical Review B, Vol. 52, Issue 5
DOI: 10.1103/PhysRevB.52.3143

Rare earth element systematics in hydrothermal fluids
journal, March 1989

Michard, Annie
Geochimica et Cosmochimica Acta, Vol. 53, Issue 3
DOI: 10.1016/0016-7037(89)90017-3

Opportunities and challenges for a sustainable energy future
journal, August 2012

Chu, Steven; Majumdar, Arun
Nature, Vol. 488, Issue 7411, p. 294-303
DOI: 10.1038/nature11475

Evaluating Rare Earth Element Availability: A Case with Revolutionary Demand from Clean Technologies
journal, February 2012

Alonso, Elisa; Sherman, Andrew M.; Wallington, Timothy J.
Environmental Science & Technology, Vol. 46, Issue 6
DOI: 10.1021/es203518d

Coating Fe ₃ O ₄ Magnetic Nanoparticles with Humic Acid for High Efficient Removal of Heavy Metals in Water
journal, September 2008

Liu, Jing-fu; Zhao, Zong-shan; Jiang, Gui-bin
Environmental Science & Technology, Vol. 42, Issue 18
DOI: 10.1021/es800924c

Introduction of amino groups into acid-resistant MOFs for enhanced U( vi ) sorption
journal, January 2015

Bai, Zhi-Qiang; Yuan, Li-Yong; Zhu, Lin
Journal of Materials Chemistry A, Vol. 3, Issue 2
DOI: 10.1039/C4TA04878D

Molecular building blocks approach to the assembly of zeolite-like metal–organic frameworks (ZMOFs) with extra-large cavities
journal, January 2006

Liu, Yunling; Kravtsov, Victor Ch.; Larsen, Randy
Chemical Communications, Issue 14
DOI: 10.1039/b600188m

Adsorption of Uranyl ions on Amine-functionalization of MIL-101(Cr) Nanoparticles by a Facile Coordination-based Post-synthetic strategy and X-ray Absorption Spectroscopy Studies
journal, September 2015

Zhang, Jian-Yong; Zhang, Na; Zhang, Linjuan
Scientific Reports, Vol. 5, Issue 1
DOI: 10.1038/srep13514

Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid
journal, December 2002

Kitaura, R.
Science, Vol. 298, Issue 5602
DOI: 10.1126/science.1078481

Selective Extraction of Heavy and Light Lanthanides from Aqueous Solution by Advanced Magnetic Nanosorbents
journal, April 2016

Zhang, Huijin; McDowell, Rocklan G.; Martin, Leigh R.
ACS Applied Materials & Interfaces, Vol. 8, Issue 14
DOI: 10.1021/acsami.6b01550

Using Functional Nano- and Microparticles for the Preparation of Metal–Organic Framework Composites with Novel Properties
journal, November 2013

Doherty, Cara M.; Buso, Dario; Hill, Anita J.
Accounts of Chemical Research, Vol. 47, Issue 2
DOI: 10.1021/ar400130a

Selective separation of rare earth ions from aqueous solution using functionalized magnetite nanoparticles: kinetic and thermodynamic studies
journal, November 2017

Ashour, Radwa M.; El-sayed, Ramy; Abdel-Magied, Ahmed F.
Chemical Engineering Journal, Vol. 327
DOI: 10.1016/j.cej.2017.06.101

Seizing the caesium
journal, March 2010

Clearfield, Abraham
Nature Chemistry, Vol. 2, Issue 3
DOI: 10.1038/nchem.567

Separation nanotechnology of diethylenetriaminepentaacetic acid bonded magnetic nanoparticles for spent nuclear fuel
journal, January 2013

Kaur, Maninder; Johnson, Andrew; Tian, Guoxin
Nano Energy, Vol. 2, Issue 1
DOI: 10.1016/j.nanoen.2012.08.005

Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework
journal, April 2016

Demir, Selvan; Brune, Nicholas K.; Van Humbeck, Jeffrey F.
ACS Central Science, Vol. 2, Issue 4
DOI: 10.1021/acscentsci.6b00066

Similar Records in DOE PAGES and OSTI.GOV collections:

Extraction of Rare Earth Elements using Magnetite@MOF Composites

Journal Article Elsaidi, Sameh K. ; Sinnwell, Michael A. ; Devaraj, Arun ; ... - Journal of Materials Chemistry A

Magnetic core-shell microspheres were developed to extract rare earth elements (REEs) from aqueous and brine solutions with up to 99.99% removal efficiency. The shell, composed of a thermally and chemically stable functionalized metal-organic framework (MOF), is grown over a synthesized Fe3O4 magnetic core (magnetite@MOF). The composite particles can be removed from the mixture under an applied magnetic field, offering a practical, and efficient REE-removal process.
https://doi.org/10.1039/c8ta04750b
Reduced Magnetism in Core–Shell Magnetite@MOF Composites

Journal Article Elsaidi, Sameh K. ; Sinnwell, Michael A. ; Banerjee, Debasis ; ... - Nano Letters

Rare-earth elements (REEs) have significant commercial and military uses.1-3 However, REE extraction through conventional mining processes is expensive and feasible at only a few locations worldwide. Alternative methods are needed to produce REEs from more geographically disperse resources and in a cost effective, environmental friendly manner.4,5 Among various sources, geothermal brine, used for generating geothermal energy can possess attractive concentrations (ppb to ppm level) of REEs along with other dissolved metal ions.6 A system that can selectively trap the REEs using an existing geothermal power plant infrastructure would be an attractive additional revenue stream for the plant operator that couldmore »« less
https://doi.org/10.1021/acs.nanolett.7b03451
Rare-Earth Element Extraction from Geothermal Brine Using Magnetic Core-Shell Nanoparticles-Techno-Economic Analysis

Journal Article Liu, Jian ; Martin, Paul F. ; McGrail, Bernard P. - Geothermics

Rare earth elements (REE) are critical materials having a wide variety of applications such as generating and storing renewable energy. Extracting rare earth metals from geothermal brines is a very challenging problem due to the low concentrations of these elements and engineering challenges with traditional chemical separations methods involving packed sorbent beds or membranes that would impede large volumetric flow rates of geothermal fluids transitioning through the geothermal power plant. We are demonstrating a simple and highly cost-effective nanofluid-based method for extracting rare earth metals from geothermal brines. Core-shell composite nanoparticles that contain a magnetic iron oxide core surrounded bymore »« less
https://doi.org/10.1016/j.geothermics.2020.101938
Extraction of Rare Earth Elements from Chloride Media with Tetrabutyl Diglycolamide in 1-Octanol Modified Carbon Dioxide

Journal Article Case, Mary ; Fox, Robert ; Baek, Donna ; ... - Metals

Rare earth elements (REEs) are critical to our modern world. Recycling REEs from used products could help with potential supply issues. Extracting REEs from chloride media with tetrabutyl diglycolamide (TBDGA) in carbon dioxide could help recycle REEs with less waste than traditional solvents. Carbon dioxide as a solvent is inexpensive, inert, and reusable. Conditions for extraction of Eu from aqueous chloride media were optimized by varying moles percent of 1-octanol modifier, temperature, pressure, Eu concentration, TBDGA concentration, Cl– concentration, and HCl concentration. These optimized conditions were tested on a Y, Ce, Eu, Tb simulant material, REEs containing NdFeB magnets, andmore »« less
Cited by 5
https://doi.org/10.3390/met9040429

Full Text Available
Magnetic Partitioning Nanofluid for Rare Earth Extraction from Geothermal Fluids

Technical Report McGrail, Bernard P. ; Thallapally, Praveen K. ; Liu, Jian ; ...

Rare earth metals are critical materials in a wide variety of applications in generating and storing renewable energy and in designing more energy efficient devices. Extracting rare earth metals from geothermal brines is a very challenging problem due to the low concentrations of these elements and engineering challenges with traditional chemical separations methods involving packed sorbent beds or membranes that would impede large volumetric flow rates of geothermal fluids transitioning through the plant. We are demonstrating a simple and highly cost-effective nanofluid-based method for extracting rare earth metals from geothermal brines. Core-shell composite nanoparticles are produced that contain a magneticmore »« less
https://doi.org/10.2172/1376278

Full Text Available

Similar Records

Title: Extraction of rare earth elements using magnetite@MOF composites

Abstract

Citation Formats

O-carboxymethyl chitosan entrapped by silica: preparation and adsorption behaviour toward neodymium (III) ions: Adsorption of neodymium with SiO journal, May 2012

Reduced Magnetism in Core–Shell Magnetite@MOF Composites journal, October 2017

Heating and separation using nanomagnet-functionalized metal–organic frameworks journal, January 2011

POROUS MATERIALS:Prospects for Giant Pores journal, February 1999

Eu(III) adsorption using di(2-thylhexly) phosphoric acid-immobilized magnetic GMZ bentonite journal, February 2012

Synthesis and chelating properties of some poly(amidoxime-hydroxamic acid) resins toward some trivalent lanthanide metal ions journal, January 2005

Graft copolymer-lanthanide complexes obtained by radiation grafting on polyethylene film journal, November 2002

Adsorption of lanthanum (III) from aqueous solution using 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester-grafted magnetic silica nanocomposites journal, September 2013

Applications of magnetic metal–organic framework composites journal, January 2013

Ion Imprinted Polymer Solid Phase Extraction (IIP‐SPE) for Preconcentrative Separation of Erbium(III) From Adjacent Lanthanides and Yttrium journal, February 2006

Adsorption of heavy rare earth(III) with extraction resin containing bis(2,4,4-trimethylpentyl) monothiophosphinic acid journal, July 2004

Minerals go critical journal, August 2011

GEOTHERMAL ENERGY FROM THE EARTH:Its Potential Impact as an Environmentally Sustainable Resource journal, November 1997

Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups journal, June 2011

Ethylenediamine grafting on a zeolite-like metal organic framework (ZMOF) for CO2 capture journal, September 2013

A critical review on solvent extraction of rare earths from aqueous solutions journal, February 2014

Adsorption behavior of rare earth elements on silica gel modified with diglycol amic acid journal, February 2015

Monodisperse Magnetic Single-Crystal Ferrite Microspheres journal, April 2005

Reticular synthesis and the design of new materials journal, June 2003

Highly porous and stable metal–organic frameworks for uranium extraction journal, January 2013

Cysteine-Functionalized Chitosan Magnetic Nano-Based Particles for the Recovery of Light and Heavy Rare Earth Metals: Uptake Kinetics and Sorption Isotherms journal, February 2015

Recovery of rare earth metals through biosorption: An overview journal, October 2013

Selective incarceration of caesium ions by Venus flytrap action of a flexible framework sulfide journal, January 2010

Selective Uptake of Rare Earths from Aqueous Solutions by EDTA-Functionalized Magnetic and Nonmagnetic Nanoparticles journal, March 2014

Magnetic Cores with Porous Coatings: Growth of Metal-Organic Frameworks on Particles Using Liquid Phase Epitaxy journal, September 2012

Sorption of europium(III) and copper(II) by a mesostructured silica doped with acyl-hydroxypyrazole derivatives journal, September 2006

Synthesis of Fe3O4@ZIF-8 magnetic core–shell microspheres and their potential application in a capillary microreactor journal, July 2013

On the Extraction of Rare Earth Elements from Geothermal Brines journal, August 2017

X-ray-absorption spectroscopy at the Fe L 2 , 3 threshold in iron oxides journal, August 1995

Rare earth element systematics in hydrothermal fluids journal, March 1989

Opportunities and challenges for a sustainable energy future journal, August 2012

Evaluating Rare Earth Element Availability: A Case with Revolutionary Demand from Clean Technologies journal, February 2012

Coating Fe 3 O 4 Magnetic Nanoparticles with Humic Acid for High Efficient Removal of Heavy Metals in Water journal, September 2008

Introduction of amino groups into acid-resistant MOFs for enhanced U( vi ) sorption journal, January 2015

Molecular building blocks approach to the assembly of zeolite-like metal–organic frameworks (ZMOFs) with extra-large cavities journal, January 2006

Adsorption of Uranyl ions on Amine-functionalization of MIL-101(Cr) Nanoparticles by a Facile Coordination-based Post-synthetic strategy and X-ray Absorption Spectroscopy Studies journal, September 2015

Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid journal, December 2002

Selective Extraction of Heavy and Light Lanthanides from Aqueous Solution by Advanced Magnetic Nanosorbents journal, April 2016

Using Functional Nano- and Microparticles for the Preparation of Metal–Organic Framework Composites with Novel Properties journal, November 2013

Selective separation of rare earth ions from aqueous solution using functionalized magnetite nanoparticles: kinetic and thermodynamic studies journal, November 2017

Seizing the caesium journal, March 2010

Separation nanotechnology of diethylenetriaminepentaacetic acid bonded magnetic nanoparticles for spent nuclear fuel journal, January 2013

Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework journal, April 2016

O-carboxymethyl chitosan entrapped by silica: preparation and adsorption behaviour toward neodymium (III) ions: Adsorption of neodymium with SiO
journal, May 2012

Reduced Magnetism in Core–Shell Magnetite@MOF Composites
journal, October 2017

Heating and separation using nanomagnet-functionalized metal–organic frameworks
journal, January 2011

POROUS MATERIALS:Prospects for Giant Pores
journal, February 1999

Eu(III) adsorption using di(2-thylhexly) phosphoric acid-immobilized magnetic GMZ bentonite
journal, February 2012

Synthesis and chelating properties of some poly(amidoxime-hydroxamic acid) resins toward some trivalent lanthanide metal ions
journal, January 2005

Graft copolymer-lanthanide complexes obtained by radiation grafting on polyethylene film
journal, November 2002

Adsorption of lanthanum (III) from aqueous solution using 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester-grafted magnetic silica nanocomposites
journal, September 2013

Applications of magnetic metal–organic framework composites
journal, January 2013

Ion Imprinted Polymer Solid Phase Extraction (IIP‐SPE) for Preconcentrative Separation of Erbium(III) From Adjacent Lanthanides and Yttrium
journal, February 2006

Adsorption of heavy rare earth(III) with extraction resin containing bis(2,4,4-trimethylpentyl) monothiophosphinic acid
journal, July 2004

Minerals go critical
journal, August 2011

GEOTHERMAL ENERGY FROM THE EARTH:Its Potential Impact as an Environmentally Sustainable Resource
journal, November 1997

Cellulose Hydrolysis by a New Porous Coordination Polymer Decorated with Sulfonic Acid Functional Groups
journal, June 2011

Ethylenediamine grafting on a zeolite-like metal organic framework (ZMOF) for CO2 capture
journal, September 2013

A critical review on solvent extraction of rare earths from aqueous solutions
journal, February 2014

Adsorption behavior of rare earth elements on silica gel modified with diglycol amic acid
journal, February 2015

Monodisperse Magnetic Single-Crystal Ferrite Microspheres
journal, April 2005

Reticular synthesis and the design of new materials
journal, June 2003

Highly porous and stable metal–organic frameworks for uranium extraction
journal, January 2013

Cysteine-Functionalized Chitosan Magnetic Nano-Based Particles for the Recovery of Light and Heavy Rare Earth Metals: Uptake Kinetics and Sorption Isotherms
journal, February 2015

Recovery of rare earth metals through biosorption: An overview
journal, October 2013

Selective incarceration of caesium ions by Venus flytrap action of a flexible framework sulfide
journal, January 2010

Selective Uptake of Rare Earths from Aqueous Solutions by EDTA-Functionalized Magnetic and Nonmagnetic Nanoparticles
journal, March 2014

Magnetic Cores with Porous Coatings: Growth of Metal-Organic Frameworks on Particles Using Liquid Phase Epitaxy
journal, September 2012

Sorption of europium(III) and copper(II) by a mesostructured silica doped with acyl-hydroxypyrazole derivatives
journal, September 2006

Synthesis of Fe3O4@ZIF-8 magnetic core–shell microspheres and their potential application in a capillary microreactor
journal, July 2013

On the Extraction of Rare Earth Elements from Geothermal Brines
journal, August 2017

X-ray-absorption spectroscopy at the Fe $L_{2, 3}$ threshold in iron oxides
journal, August 1995

Rare earth element systematics in hydrothermal fluids
journal, March 1989

Opportunities and challenges for a sustainable energy future
journal, August 2012

Evaluating Rare Earth Element Availability: A Case with Revolutionary Demand from Clean Technologies
journal, February 2012

Coating Fe ₃ O ₄ Magnetic Nanoparticles with Humic Acid for High Efficient Removal of Heavy Metals in Water
journal, September 2008

Introduction of amino groups into acid-resistant MOFs for enhanced U( vi ) sorption
journal, January 2015

Molecular building blocks approach to the assembly of zeolite-like metal–organic frameworks (ZMOFs) with extra-large cavities
journal, January 2006

Adsorption of Uranyl ions on Amine-functionalization of MIL-101(Cr) Nanoparticles by a Facile Coordination-based Post-synthetic strategy and X-ray Absorption Spectroscopy Studies
journal, September 2015

Formation of a One-Dimensional Array of Oxygen in a Microporous Metal-Organic Solid
journal, December 2002

Selective Extraction of Heavy and Light Lanthanides from Aqueous Solution by Advanced Magnetic Nanosorbents
journal, April 2016

Using Functional Nano- and Microparticles for the Preparation of Metal–Organic Framework Composites with Novel Properties
journal, November 2013

Selective separation of rare earth ions from aqueous solution using functionalized magnetite nanoparticles: kinetic and thermodynamic studies
journal, November 2017

Seizing the caesium
journal, March 2010

Separation nanotechnology of diethylenetriaminepentaacetic acid bonded magnetic nanoparticles for spent nuclear fuel
journal, January 2013

Extraction of Lanthanide and Actinide Ions from Aqueous Mixtures Using a Carboxylic Acid-Functionalized Porous Aromatic Framework
journal, April 2016