A Critical Review on Superoxide-Based Sodium–Oxygen Batteries
Abstract
Abstract Sodium superoxide (NaO 2 ) based sodium–oxygen batteries (Na‐O 2 ) possess high theoretical energy density and high energy efficiency that can be an alternative energy storage device to lithium‐ion batteries. However, the state‐of‐the‐art sodium–oxygen batteries are still far from real application due to the limited understanding of the cell chemistry and reaction mechanism. This article reviews the recent advances on NaO 2 ‐based Na‐O 2 batteries, especially focusing on the reaction mechanism and the stability of NaO 2 . The parasitic reactions from the highly active NaO 2 are discussed. It is hoped this provides insightful understanding on the mechanism and the role of the discharge product in Na‐O 2 batteries.
- Authors:
-
[1]
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Argonne National Lab. (ANL), Argonne, IL (United States). Applied Materials Division
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
- OSTI Identifier:
- 1573034
- Alternate Identifier(s):
- OSTI ID: 1472178
- Grant/Contract Number:
- AC02-06CH11357; DE‐AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Small Methods
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 4; Journal ID: ISSN 2366-9608
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; reaction mechanism; sodium superoxide; sodium-oxygen batteries; solvent effect
Citation Formats
Bi, Xuanxuan, Wang, Rongyue, Amine, Khalil, and Lu, Jun. A Critical Review on Superoxide-Based Sodium–Oxygen Batteries. United States: N. p., 2018.
Web. doi:10.1002/smtd.201800247.
Bi, Xuanxuan, Wang, Rongyue, Amine, Khalil, & Lu, Jun. A Critical Review on Superoxide-Based Sodium–Oxygen Batteries. United States. https://doi.org/10.1002/smtd.201800247
Bi, Xuanxuan, Wang, Rongyue, Amine, Khalil, and Lu, Jun. Fri .
"A Critical Review on Superoxide-Based Sodium–Oxygen Batteries". United States. https://doi.org/10.1002/smtd.201800247. https://www.osti.gov/servlets/purl/1573034.
@article{osti_1573034,
title = {A Critical Review on Superoxide-Based Sodium–Oxygen Batteries},
author = {Bi, Xuanxuan and Wang, Rongyue and Amine, Khalil and Lu, Jun},
abstractNote = {Abstract Sodium superoxide (NaO 2 ) based sodium–oxygen batteries (Na‐O 2 ) possess high theoretical energy density and high energy efficiency that can be an alternative energy storage device to lithium‐ion batteries. However, the state‐of‐the‐art sodium–oxygen batteries are still far from real application due to the limited understanding of the cell chemistry and reaction mechanism. This article reviews the recent advances on NaO 2 ‐based Na‐O 2 batteries, especially focusing on the reaction mechanism and the stability of NaO 2 . The parasitic reactions from the highly active NaO 2 are discussed. It is hoped this provides insightful understanding on the mechanism and the role of the discharge product in Na‐O 2 batteries.},
doi = {10.1002/smtd.201800247},
journal = {Small Methods},
number = 4,
volume = 3,
place = {United States},
year = {Fri Sep 21 00:00:00 EDT 2018},
month = {Fri Sep 21 00:00:00 EDT 2018}
}
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