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Title: Turnover rates on complex heterogeneous catalysts

  1. Dept. of Chemical Engineering, University of Virginia, Charlottesville VA 22904
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Publisher's Accepted Manuscript
Journal Name:
AIChE Journal
Additional Journal Information:
Journal Name: AIChE Journal Journal Volume: 64 Journal Issue: 11; Journal ID: ISSN 0001-1541
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States

Citation Formats

Davis, Robert. Turnover rates on complex heterogeneous catalysts. United States: N. p., 2018. Web. doi:10.1002/aic.16385.
Davis, Robert. Turnover rates on complex heterogeneous catalysts. United States. doi:10.1002/aic.16385.
Davis, Robert. Mon . "Turnover rates on complex heterogeneous catalysts". United States. doi:10.1002/aic.16385.
title = {Turnover rates on complex heterogeneous catalysts},
author = {Davis, Robert},
abstractNote = {},
doi = {10.1002/aic.16385},
journal = {AIChE Journal},
number = 11,
volume = 64,
place = {United States},
year = {2018},
month = {9}

Journal Article:
Free Publicly Available Full Text
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DOI: 10.1002/aic.16385

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Works referenced in this record:

Surface and Interface Engineering of Noble-Metal-Free Electrocatalysts for Efficient Energy Conversion Processes
journal, February 2017

Effect of alumina and titania on the oxidation of CO over Au nanoparticles evaluated by 13C isotopic transient analysis
journal, March 2006

Atomically FeN2 moieties dispersed on mesoporous carbon: A new atomic catalyst for efficient oxygen reduction catalysis
journal, May 2017

Spectroscopic insights into the nature of active sites in iron–nitrogen–carbon electrocatalysts for oxygen reduction in acid
journal, November 2016

Nano-structured non-platinum catalysts for automotive fuel cell application
journal, September 2015

Temporal Analysis of Products (TAP)—A Unique Catalyst Evaluation System with Submillisecond Time Resolution
journal, February 1988

ATR-IR Flow-Through Cell for Concentration Modulation Excitation Spectroscopy:  Diffusion Experiments and Simulations
journal, November 2003

  • Urakawa, Atsushi; Wirz, Ronny; Bürgi, Thomas
  • The Journal of Physical Chemistry B, Vol. 107, Issue 47
  • DOI: 10.1021/jp0359889

Temporal analysis of products (TAP)—Recent advances in technology for kinetic analysis of multi-component catalysts
journal, January 2010

  • Gleaves, John T.; Yablonsky, Gregory; Zheng, Xiaolin
  • Journal of Molecular Catalysis A: Chemical, Vol. 315, Issue 2
  • DOI: 10.1016/j.molcata.2009.06.017

Oxygen-exchange reactions during CO oxidation over titania- and alumina-supported Au nanoparticles
journal, July 2006

Exploring catalytic solid/liquid interfaces by in situ attenuated total reflection infrared spectroscopy
journal, January 2010

  • Andanson, Jean-Michel; Baiker, Alfons
  • Chemical Society Reviews, Vol. 39, Issue 12
  • DOI: 10.1039/b919544k

Kinetic and Theoretical Insights into the Mechanism of Alkanol Dehydration on Solid Brønsted Acid Catalysts
journal, February 2016

  • Knaeble, William; Iglesia, Enrique
  • The Journal of Physical Chemistry C, Vol. 120, Issue 6
  • DOI: 10.1021/acs.jpcc.5b11127

Interaction between Ketopantolactone and Chirally Modified Pt Investigated by Attenuated Total Reflection IR Concentration Modulation Spectroscopy
journal, November 2003

  • Bonalumi, Norberto; Bürgi, Thomas; Baiker, Alfons
  • Journal of the American Chemical Society, Vol. 125, Issue 44
  • DOI: 10.1021/ja037371a

Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostructures
journal, January 1999

  • Barton, David G.; Shtein, Max; Wilson, Ryan D.
  • The Journal of Physical Chemistry B, Vol. 103, Issue 4
  • DOI: 10.1021/jp983555d

In Situ Infrared Spectroscopy of Catalytic Solid−Liquid Interfaces Using Phase-Sensitive Detection:  Enantioselective Hydrogenation of a Pyrone over Pd/TiO 2
journal, October 2002

  • Bürgi, Thomas; Baiker, Alfons
  • The Journal of Physical Chemistry B, Vol. 106, Issue 41
  • DOI: 10.1021/jp0255987

Evolution, achievements, and perspectives of the TAP technique
journal, March 2007

Structural and Catalytic Characterization of Solid Acids Based on Zirconia Modified by Tungsten Oxide
journal, January 1999

  • Barton, David G.; Soled, Stuart L.; Meitzner, George D.
  • Journal of Catalysis, Vol. 181, Issue 1
  • DOI: 10.1006/jcat.1998.2269

Isotopic and Chemical Titration of Acid Sites in Tungsten Oxide Domains Supported on Zirconia
journal, February 2001

  • Baertsch, Chelsey D.; Soled, Stuart L.; Iglesia, Enrique
  • The Journal of Physical Chemistry B, Vol. 105, Issue 7
  • DOI: 10.1021/jp003073d

Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy
journal, August 2014

  • Meemken, Fabian; Müller, Philipp; Hungerbühler, Konrad
  • Review of Scientific Instruments, Vol. 85, Issue 8
  • DOI: 10.1063/1.4891188

Synthesis of solid superacid of tungsten oxide supported on zirconia and its catalytic action for reactions of butane and pentane
journal, January 1988

  • Hino, Makoto; Arata, Kazushi
  • Journal of the Chemical Society, Chemical Communications, Issue 18
  • DOI: 10.1039/c39880001259

Nature of Catalytically Active Sites in the Supported WO 3 /ZrO 2 Solid Acid System: A Current Perspective
journal, February 2017

Design and operating characteristics of a transient kinetic analysis catalysis reactor system employing in situ transmission Fourier transform infrared
journal, September 2006

  • Yang, Yong; Disselkamp, R. S.; Szanyi, J.
  • Review of Scientific Instruments, Vol. 77, Issue 9
  • DOI: 10.1063/1.2349602

Fe-N Decorated Hybrids of CNTs Grown on Hierarchically Porous Carbon for High-Performance Oxygen Reduction
journal, July 2014

Computational and experimental evidence for a new TM–N 3 /C moiety family in non-PGM electrocatalysts
journal, January 2015

  • Kabir, Sadia; Artyushkova, Kateryna; Kiefer, Boris
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 27
  • DOI: 10.1039/C5CP02230D

Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
journal, February 2016

Sensitivity enhancement and dynamic behavior analysis by modulation excitation spectroscopy: Principle and application in heterogeneous catalysis
journal, October 2008

  • Urakawa, Atsushi; Bürgi, Thomas; Baiker, Alfons
  • Chemical Engineering Science, Vol. 63, Issue 20
  • DOI: 10.1016/j.ces.2007.06.009

Multiproduct Steady-State Isotopic Transient Kinetic Analysis of the Ethanol Coupling Reaction over Hydroxyapatite and Magnesia
journal, February 2015

  • Hanspal, Sabra; Young, Zachary D.; Shou, Heng
  • ACS Catalysis, Vol. 5, Issue 3
  • DOI: 10.1021/cs502023g

The water-gas shift reaction on Pt/γ-Al2O3 catalyst: Operando SSITKA-DRIFTS-mass spectroscopy studies
journal, November 2008

  • Kalamaras, Christos M.; Olympiou, George G.; Efstathiou, Angelos M.
  • Catalysis Today, Vol. 138, Issue 3-4
  • DOI: 10.1016/j.cattod.2008.06.010

Characterization of Catalytic Surfaces by Isotopic-Transient Kinetics during Steady-State Reaction
journal, May 1995

  • Shannon, Schohn L.; Goodwin, James G.
  • Chemical Reviews, Vol. 95, Issue 3
  • DOI: 10.1021/cr00035a011

Acid strength and solvation in catalysis by MFI zeolites and effects of the identity, concentration and location of framework heteroatoms
journal, April 2014

Heterogeneous Asymmetric Hydrogenation of Activated Ketones: Mechanistic Insight into the Role of Alcohol Products by in Situ Modulation-Excitation IR Spectroscopy
journal, February 2012

  • Maeda, Nobutaka; Sano, Shogo; Mallat, Tamas
  • The Journal of Physical Chemistry C, Vol. 116, Issue 6
  • DOI: 10.1021/jp210939d

Molecular Insight into Pt-Catalyzed Chemoselective Hydrogenation of an Aromatic Ketone by In Situ Modulation–Excitation IR Spectroscopy
journal, August 2012

  • Chen, Mengmeng; Maeda, Nobutaka; Baiker, Alfons
  • ACS Catalysis, Vol. 2, Issue 9
  • DOI: 10.1021/cs300408x

Isotopic Transient Kinetic Analysis of Cs-Promoted Ru/MgO during Ammonia Synthesis
journal, September 2002

Recent Approaches in Mechanistic and Kinetic Studies of Catalytic Reactions Using SSITKA Technique
journal, November 2014

  • Ledesma, Cristian; Yang, Jia; Chen, De
  • ACS Catalysis, Vol. 4, Issue 12
  • DOI: 10.1021/cs501264f

Solvation and acid strength effects on catalysis by faujasite zeolites
journal, February 2012

Identification of active Zr–WOx clusters on a ZrO2 support for solid acid catalysts
journal, November 2009

  • Zhou, Wu; Ross-Medgaarden, Elizabeth I.; Knowles, William V.
  • Nature Chemistry, Vol. 1, Issue 9
  • DOI: 10.1038/nchem.433

Isotopic Transient Analysis of Ammonia Synthesis over Ba or Cs-Promoted Ru/Carbon Catalysts
journal, March 2004

Competition of chiral modifiers on platinum: A transient catalytic and in situ ATR-IR study in continuous reactors
journal, December 2006

Atomically Dispersed Co and Cu on N-Doped Carbon for Reactions Involving C–H Activation
journal, March 2018

Turnover Rates in Heterogeneous Catalysis
journal, May 1995

Influence of the Preparative Method on the Activity of Highly Acidic WOx/ZrO2and the Relative Acid Activity Compared with Zeolites
journal, June 1997

  • Santiesteban, J. G.; Vartuli, J. C.; Han, S.
  • Journal of Catalysis, Vol. 168, Issue 2
  • DOI: 10.1006/jcat.1997.1658

Reduction of Propionic Acid over a Pd-Promoted ReO x /SiO 2 Catalyst Probed by X-ray Absorption Spectroscopy and Transient Kinetic Analysis
journal, July 2018

Relating n -Pentane Isomerization Activity to the Tungsten Surface Density of WO x /ZrO 2
journal, September 2010

  • Soultanidis, Nikolaos; Zhou, Wu; Psarras, Antonis C.
  • Journal of the American Chemical Society, Vol. 132, Issue 38
  • DOI: 10.1021/ja105519y

Spectroscopic Detection of Active Species on Catalytic Surfaces: Steady-State versus Transient Method
journal, September 2012

  • Maeda, Nobutaka; Meemken, Fabian; Hungerbühler, Konrad
  • CHIMIA International Journal for Chemistry, Vol. 66, Issue 9
  • DOI: 10.2533/chimia.2012.664

Forty years of temporal analysis of products
journal, January 2017

  • Morgan, K.; Maguire, N.; Fushimi, R.
  • Catalysis Science & Technology, Vol. 7, Issue 12
  • DOI: 10.1039/C7CY00678K

Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
journal, August 2017

Discriminating Catalytically Active FeN x Species of Atomically Dispersed Fe–N–C Catalyst for Selective Oxidation of the C–H Bond
journal, July 2017

  • Liu, Wengang; Zhang, Leilei; Liu, Xin
  • Journal of the American Chemical Society, Vol. 139, Issue 31
  • DOI: 10.1021/jacs.7b05130

Investigation of Alumina-Supported Au Catalyst for CO Oxidation by Isotopic Transient Analysis and X-ray Absorption Spectroscopy
journal, February 2005

  • Calla, Jason T.; Davis, Robert J.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 6
  • DOI: 10.1021/jp0488719

Isotopic transient analysis of the ethanol coupling reaction over magnesia
journal, February 2013