Turnover rates on complex heterogeneous catalysts

doi:10.1002/aic.16385

Title: Turnover rates on complex heterogeneous catalysts

Authors:

Davis, Robert ^[1]

Dept. of Chemical Engineering, University of Virginia, Charlottesville VA 22904

Publication Date:: 2018-09-17

Sponsoring Org.:: USDOE

OSTI Identifier:: 1472153

Grant/Contract Number:: DEFG02-95ER14549

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: AIChE Journal

Additional Journal Information:: Journal Name: AIChE Journal Journal Volume: 64 Journal Issue: 11; Journal ID: ISSN 0001-1541

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: United States

Language:: English

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                    Davis, Robert. Turnover rates on complex heterogeneous catalysts.  United States: N. p., 2018. 
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                    Davis, Robert. Turnover rates on complex heterogeneous catalysts.  United States.  doi:10.1002/aic.16385.

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@article{osti_1472153,

  title        = {Turnover rates on complex heterogeneous catalysts},

  author       = {Davis, Robert},

  abstractNote = {},

  doi          = {10.1002/aic.16385},

  journal      = {AIChE Journal},

  number       = 11,

  volume       = 64,

  place        = {United States},

  year         = {2018},

  month        = {9}

}

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DOI: 10.1002/aic.16385

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Title: Turnover rates on complex heterogeneous catalysts

Citation Formats

Surface and Interface Engineering of Noble-Metal-Free Electrocatalysts for Efficient Energy Conversion Processes journal, February 2017

Effect of alumina and titania on the oxidation of CO over Au nanoparticles evaluated by 13C isotopic transient analysis journal, March 2006

Atomically FeN2 moieties dispersed on mesoporous carbon: A new atomic catalyst for efficient oxygen reduction catalysis journal, May 2017

Low temperature water–gas shift: Applications of a modified SSITKA–DRIFTS method under conditions of H2 co-feeding over metal/ceria and related oxides journal, December 2007

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Mechanistic studies of methanol synthesis over Cu from CO/CO2/H2/H2O mixtures: The source of C in methanol and the role of water journal, February 2013

Nano-structured non-platinum catalysts for automotive fuel cell application journal, September 2015

Temporal Analysis of Products (TAP)—A Unique Catalyst Evaluation System with Submillisecond Time Resolution journal, February 1988

ATR-IR Flow-Through Cell for Concentration Modulation Excitation Spectroscopy: Diffusion Experiments and Simulations journal, November 2003

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Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostructures journal, January 1999

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Evolution, achievements, and perspectives of the TAP technique journal, March 2007

Structural and Catalytic Characterization of Solid Acids Based on Zirconia Modified by Tungsten Oxide journal, January 1999

Isotopic and Chemical Titration of Acid Sites in Tungsten Oxide Domains Supported on Zirconia journal, February 2001

Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy journal, August 2014

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Sensitivity enhancement and dynamic behavior analysis by modulation excitation spectroscopy: Principle and application in heterogeneous catalysis journal, October 2008

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The water-gas shift reaction on Pt/γ-Al2O3 catalyst: Operando SSITKA-DRIFTS-mass spectroscopy studies journal, November 2008

Characterization of Catalytic Surfaces by Isotopic-Transient Kinetics during Steady-State Reaction journal, May 1995

Acid strength and solvation in catalysis by MFI zeolites and effects of the identity, concentration and location of framework heteroatoms journal, April 2014

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Solvation and acid strength effects on catalysis by faujasite zeolites journal, February 2012

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Isotopic Transient Analysis of Ammonia Synthesis over Ba or Cs-Promoted Ru/Carbon Catalysts journal, March 2004

Competition of chiral modifiers on platinum: A transient catalytic and in situ ATR-IR study in continuous reactors journal, December 2006

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Turnover Rates in Heterogeneous Catalysis journal, May 1995

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Isotopic transient analysis of ammonia synthesis over Ru/MgO catalysts promoted by cesium, barium, or lanthanum journal, March 2004

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Forty years of temporal analysis of products journal, January 2017

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Surface and Interface Engineering of Noble-Metal-Free Electrocatalysts for Efficient Energy Conversion Processes
journal, February 2017

Effect of alumina and titania on the oxidation of CO over Au nanoparticles evaluated by 13C isotopic transient analysis
journal, March 2006

Atomically FeN2 moieties dispersed on mesoporous carbon: A new atomic catalyst for efficient oxygen reduction catalysis
journal, May 2017

Low temperature water–gas shift: Applications of a modified SSITKA–DRIFTS method under conditions of H2 co-feeding over metal/ceria and related oxides
journal, December 2007

Spectroscopic insights into the nature of active sites in iron–nitrogen–carbon electrocatalysts for oxygen reduction in acid
journal, November 2016

Mechanistic studies of methanol synthesis over Cu from CO/CO2/H2/H2O mixtures: The source of C in methanol and the role of water
journal, February 2013

Nano-structured non-platinum catalysts for automotive fuel cell application
journal, September 2015

Temporal Analysis of Products (TAP)—A Unique Catalyst Evaluation System with Submillisecond Time Resolution
journal, February 1988

ATR-IR Flow-Through Cell for Concentration Modulation Excitation Spectroscopy: Diffusion Experiments and Simulations
journal, November 2003

Temporal analysis of products (TAP)—Recent advances in technology for kinetic analysis of multi-component catalysts
journal, January 2010

Oxygen-exchange reactions during CO oxidation over titania- and alumina-supported Au nanoparticles
journal, July 2006

Exploring catalytic solid/liquid interfaces by in situ attenuated total reflection infrared spectroscopy
journal, January 2010

Kinetic and Theoretical Insights into the Mechanism of Alkanol Dehydration on Solid Brønsted Acid Catalysts
journal, February 2016

Interaction between Ketopantolactone and Chirally Modified Pt Investigated by Attenuated Total Reflection IR Concentration Modulation Spectroscopy
journal, November 2003

Structure and Electronic Properties of Solid Acids Based on Tungsten Oxide Nanostructures
journal, January 1999

In Situ Infrared Spectroscopy of Catalytic Solid−Liquid Interfaces Using Phase-Sensitive Detection: Enantioselective Hydrogenation of a Pyrone over Pd/TiO ₂
journal, October 2002

Multi-product steady-state isotopic transient kinetic analysis of CO hydrogenation over supported molybdenum carbide
journal, October 2013

Evolution, achievements, and perspectives of the TAP technique
journal, March 2007

Structural and Catalytic Characterization of Solid Acids Based on Zirconia Modified by Tungsten Oxide
journal, January 1999

Isotopic and Chemical Titration of Acid Sites in Tungsten Oxide Domains Supported on Zirconia
journal, February 2001

Simultaneous probing of bulk liquid phase and catalytic gas-liquid-solid interface under working conditions using attenuated total reflection infrared spectroscopy
journal, August 2014

Synthesis of solid superacid of tungsten oxide supported on zirconia and its catalytic action for reactions of butane and pentane
journal, January 1988

Nature of Catalytically Active Sites in the Supported WO ₃ /ZrO ₂ Solid Acid System: A Current Perspective
journal, February 2017

Design and operating characteristics of a transient kinetic analysis catalysis reactor system employing in situ transmission Fourier transform infrared
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Fe-N Decorated Hybrids of CNTs Grown on Hierarchically Porous Carbon for High-Performance Oxygen Reduction
journal, July 2014

Computational and experimental evidence for a new TM–N ₃ /C moiety family in non-PGM electrocatalysts
journal, January 2015

Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
journal, February 2016

Importance of Product Readsorption during Isotopic Transient Analysis of Ammonia Synthesis on Ba-Promoted Ru/BaX Catalyst
journal, October 2002

Sensitivity enhancement and dynamic behavior analysis by modulation excitation spectroscopy: Principle and application in heterogeneous catalysis
journal, October 2008

Multiproduct Steady-State Isotopic Transient Kinetic Analysis of the Ethanol Coupling Reaction over Hydroxyapatite and Magnesia
journal, February 2015

The water-gas shift reaction on Pt/γ-Al2O3 catalyst: Operando SSITKA-DRIFTS-mass spectroscopy studies
journal, November 2008

Characterization of Catalytic Surfaces by Isotopic-Transient Kinetics during Steady-State Reaction
journal, May 1995

Acid strength and solvation in catalysis by MFI zeolites and effects of the identity, concentration and location of framework heteroatoms
journal, April 2014

Heterogeneous Asymmetric Hydrogenation of Activated Ketones: Mechanistic Insight into the Role of Alcohol Products by in Situ Modulation-Excitation IR Spectroscopy
journal, February 2012

Molecular Insight into Pt-Catalyzed Chemoselective Hydrogenation of an Aromatic Ketone by In Situ Modulation–Excitation IR Spectroscopy
journal, August 2012

Isotopic Transient Kinetic Analysis of Cs-Promoted Ru/MgO during Ammonia Synthesis
journal, September 2002

Recent Approaches in Mechanistic and Kinetic Studies of Catalytic Reactions Using SSITKA Technique
journal, November 2014

Solvation and acid strength effects on catalysis by faujasite zeolites
journal, February 2012

Identification of active Zr–WOx clusters on a ZrO2 support for solid acid catalysts
journal, November 2009

Isotopic Transient Analysis of Ammonia Synthesis over Ba or Cs-Promoted Ru/Carbon Catalysts
journal, March 2004

Competition of chiral modifiers on platinum: A transient catalytic and in situ ATR-IR study in continuous reactors
journal, December 2006

Determination of the Au active site and surface active species via operando transmission FTIR and isotopic transient experiments on 2.3wt.% Au/TiO2 for the WGS reaction
journal, May 2012

Atomically Dispersed Co and Cu on N-Doped Carbon for Reactions Involving C–H Activation
journal, March 2018

Turnover Rates in Heterogeneous Catalysis
journal, May 1995

Influence of the Preparative Method on the Activity of Highly Acidic WOx/ZrO2and the Relative Acid Activity Compared with Zeolites
journal, June 1997

Reduction of Propionic Acid over a Pd-Promoted ReO _x /SiO ₂ Catalyst Probed by X-ray Absorption Spectroscopy and Transient Kinetic Analysis
journal, July 2018

Relating n -Pentane Isomerization Activity to the Tungsten Surface Density of WO _x /ZrO ₂
journal, September 2010

Isotopic transient analysis of ammonia synthesis over Ru/MgO catalysts promoted by cesium, barium, or lanthanum
journal, March 2004

Spectroscopic Detection of Active Species on Catalytic Surfaces: Steady-State versus Transient Method
journal, September 2012

Forty years of temporal analysis of products
journal, January 2017

Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
journal, August 2017

Discriminating Catalytically Active FeN _x Species of Atomically Dispersed Fe–N–C Catalyst for Selective Oxidation of the C–H Bond
journal, July 2017

Investigation of Alumina-Supported Au Catalyst for CO Oxidation by Isotopic Transient Analysis and X-ray Absorption Spectroscopy ^†
journal, February 2005

Isotopic transient analysis of the ethanol coupling reaction over magnesia
journal, February 2013